Question
Write a note on Strecker reaction.

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Match the common names given in Column I with the IUPAC names given in Column II.
 
Column I
(Common names)
 
Column II
(IUPAC names)
(i)
Cinnamaldehyde
(a)
Pentanal
(ii)
Acetophenone
(b)
Prop-2-enal
(iii)
Valeraldehyde
(c)
4-Methylpent-3-en-2-one
(iv)
Acrolein
(d)
3-Phenylprop-2-enal
(v)
Mesityl oxide
(e)
1-Phenylethanone
The following data were obtained during the first order thermal decomposition of $N_2O_5(g)$ at a constant volume:
$2N_2O_5(g) → 2N_2O_4(g) + O_2(g)$
S. No. Time/s Total pressure/atm
$1.$ $0$ $0.5$
$2.$ $100$ $0.512$
Calculate the rate constant.
The rate of a reaction becomes four times when the temperature changes from $293\ K$ to $313\ K.$ Calculate the energy of activation $(E_a)$ of the reaction assuming that it does not change with temperature.
$[R=8.314\ J\ K^{-1}\ MOL^{-1},\log 4=0.6021]$
Draw the structure of the following:
$H_2S_2O_8$
For $M^{2+}/M$ and $M^{3+}/M^{2+}$ systems the values for some metals are as follows:
$Cr^{2+}/Cr$ $- 0.9 V$ $Cr^3/Cr^{2+}$ $- 0.4 V$
$Mn^{2+}/Mn$ $- 1.2 V$ $Mn^{3+}/Mn^{2+}$ $+ 1.5 V$
$Fe^{2+}/Fe$ $- 0.4 V$ $Fe^{3+}/Fe^{2+}$ $+ 0.8 V$
Use this data to comment upon:
  1. The stability of $Fe^{3+}$ in acid solution as compared to that of $Cr^{3+}$ or $Mn^{3+}.$
  2. The ease with which iron can be oxidised as compared to a similar process for either chromium or manganese metal.
What is the reaction of formic acid with the following :
(i) Concentrated $H _2 SO _4$
(ii) Aqueous $C l _{ 2 }$ (chlorine water)

Physical and chemical adsorption respond differently with a rise in temperature. What is this difference and why is it so?
Ethers can be prepared by Williamson synthesis in which an alkyl halide is reacted with sodium alkoxide. Di-tert-butyl ether can’t be prepared by this method. Explain.
How are polymers classified on the basis of structure?
How can you prepare $Cl_2$ from $HCl$ and $HCl$ from $Cl_2?$ Write reactions only.