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M.C.Q [1M]

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MCQ 21 Mark
What is the molality of an aqueous solution,whose relative lowering of vapour pressure is 0.1
  • A
    2m
  • B
    2.75m
  • C
    3.25m
  • D
    5.56m
Answer
  1. 5.56m
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MCQ 31 Mark
When two perfect solutions with volume V each are combined, What is the volume of the solution as a result?
  • A
    V
  • B
    2V
  • C
    Greater than 2V
  • D
    Less than 2V
Answer
  1. 2V

Explanation:

When two perfect solutions are mixed, there is no change in volume.

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MCQ 41 Mark
The volume occupied by a single gas in a mixture at the same temperature and pressure is referred to as the single - gas volume.
  • A
    Absolute volume
  • B
    Partial volume
  • C
    Total volume of a gas mixture
  • D
    None of the mentioned
Answer
  1. Partial volume

Explanation:

At the same temperature and pressure, the volume occupied by a single gas alone in a combination is a portion of a volume.

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MCQ 51 Mark
Considering the formation, breaking and strength of hydrogen bond, predict which of the following mixtures will show a positive deviation from Raoult’s law?
  • A
    Methanol and acetone.
  • B
    Chloroform and acetone.
  • C
    Nitric acid and water.
  • D
    Phenol and aniline.
Answer
  1. Methanol and acetone.

Explanation:

Mixture of Methanol and acetone shows positive deviation because methanol-methanol and acetone-acetone interactions are more than methanol-acetone. The more number of hydrogen bonds are broken the less number of new H-bonds are formed.

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MCQ 61 Mark
When 1 mole of a substance is present in 1L of the solution, it is known as :
  • A
    Normal solution
  • B
    Molar solution
  • C
    Molal solution
  • D
    None of the above
Answer
  1. Molar solution

Explanation:

Molar concentration is a measure of the concentration of a solute in a solution and its unit is mol L−1. Molarity is a method to express the concentration of a solution. It is defined as the number of moles of solute dissolved per liter of solution.

Hence, when 1 mole of a substance is present in 1L of the solution, it is known as a molar solution.

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MCQ 71 Mark
The vapour pressure of a dilute solution of a solute is not influenced by:
  • A
    Temperature of solution
  • B
    Melting point of solute
  • C
    Mole fraction of solute
  • D
    Degree of dissociation of solute
Answer
  1. Melting point of solute

Explanation:

Vapour pressure of a dilute solution depends upon the temperature, mole fraction, and degree of dissociation of solute and independent of the melting point of solute.

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MCQ 81 Mark
Which has the lowest boiling point at 1atm pressure?
  • A
    0.1 M KCl
  • B
    0.1 M Urea
  • C
    0.1 M CaCl2
  • D
    0.1 M A1Cl3
Answer
  1. 0.1 M Urea
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MCQ 91 Mark
A solution containing 10.2g glycerine per litre is isotonic with a 2% solution of glucose. What is the molecular mass of glycerine?
  • A
    91.8g
  • B
    1198g
  • C
    83.9g
  • D
    890.3g
Answer
  1. 91.8g
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MCQ 101 Mark
The mass of a non - volatile non - electrolyte solute (molar mass = 50g mol−1) needed to be dissolved in 114g octane to reduce its vapour pressure to 75% is:
  • A
    37.5g
  • B
    75g
  • C
    150g
  • D
    50g
Answer
  1. 150g
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MCQ 111 Mark
 When a solute is present in trace quantities the following expression is used:
  • A
    Gram per million
  • B
    Milligram percent
  • C
    Microgram percent
  • D
    Parts per million
Answer
  1. Parts per million
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MCQ 131 Mark
A concentrated solution contains high amount of ________:
  • A
    Solvent
  • B
    Solute
  • C
    Both solute and solvent
  • D
    None of these
Answer
  1. Solute

Explanation:

A concentrated solution contains the maximum amount of solute that can be dissolved because solubility depends on temperature, a solution that is concentrated at one temperature may not be concentrated at a higher temperature.

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MCQ 141 Mark
1M, 2.5 litre NaOH solution is mixed with another 0.5M, 3 litre NaOH solution. Then find out the molarity of resultant solution:
  • A
    0.80M
  • B
    1.0M
  • C
    0.73M
  • D
    0.50M
Answer
  1. 0.73M
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MCQ 151 Mark
Identify which of the following statements is FALSE.
  • A
    The vapor pressure of a liquid decreases with increasing atmospheric pressure.
  • B
    The value of an equilibrium constant is dependent on temperature.
  • C
    The rate of a spontaneous reaction cannot be determined solely by its Gibbs free energy.
  • D
    During a phase transition, the temperature of a substance must be constant.
Answer
  1. During a phase transition, the temperature of a substance must be constant.

Explanation:

During phase transition, temperature is taken on the x-axis of the phase transition curve, hence, during phase transition the temperature of substance changes.

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MCQ 161 Mark
Equipment needed for measuring the vapour pressure of a liquid:
  • A
    Buret
  • B
    Calorimeter
  • C
    Manometer
  • D
    Voltmeter
Answer
  1. Manometer

Explanation:

A Manometer is a device to measure pressures. A common simple manometer consists of a U shaped tube of glass filled with some liquid. Typically the liquid is mercury because of its high density.

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MCQ 171 Mark
A solution made up of numerous components in which each component’s property is the weighted sum of its separate properties. The answer is:
  • A
    Ideal Solution
  • B
    Non - Ideal solution
  • C
    Real Solution
  • D
    None of the mentioned
Answer
  1. Ideal Solution

Explanation:

An ideal solution is made up of numerous components, each of which has a property that is the weighted sum of the attributes of the others.

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MCQ 181 Mark
The values of Van’t Hoff factors for KCl, NaCl and K2SO4, respectively, are __________.
  • A
    2, 2 and 2
  • B
    2, 2 and 3
  • C
    1, 1 and 2
  • D
    1, 1 and 1
Answer
  1. 2, 2 and 3

Explanation:

KCl (K+ + Cl) and NaCl(Na+ + Cl) ionize to give 2 ions and K2SO4(2K+ + SO-4) ionizes to give 3 ions thus, van’t Hoff factors for KCl, NaCl and K2SOare 2, 2 and 3 respectively.

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MCQ 191 Mark
Which of the following are true solutions?
  • A
    ENO salt in water
  • B
    Tomato soup
  • C
    Aam panna
  • D
    Filtered black tea
Answer
  1. ENO salt in water

Explanation:

The definition of true solution is a homogeneous mixture of two or more substances in which substance dissolved (solute) in solvent has the size of the particle less than 10−9m or 1nm. So the perfect example of true solution is ENO salt in water. ENO is perfectly soluble in water and has minimum size.

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MCQ 201 Mark
Vant Hoff factor for a dilute solution of glucose is:
  • A
    0
  • B
    1
  • C
    1.5
  • D
    2
Answer
  1. 1

Explanation:

Solution of glucose is a non-electrolytic solution.

For a non - electrolytic solution, vant hoff factor is 1.

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MCQ 211 Mark
Partial pressure of a solution component is directly proportional to its mole fraction. This is known as:
  • A
    Henry’s law
  • B
    Raoult’s law
  • C
    Distribution law
  • D
    Ostawald’s dilution law
Answer
  1. Raoult’s law
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MCQ 231 Mark
H2S is a toxic gas used in qualitative analysis. If solubility of H2S in water at STP is 0.195m. what is the value of KH?
  • A
    0.0263 bar
  • B
    69.16 bar
  • C
    192 bar
  • D
    282 bar
Answer
  1. 282 bar
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MCQ 241 Mark
The possible van't Hoff factor for sodium chloride in water assuming sodium chloride is partially ionized:
  • A
    0.5
  • B
    0.75
  • C
    2.5
  • D
    1.5
Answer
  1. 1.5
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MCQ 251 Mark
3 moles of P and 2 moles of Q are mixed, what will be their total vapour pressure in the solution if their partial vapour pressures are 80 and 60 torr respectively?
  • A
    80 torr
  • B
    140 torr
  • C
    72 torr
  • D
    70 torr
Answer
  1. 72 torr
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MCQ 261 Mark
The system that forms maximum boilingazetrope is:
  • A
    Acetone - chloroform
  • B
    Ethanol - acetone
  • C
    N - hexane - n - heptane
  • D
    Carbon disulphide - acetone
Answer
  1. Acetone - chloroform
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MCQ 271 Mark
On the basis of information given below mark the correct option.

Information:

  1. In bromoethane and chloroethane mixture intermolecular interactions of A–A and B–B type are nearly same as A–B type interactions.
  2. In ethanol and acetone mixture A–A or B–B type intermolecular interactions are stronger than A–B type interactions.
  3. In chloroform and acetone mixture A–A or B–B type intermolecular interactions are weaker than A–B type interactions.
    • A
    • Solution (B) and (C) will follow Raoult’s law.
  1. B
  2. Solution (A) will follow Raoult’s law.
  3. C
  4. Solution (B) will show negative deviation from Raoult’s law.
  5. D
  6. Solution (C) will show positive deviation from Raoult’s law.
  7. Answer
    1. Solution (A) will follow Raoult’s law.

    Explanation:

    For an ideal solution A-A and B-Bintermolecular interactions should be nearly same as A-B type interactions.

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    MCQ 281 Mark
    People add sodium chloride to water while boiling eggs. This is to:
    Answer
    1. Increase the boiling point.
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    MCQ 291 Mark
    The pressure that a single component in a gaseous mixture would exert if it existed alone in the same volume as the mixture and at the same temperature as the mixture is referred to as.
    Answer
    1. Partial pressure

    Explanation:

    Partial pressure is the pressure exerted by a single component in a gaseous mixture if it exists alone in the same volume.

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    MCQ 301 Mark
    When a solution containing non - volatile solute is diluted with water,
    Answer
    1. Its boiling point increases.
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    MCQ 311 Mark
    234.2gm of sugar syrup contains 34.2gm of sugar. What is the molal concentration of the solution.
    Answer
    1. 0.5
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    MCQ 321 Mark
    Most of the processes in our body occur in:
    Answer
    1. Liquid solution
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    MCQ 331 Mark
    When a solution is diluted at constant temperature, its vapour pressure:
    Answer
    1. Increases

    Explanation:

    When a solution is diluted at a constant temperature, its vapour pressure increases.

    When the solution is diluted, the mole fraction of solute decreases and the mole fraction of solvent increases. 

    Hence, the relative lowering in vapour pressure decreases and the vapor pressure increases.

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    MCQ 341 Mark
    The vapour pressure of water at 300K in a closed container is 0.4 atm. If the volume of the container is doubled, its vapour pressure at 300K will be:
    Answer
    1. 0.4 atm

    Explanation:

    Vapour pressure will be the same because it doesn't depend on the volume it depends only on Temperature.

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    MCQ 351 Mark
    Which of the following property indicates weak intermolecular forces of attraction in liquid?
    Answer
    1. High vapour pressure

    Explanation:

    The molecules that are having weak intermolecular forces of attraction, they can easily dissociate and convert into vapour state, so, molecules with weak intractions have high vapour pressure.

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    MCQ 361 Mark
    In an endothermic process, solubility increases with ______ in temperature:
    Answer
    1. Increase

    Explanation:

    The effect of temperature on solubility depends on the type of reaction that occurs during the process of dissolving the solute in the solvent. In endothermic reactions, increasing the temperature increases the solubility of the solute in a solution. In exothermic reactions, increasing the temperature decreases the solubility of the solute.

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    MCQ 371 Mark
    Among the following substances the lowest vapour pressure is exerted by:
    Answer
    1. Mercury
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    MCQ 381 Mark
    Sprinkling of salt helps in clearing the snow covered roads in hills. The phenomenon involved in the process is:
    Answer
    1. Depression in freezing point of snow.
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    MCQ 391 Mark
    If PCl5​ is 80% dissociated at 250 then its vapour density at room temperature will be:
    Answer
    1. 104.25
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    MCQ 401 Mark
    The molal elevation constant depends upon:
    Answer
    1. Nature of the solvent.
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    MCQ 411 Mark
    Which salt may show the same value of van't Hoff factor (i) as that of K4​Fe(CN)6​ in very dilute solution state?
    Answer
    1. Al2​(SO4​)3​
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    MCQ 421 Mark
    If 2gm of NaOH is present is 200ml of its solution, its molarity will be:
    Answer
    1. 0.25
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    MCQ 431 Mark
    Which of the following binary mixtures will have same composition in liquid and vapour phase?
    Answer
    1. Water-Nitric acid.
    2. Water-Ethanol.

    Explanation:

    Non-ideal solution mixtures with same composition in liquid and vapour phase are azeotropes. Water-nitric acid has maximum boiling azeotrope and water-ethanol has a minimum boiling azeotrope.

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    MCQ 441 Mark
    At a certain temperature, the vapour pressure of water is 50mm. The relative lowering of vapour pressure of a solution containing 36g of glucose in 900g of water is:
    Answer
    1. 0.004
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    MCQ 451 Mark
    When heating of a miscible solution begins, vapours formed will be:
    Answer
    1. Of both liquids with a higher concentration of liquid having low boiling point

    Explanation:

    When heating begins in miscible solutions, vapours will be of both liquids with a higher concentration of liquid having a low boiling point (since that component will be more volatile in nature).

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    MCQ 461 Mark
    What weight of glycerol should be added to 600g of water in order to lower its freezing point by 10°C?
    Answer
    1. 297g
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    MCQ 471 Mark
    Which of the following solutions shows positive deviation from Raoult’s law?
    Answer
    1. Acetone + Ethanol
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    MCQ 481 Mark
    Which characteristic the weak intermolecular forces of attraction in a liquid?
    Answer
    1. High vapour pressure

    Explanation:

    High vapour pressure leads to the weak intermolecular forces of attraction in a liquid.Weaker are the intermolecular forces of attractions, more is the tendency for evaporation, more is vapour pressure, lower is boiling point.

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    MCQ 491 Mark
    The correct statement among the following is:
    Answer
    1. Smoke is carbon dispersed in air.

    Explanation:

    Smoke is carbon (solid particle) dispersed in air. It is the type of solid in gas type of solution.

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    MCQ 501 Mark
    The atmospheric pollution is generally measured in the units of:
    Answer
    1. ppm
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