Question
Write a note on Strecker reaction.

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For a reaction
$2\text{H}_2\text{O}_2\frac{\text{I}^-}{\text{alkaline medium}}2\text{H}_2\text{O}+\text{O}_2$
the proposed mechanism is as given below:
  1. $\text{H}_2\text{O}_2+\text{I}^{-}\xrightarrow{\ \ \ \ \ \ \ }\text{H}_2\text{O}+\text{IO}^{-}(\text{slow})$
  2. $\text{H}_2\text{O}_2+\text{IO}^{-}\xrightarrow{\ \ \ \ \ \ \ }\text{H}_2\text{O}+\text{I}^{-}+\text{O}_2(\text{fast})$
  1. Write rate law for the reaction.
  2. Write the overall order of reaction.
  3. Out of steps (1) and (2), which one is rate determining step?
Explain chemical reactivity of transition metals.
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Although phenoxide ion has more number of resonating structures than carboxylate ion, carboxylic acid is a stronger acid than phenol. Why?
What factors are responsible for deviations for Raoult's law?
Write the mechanism of the following reaction :
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1.25 g of protein is present in 300 mL aqueous solution of a protein. The osmotic pressure of this solution at 300 K was found to be $2.50 \times 10^{-3}$ bar. Calculate the molar mass of protein. $[R=0.083 L$ bar $\operatorname{mol}^{-1} K^{-1}$ ].
(A) why are transition elements good catalysts ?
(B) Zinc does not exhibit variable oxidate state, why?
The rate of a reaction becomes four times when the temperature changes from $293 K$ to $313K.$ Calculate the energy of activation $(E_a)$ of the reaction assuming that it does not change with temperature. $\ce{[R=8.314 J K^{-1} MOL^{-1}, \log 4=0.6021]}$
Write the structures of A, B, C, D and E in the following reactions.
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