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Write the significance/applications of dipole moment.

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Calculate the equilibrium constant for the following equilibrium system at 1120K.

$\text{C}(\text{s})+\text{CO}_2(\text{g})+2\text{Cl}_2\stackrel{\text{K}_\text{p}}{\rightleftharpoons}2\text{COCl}_2(\text{g})$

Given the following equations and equilibrium constants:

$\text{CO}(\text{s})+\text{Cl}_2(\text{g})\rightleftharpoons\text{COCl}_2(\text{g})$

$\text{Kp}_1 = 6.0 \times 10-3 \dots(1)$

$\text{CO}(\text{s})+\text{Cl}_2(\text{g})\rightleftharpoons\text{CO}_2(\text{g})$

$\text{Kp}_2 = 1.3 \times 1014 \dots(2)$

Each first element of a group differs in properties with other members of group. Explain the statement with reason.
or
In second period there is a difference between properties of elements. Why?
It has been found that the pH of a 0.01M solution of an organic acid is 4.15. Calculate the concentration of the anion, the ionization constant of the acid and its pKa.
6 An alkene 'A' contains three C-C, eight C–H $\sigma$ bonds and one C–C $\pi$ bond. ‘A’ on ozonolysis gives two moles of an aldehyde of molar mass 44 u. Write IUPAC name of 'A'.
Calculate the pH of a buffer which is 0.1M in acetic acid and 0.15M in sodium acetate. Given that the ionisation constants of acetic acid is 1.75 × 10-5. Also calculate the change in pH of the buffer if to 1L of the buffer (i) 1cc of 1M NaOH are added. (ii) 1cc of 1M HCl are added. Assume that the charge in volume is negligible. (iii) What will be the buffer index of the above buffer?
What is meant by the term average bond enthalpy? Why there is difference in bond enthalpy of O–H bond in ethanol (C2H5OH) and water?
Write balanced chemical equation for the following reactions:
Permanganate ion $(\text{MnO}^-_4)$ reacts with sulphur dioxide gas in acidic medium to produce Mn2+ and hydrogensulphate ion.
(Balance by ion electron method)
At a certain temperature and total pressure of 10Pa, iodine vapour contains 40% by volume of I atoms $\text{I}_2\text{(g)}\rightleftharpoons2\text{I}\text{(g)}$ Calculate Kp for the equilibrium.
Calculate the degree of ionization of 0.05 M acetic acid if its $pK _{ a }$ value is 4.74 . How is the degree of dissociation affected when its solution also contains
a. 0.01 M
b. $0.1 M HCl ?$
  1. Commercially available concentrated hydrochloric acid contains 45% HCl by mass.
  1. What is the molarity of this solution? The density is 1.19g mL.
  2. What volume of cone. HCl is required to make 1.00L of 0.24M HCl?
  1. Write the balanced chemical equations for the following:
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  2. HNO3 + P→ NO2 + H3PO4 + H2O