Question
Write limitations of Werner's Coordination Theory
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$\log{k}=14.2-\frac{\text{1.0}\times\text{10}^{4}}{\text{T}}K$
Calculate Ea for this reaction and rate constant k if its half-life period be 200 minutes.
(Given: R = 8.314 J K–1 mol–1)
Match the starting materials given in Column I with the products formed by these (Column II) in the reaction with II.
Column I | Column II | ||
(i) | CH3-o-CH3 | (a) | ![]() |
(ii) | ![]() | (b) | $\ \ \ \ \ \ \ \ \ \ \ \ \ \text{CH}_3 \\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ | \\ \text{CH}_3-\text{C}-\text{I}+\text{CH}_3\text{OH} \\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ | \\ \ \ \ \ \ \ \ \ \ \ \ \ \ \text{CH}_3$ |
(iii) | $\ \ \ \ \ \ \ \ \ \ \ \ \ \text{CH}_3 \\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ | \\ \text{H}_3\text{C}-\text{C}-\text{O}-\text{CH}_3 \\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ | \\ \ \ \ \ \ \ \ \ \ \ \ \ \ \text{CH}_3$ | (c) | ![]() |
(iv) | ![]() | (d) | CH3-OH + CH3-I |
(e) | ![]() | ||
(f) | ![]() | ||
(g) | $\ \ \ \ \ \ \ \ \ \ \ \ \ \text{CH}_3 \\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ | \\ \text{CH}_3-\text{C}-\text{OH}+\text{CH}_3\text{I} \\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ | \\ \ \ \ \ \ \ \ \ \ \ \ \ \ \text{CH}_3$ |
Match the structures of compounds given in Column I with the classes of compounds given in Column II.
| Column I | Column II | ||
| (i) | $\text{CH}_3-\text{CH}-\text{CH}_3\\ \ \ \ \ \ \ \ \ \ \ \ \ \ |\\ \ \ \ \ \ \ \ \ \ \ \ \ \text{X}$ | (a) | Aryl halide |
| (ii) | $\text{CH}_2==\text{CH}-\text{CH}_2-\text{X}$ | (b) | Alkyl halide |
| (iii) | ![]() | (c) | Vinyl halide |
| (iv) | $\text{CH}_2==\text{CH}-\text{X}$ | (d) | Allyl halide |