Question
Write the classification of polymers based on structure. Give examples###Write the reactions involved in the preparation of (1) Polyvinyl chloride (PVC) (2) Polypropylene.

Answer

Based on structure polymers are classified as linear chain polymers, branched chain polymers and network or cross linked polymers.

(1) Linear chain polymers : When the monomer molecules are joined together in a linear arrangement, the resulting polymer is straight-chain or long-chain polymer, e.g., polythene, PVC.
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(2) Branched-chain polymers : These polymers consist of long and straight chain with smaller side chains give rise to branched-chain polymers. They have low density. They have lower melting points and tensile strength. Polypropylene having methyl groups as branches.
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(3) Network or cross-linked polymers : These polymers consist of cross-linking of chains by strong covalent bonds leading to a network-like structure. Cross-linking results from polyfunctional monomers, e.g., melamine, bakelite, vulcanization of rubber. These polymers are hard rigid and brittle.
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