Question
Write a notes on
  1. Sheet silicates
  2. Three dimensional silicate

Answer

1. Sheet silicates:
Silicates which contain $\left( Si _2 O _5\right)_n^{2 n-}$ are called sheet or phyllo silicates. In these, Each $\left[ SiO _4\right]^{4-}$ tetrahedron unit shares three oxygen atoms with others and thus by forming twodimensional sheets. These sheets, silicates form layered structures in which silicate sheets are stacked over each other. The attractive forces between these layers are very week, hence they can be cleaved easily just like graphite.


Image
Example: Talc, Mica etc...
2. Three dimensional silicate:
Silicates in which all the oxygen atoms of $\left[ SiO _4\right]^{4-}$ tetrahedra are shared with other tetrahedra to form three-dimensional network are called three dimensional or tecto silicates. They have general formula $\left( SiO _2\right)_n$.
Examples:
Quartz. These tecto silicates can be converted into Three dimentional aluminosilicates by replacing $\left[\left[ SiO _4\right]^{4-}-\right.$ units by $\left[ AlO _4\right]^{5-}$ units. E.g. Feldspar, Zeolites etc.,

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