c This reaction is carbylamine reaction. This reaction produces poisons foul smell isocyanide this test is given by $1^{\circ}$ amines only. In this reaction $3$ moles of $KOH$ is required.
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Assertion : Acetamide reacts with $Br_2$ in presence of methanolic $CH_3ONa$ to form methyl $N-$ methylcarbamate.
Reason : Methyl isocyanate is formed as an intermediate which reacts with methanol to form methyl $N-$ methylcarbamate.