Questions · Page 2 of 2

1 Marks Question

Question 541 Mark
What are glycosidic linkages? In which type of biomolecules are they present?
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Question 561 Mark
Why must vitamin C be supplied regularly in diet?
Answer
Vitamin C are soluble in water. Water soluble vitamins must be supplied regularly in diet because they are readily excreted in urine and cannot be stored in our body.
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Question 571 Mark
How do enzymes help a substrate to be attacked by the reagent effectively?
Answer
Enzymes arehighly specific. They react with substrate molecule and form intermediate complex. They reduce the magnitude of activation energy.
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Question 581 Mark
Why is cellulose not digested in human body?
Answer
It is due to the fact that human beings do not have enzyme to digest cellulose.
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Question 591 Mark
Answer the following questions.
Which of the following biomolecules is insoluble in water? Justify. Insulin, Haemoglobin, Keratin.
Answer
Keratin being a fibrous protein insoluble in water.
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Question 601 Mark
Write biological importance of nucleic acid.
Answer
  1. To transmit genetic material to their offsprings.
  2. Protein synthesis.
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Question 611 Mark
What are oligosaccharides?
Answer
Carbohydrates which on hydrolysis give 2-10 molecules of monosaccharides are called oligosaccharides. For example, sucrose, raffinose, stachyose, etc.
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Question 621 Mark
How do you explain the presence of five —OH groups in glucose molecule?
Answer
Glucose gives penta-acetyl derivative on acetylation with acetic anhydride.
$\text{CHO}| (\text{CHOH})_4|\text{CH}_2\text{OH}|\text{CH}_2\text{OH}\xrightarrow{\ \ \ \ \ \ \ \ \ }\text{CHO}|(\text{CHOCOCH}_3)_4|\text{CH}_2\text{OH}_2\text{OCOCH}_3$
This confirms the presence of five -OH groups.
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Question 631 Mark
Monosaccharides contain carbonyl group hence are classified, as aldose or ketose. The number of carbon atoms present in the monosaccharide molecule are also considered for classification. In which class of monosaccharide will you place fructose?
Answer
Monosaccharides contain carbonyl group. Hence, are classified as aldose or ketose.
When aldehyde group is present, the monosaccharides are known as aldose. When ketone group is present, the monosaccharides are known as ketose. Fructose has molecular formula C6H12O6 containing six carbon and keto group and is classified as ketohexose.

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Question 641 Mark
The letters ‘D’ or ‘L’ before the name of a stereoisomer of a compound indicate the correlation of configuration of that particular stereoisomer. This refers to their relation with one of the isomers of glyceraldehyde. Predict whether the following compound has ‘D’ or ‘L’ configuration.

Answer
The letters ‘D’ or ‘L’ before the name of any compound indicate the relative configuration of a particular stereoisomer. This refers to their relation with a particular isomer of glyceraldehydes.
D’ before the name of glucose represents the configuration whereas ‘(+)’ represents dextrorotatory nature of the molecule. It may be remembered that ‘D’ and ‘L’ have no relation with the optical activity of the compound. For assigning the configuration of monosaccharides, it is the lowest asymmetric carbon atom which is compared. The given compound has L-configuration.
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Question 661 Mark
Under what conditions glucose is converted to gluconic and saccharic acid?
Answer
Glucose is converted to gluconic acid by Br2 water and to saccharic acid by cone HNO3.
$\ \text{CHO} \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \text{COOH} \\ \ \ {|} \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ {|} \\ \text{(CHOH)}_4 + \text{O} \xrightarrow{\text{Br}_2/\text{H}_2\text{O}}(\text{CHOH})_4\\ \ \ {|} \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ {|} \\ \ \text{CH}_2\text{OH} \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \text{CH}_2\text{OH} \\ \text{Glucose} \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \text{Gluconoc acid}$
$\ \text{CHO} \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \text{COOH} \\ \ \ {|} \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ {|} \\ \text{(CHOH)}_4 +3[ \text{O}] \xrightarrow{\text{Br}_2/\text{H}_2\text{O}}(\text{CHOH})_4\\ \ \ {|} \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ {|} \\ \ \text{CH}_2\text{OH} \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \text{CH}_2\text{OH} \\ \text{Glucose} \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \text{Saccharic acid}$
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Question 691 Mark
How do you explain the presence of an aldehydic group in a glucose molecule?
Answer
Glucose gets oxidised to six carbon carboxylic acid (gluconic acid) on reaction with a mild oxidising agent like bromine water. This indicates that the carbonyl group is present as an aldehydic group.
$\ \text{CHO} \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \text{COOH} \\ \ \ {|} \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ {|} \\ \text{(CHOH)}_4 \xrightarrow{\text{Br}_2/\text{H}_2\text{O}}(\text{CHOH})_4\\ \ \ {|} \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ {|} \\ \ \text{CH}_2\text{OH} \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \text{CH}_2\text{OH} \\ \text{Glucose} \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \text{Glucose acid}$
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Question 711 Mark
Name the sugar present in milk. How many monosaccharide units are present in it? What are such oligosaccharides called?
Answer
Lactose is present in milk. Two monosaccharide units (i.e., glucose and galactose) are present in it. Such oligosaccharides are called disaccharides.
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Question 721 Mark
In nucleoside a base is attached at 1′ position of sugar moiety. Nucleotide is formed by linking of phosphoric acid unit to the sugar unit of nucleoside. At which position of sugar unit is the phosphoric acid linked in a nucleoside to give a nucleotide?
Answer
Phosphoric acid unit is linked preferably at 5′-position of sugar moiety of a nucleoside to give a nucleotide.

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Question 731 Mark
Aldopentoses named as ribose and 2-deoxyribose are found in nucleic acids. What is their relative configuration?
Answer
Configuration assigned is O. Thus, ribose is $\beta-$D-ribose Deoxyribose is $\beta-$D-2-deoxyribose.
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Question 741 Mark
Write IUPAC names of the following compounds and classify them into primary, secondary and tertiary amines.
(CH3)3CNH2
Answer
(CH3)3CNH2
Tert-butylamine (primary amine)
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Question 751 Mark
Answer the following questions.
Name the protein and its shape present in oxygen carrier in human body.
Answer
Globular protein and its shape is spherical.
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Question 781 Mark
Why does compound (A) given below not form an oxime?

Answer
Glucose pentaacetate (structure A) doesn’t have a free —OH group at C1 and so can’t be converted to the open chain form to give —CHO group and hence doesn’t form the oxime.

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Question 791 Mark
Name two of the different types of RNA molecules found in the cells of organisms.
Answer
Messenger RNA (mRNA) and transfer RNA (tRNA).
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Question 801 Mark
Among the amino acids phenylalanine, glutamine and alanine which one is an essential amino acid?
Answer
Phenylalanine is an essential amino acid.
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Question 811 Mark
Some enzymes are named after the reaction, where they are used. What name is given to the class of enzymes which catalyse the oxidation of one substrate with simultaneous reduction of another substrate?
Answer
Oxidoreductase is class of enzymes which catalyse the oxidation of one substrate with simultaneous reduction of another substrate.
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Question 821 Mark
Write IUPAC names of following and classify them into primary, secondary, tertiary amines:
CH3NHCH(CH3)2
Answer
CH3NHCH(CH3)2
Methyl isopropyl amine (secondary)
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Question 831 Mark
Which moieties of nucleosides are involved in the formation of phosphodiester linkages present in dinucleotides? What does the word diester in the name of linkage indicate? Which acid is involved in the formation of this linkage?
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Question 841 Mark
How do you explain the presence of all the six carbon atoms in glucose in a straight chain?
Answer
On prolonged heating with HI, glucose gives n-hexane.
$\text{Glucose}\ \xrightarrow{\ \ \ \ \ \ \ \ \ \ \text{HI} }\text{CH}_{3}-\text{CH}_{2}-\text{CH}_{2}-\text{CH}_{2}-\text{CH}_{3}$
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Question 871 Mark
Activation energy for the acid catalysed hydrolysis of sucrose is 6.22kJ mol–1, while the activation energy is only 2.15kJ mol–1 when hydrolysis is catalysed by the enzyme sucrase. Explain.
Answer
Enzymes are biocatalysts. They reduce the magnitude of activation energy by providing alternative path. In the hydrolysis of sucrose, the enzyme sucrase reduces the activation energy from 6.22kJ mol-1 to 2.15kJ mol-1. As a result, enzyme catalysed reactions occur at a much faster rate than the ordinary chemical reactions using conventional catalysts.
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Question 901 Mark
Structures of glycine and alanine are given below. Show the peptide linkage in glycylalanine.
$\text{H}_{2}\text{N}-\text{CH}_{2}-\text{COOH} :\text{H}_2\text{N}-\text{CH}_2-\text{COOH}\\\\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ |\\\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \text{CH}_3$
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Question 941 Mark
Name the molecule which provides energy for all the activities of a cell.
Answer
Adenosine triphosphate (ATP).
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Question 951 Mark
During curdling of milk, what happens to sugar present in it?
Answer
When milk is curdeled, its sugar get oxidize to form lactic acid.
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Question 961 Mark
$\alpha-$Helix is a secondary structure of proteins formed by twisting of polypeptide chain into right handed screw like structures. Which type of interactions are responsible for making the $\alpha-$helix structure stable?
Answer
In $\alpha-$helix, apolypeptide chain is stabilized by the formation of hydrogen bonds between NH— group of amino acids in one turn with the >C —O groups of amino acids belonging to adjacent turn.
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1 Marks Question - Page 2 - Chemistry STD 12 Science Questions - Vidyadip