Question
  1. Write chemical equations when:
  1. Borax is heated strongly.
  2. Aluminium is treated with dilute NaOH.
  3. Dimethyldichlorosilane is hydrolysed followed by condensation polymeri-sation.
  1.  
  1. Explain that $CO_2$ is a gas while $SiO_2$ is solid at room temperature.
  2. $SnCl_2$​​​​​​​ acts as reducing agent. Explain.

Answer

  1.  
  1. $\text{Na}_2\text{B}_4\text{O}_7.10\text{H}_2\text{O}\xrightarrow{\ \ \ \text{heat}\ \ \ }\text{Na}_2\text{B}_4\text{O}_7\\ \ \ \ \ \ \ \ ^\text{Borax}\\ \xrightarrow{\ \ \text{heat}\ \ }2\text{NaBO}_2+\text{B}_2\text{O}_3\\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ ^\text{Sodium}\ \ \ \ \ \ \ \ ^\text{Boric}\\ \ \ \ \ \ \ \ \ \ \ \ \ ^\text{metaborate}\ \ \ ^\text{anhydride}$
  2. $2\text{Al}+2\text{NaOH}+2\text{H}_2\text{O}\xrightarrow{\ \ \ \ }2\text{NaAlO}_2+3\text{H}_2\\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ ^\text{Sodium}\\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ ^\text{metaaluminate}$
  3.  
  1.  
  1. $CO_2$ exists as descrete molecules whereas $SiO_2$ is three dimensional covalent solid.
  2. $Sn^{4+}$ is more stable than $Sn^{2+}$, therefore $SnCl_2$ is good reducing agent.

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