Write IUPAC name of the following compounds : - Vidyadip

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Write IUPAC name of the following compounds :

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An ether $(A), C_5H_{12}O,$ when heated with excess of hot $HI$ produce two alkyl halides which on hydrolysis form compound $(B)$ and $(C),$ oxidation of $(B)$ gave and acid $(D),$ whereas oxidation of $(C)$ gave a ketone $(E).$ Deduce the structural formula of $(A), (B), (C), (D)$ and $(E).$

Discuss the structure of sulfur dioxide.

Coordination number used in coordination of compounds is somewhat different than that used in solid state. Explain.

From the rate expressions for the following reactions, determine their order :
(a) $2 N _2 O _{5( g )} \rightarrow 4 NO _{2( g )}+ O _{2( g )}:$ Rate $= k \left[ N _2 O _5\right]$
(b) $CHCl _{3( g )}+ Cl _{2( g )} \rightarrow CCl _{4( g )}+ HCl _{( g )}:$ Rate $= k \left[ CHL _3\right]\left[ Cl _2\right]^{1 / 2}$
(c) $C _2 H _5 Cl _{( g )} \rightarrow C _2 H _{4( g )}+ HCl _{( g )}$ : Rate $= k \left[ C _2 H _5 Cl \right]$
(d) $2 NO _{2( g )}+ F _{2( g )} \rightarrow 2 NO _2 F _{( g )} \rightarrow$ : Rate $= k \left( NO _2\right]\left[ F _2\right]$

A mixture of benzene and toluene contains $30\%$ by mass of toluene. At $30{}^\circ C,$ vapour pressure of pure toluene is $36.7\ mm\ Hg$ and that of pure benzene is $118.2\ mm\ Hg.$ Assuming that the two liquids form ideal solutions, calculate the total pressure and partial pressure of each constituent above the solution at $30{}^\circ C.$

Explain the following :
Planar packing arrangement of spheres.
OR
Close packing in two dimensions.
OR
AAAA type and ABAB type of two dimensional arrangement.
OR
(i) Square close packing
(ii) Hexagonal close packing.

Set up the cell consisting of $H _{( aq )}^{+} \mid H _{2( g )}$ and $P b _{( a q )}^{2+} \mid Pb _{( s )}$ electrodes. Calculate the emf at $25^{\circ} C$ of the cell if $\left[ Pb ^{2+}\right]=0.1 M$,
$\left[ H ^{+}\right]=0.5 M$ and hydrogen gas is at $2 atm$ pressure. $E _{ pb ^{2+} / pb }=-0.126 V$.

Explain Hoffmann degradation of amides.
Write a note on Hoffmann bromamide degradation.

Discuss the mechanism of alkaline hydrolysis of bromomethane.

Explain the trend in the density, melting and boiling points of Group 16 elements.