Based on structure polymers are classified as linear chain polymers, branched chain polymers and network or cross linked polymers.
(1) Linear chain polymers : When the monomer molecules are joined together in a linear arrangement, the resulting polymer is straight-chain or long-chain polymer, e.g., polythene, PVC.

(2) Branched-chain polymers : These polymers consist of long and straight chain with smaller side chains give rise to branched-chain polymers. They have low density. They have lower melting points and tensile strength. Polypropylene having methyl groups as branches.

(3) Network or cross-linked polymers : These polymers consist of cross-linking of chains by strong covalent bonds leading to a network-like structure. Cross-linking results from polyfunctional monomers, e.g., melamine, bakelite, vulcanization of rubber. These polymers are hard rigid and brittle.
