Question
Write electrode reactions taking place in:
- Ni–Cd cell.
- Lead Acid Accumulator.
$\text{NiO}_2(\text{s) + 2H}_2\text{O}+2\text{e}^-\xrightarrow{ \ \ \ \ \ \ \ }\text{Ni(OH)}_2(\text{s})+2\text{OH}^-(\text{aq})$
$\text{SO}_4^{2-}+4\text{H}^++2\text{e}^-\xrightarrow{\ \ \ \ \ \ \ \ \ }\text{PbSO}_4+2\text{H}_2\text{O}$ (at cathode)
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(At. no. of Ni = 28)
Mg (s)+Cu2+ (aq) $\rightarrow$ Mg2+ (aq) + Cu (s)
Given: Eocell = + 2.71 V, 1 F = 96500 C mol–1