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M.C.Q (1 Marks)

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35 questions · timed · auto-graded

MCQ 21 Mark
If the concentration of $Zn ^{+2}$ and $Cu ^{+2}$ ions in Daniell cell is one unit ( 1 mole $dm ^{-3}$ ), then the value of electric potential will be :
  • A
    0.00 V
  • 1.10 V
  • C
    1.35 V
  • D
    2.00 V
Answer
Correct option: B.
1.10 V
b
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MCQ 31 Mark
The reaction
$
\frac{1}{2} H_{2(g)}+AgCl_{(aq)} \rightleftharpoons H_{(aq)}^{+}+Cl_{(aq)}^{-}+Ag_{(s)}
$ takes place in a galvanic cell. Its correct representation is :
  • A
    $Ag / AgCl _{\text {(s) }} / KCl _{( aq )} / / AgNO _{3( aq )} / Ag _{\text {(s) }}$
  • B
    $Pt , H _{2(g)} / HCl _{( aq )} / / AgNO _{3( aq } / Ag _{( s )}$
  • $Pt , H _{2(g)} / HCl _{\text {(aq) }} / / AgCl _{( aq )} / Ag _{\text {(s) }}$
  • D
    $Pt , H _{2(g} / KCl _{\text {(qq })} / / AgCl _{\text {(s) }} / Ag$
Answer
Correct option: C.
$Pt , H _{2(g)} / HCl _{\text {(aq) }} / / AgCl _{( aq )} / Ag _{\text {(s) }}$
c
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MCQ 41 Mark
The standard electrode potential values of three metallic cations $X , Y , Z$ are, $0.52 V,-3.03 V$ and -1.18 V respectively. The order of reducing ability of corresponding metal is :
  • Y $>$ Z $>$ X
  • B
    $X >$ Y $>$ Z
  • C
    $Z>Y>X$
  • D
    $Z>X>Y$
Answer
Correct option: A.
Y $>$ Z $>$ X
a
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MCQ 51 Mark
At $25^{\circ} C$, the standard electromotive force of $Zn +$ $Cu ^{2+} \rightarrow Cu + Zn ^{2+}$ is 1.10 , then on using $0.1 M Cu ^{2+}$ and $0.1 M Zn ^{2+}$ solution in this cell, the electromotive force of the cell will be :
  • 1.10 V
  • B
    +0.110 V
  • C
    -1.10 V
  • D
    -0.11 V
Answer
Correct option: A.
1.10 V
a
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MCQ 61 Mark
For $Zn - Cu$ cell, $E ^{\circ}=1.10 V$. If the reduction potential $\left[ Cu ^{2+}{ }_{( aq )} / Cu _{( s )}\right]$ pair is 0.34 V , then the reduction potential of $\left[ Zn ^{2+}{ }_{(a q)} / Zn _{( s )}\right]$ pair will be :
  • -0.76 V
  • B
    0.76 V
  • C
    7.6 V
  • D
    0.38 V
Answer
Correct option: A.
-0.76 V
a
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MCQ 71 Mark
If the cell reaction is spontaneous, then :
  • A
    $E ^{\circ}=- ve$
  • B
    $E ^{\circ}=+ ve$
  • $emf =+ ve$
  • D
    $\left(\Delta G + E ^{\circ}\right)=+ ve$
Answer
Correct option: C.
$emf =+ ve$
c
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MCQ 81 Mark
Saturated solution of $KNO _3$ used in salt bridge because :
  • A
    $KNO _3$ has high solubility in water
  • The speed of $K ^{+}$and $NO _3{ }^{-}$is almost same
  • C
    The speed $K ^{+}$is more than that of $NO _3^{-}$
  • D
    The speed of $K ^{+}$is less than that of $NO _3$
Answer
Correct option: B.
The speed of $K ^{+}$and $NO _3{ }^{-}$is almost same
b
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MCQ 91 Mark
For any spontaneous reaction, the equilibrium constant, $E _{\text {cell }}^{\circ}$ and $\Delta G$ respectively will be :
  • A
    $<1,+$ ve, - ve
  • $>1,+v e,-v e$
  • C
    $=1,+ ve ,+ ve$
  • D
    $=1,- ve ,- ve$
Answer
Correct option: B.
$>1,+v e,-v e$
b
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MCQ 101 Mark
At the equilibrium state of any cell reaction, the electromotive force (EMF) of the cell is :
  • A
    Positive
  • Zero
  • C
    Negative
  • D
    None of these
Answer
Correct option: B.
Zero
b
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MCQ 111 Mark
Cell constant is determined by measuring the conductivity of aqueous solution of which substance?
  • A
    NaCl
  • B
    $CaCl _2$
  • KCl
  • D
    $MgCl _2$
Answer
Correct option: C.
KCl
c
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MCQ 121 Mark
The reaction taking place at cathode in a fuel cell made of $H _2$ and $O _2$ is :
  • A
    $2 H _{2(g)}+4 OH _{\text {(aq) }}^{-} \rightarrow 4 H _2 O _{(f)}+4 e ^{-}$
  • B
    $2 H _{2(g)}+ O _{2(g)} \rightarrow 2 H _2 O _{\text {(l) }}$
  • $O _{2(g)}+2 H _2 O _{( l )}+4 e ^{-} \rightarrow 4 OH _{\text {(aq) }}^{-}$
  • D
    $4 OH _{( aq )}^{-} \rightarrow O _{2(g)}+2 H _2 O _{( l )}+4 e ^{-2}$
Answer
Correct option: C.
$O _{2(g)}+2 H _2 O _{( l )}+4 e ^{-} \rightarrow 4 OH _{\text {(aq) }}^{-}$
c
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MCQ 131 Mark
The reaction taking place at the anode in lead accumulator cell is :
  • A
    $PbO _{2(s)} \rightarrow PbSO _{4(s)}$
  • B
    $PbSO _{4(s)} \rightarrow PbO _{2(s)}$
  • $Pb _{( s )}+ SO _{4( aq )}^{2-} \rightarrow PbSO _{4(s)}+2 e ^{-}$
  • D
    $Pb _{( s )}+ PbO _{2(s)}+2 H _2 SO _{4( aq )} \rightarrow 2 PbSO _{4( aq )}+2 H _2 O _{(l)}$
Answer
Correct option: C.
$Pb _{( s )}+ SO _{4( aq )}^{2-} \rightarrow PbSO _{4(s)}+2 e ^{-}$
c
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MCQ 141 Mark
The formula for conductivity of a solution is :
  • A
    $\kappa=\frac{G}{R}$
  • B
    $\kappa=\frac{l}{A}$
  • $\kappa=\frac{\text { Cell constant }\left( G ^{\circ}\right)}{( R )}$
  • D
    None of the above.
Answer
Correct option: C.
$\kappa=\frac{\text { Cell constant }\left( G ^{\circ}\right)}{( R )}$
(c)
$\kappa=\frac{\text { Cell constant }\left( G ^{\circ}\right)}{( R )}$
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MCQ 151 Mark
Electronic conductivity depends on which of the following:
  • A
    Nature and structure of metal
  • B
    Heat
  • C
    Number of valence electrons per atom
  • All of the above.
Answer
Correct option: D.
All of the above.
d
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MCQ 161 Mark
Which of the following has the highest conductivity?
  • A
    Sodium
  • Silver
  • C
    Gold
  • D
    Copper
Answer
Correct option: B.
Silver
b
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MCQ 171 Mark
The inverse of resistance is :
  • A
    Resistivity
  • Conductance
  • C
    Cell constant
  • D
    Conductivity
Answer
Correct option: B.
Conductance
b
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MCQ 181 Mark
The metabolic reaction used in Daniell cell is :
  • A
    $Zn _{( s )}+ Cu _{( s )} \rightarrow Zn _{( aq )}^{2+}+ Cu _{( sq )}^{2+}$
  • B
    $Zn _{\text {(s) }} \rightarrow Zn _{\text {(aq) }}^{2+}+2 e ^{-}$
  • $Zn _{( s )}+ Cu _{\text {(aq) }}^{2+} \rightarrow Zn _{( sq )}^{2+}+ Cu _{( s )}$
  • D
    $Cu _{( s )}+ Zn _{( aq )}^{2+} \rightarrow Cu _{( aq )}^{2+}+ Zn _{( s )}$
Answer
Correct option: C.
$Zn _{( s )}+ Cu _{\text {(aq) }}^{2+} \rightarrow Zn _{( sq )}^{2+}+ Cu _{( s )}$
c
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MCQ 191 Mark
In which of the following conditions does the molar conductivity of the solution increase?
  • A
    On increasing the concentration
  • B
    On reducing the temperature
  • On increasing dilution
  • D
    None of the above.
Answer
Correct option: C.
On increasing dilution
c
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MCQ 201 Mark
What will be the products obtained at anode and cathode during electrolysis of dilute aqueous solution of $Na _2 SO _4$ ? If Pt electrode is used.
  • A
    $O _2, Na$
  • B
    $H _2, NaOH$
  • $O _2, H _2$
  • D
    $S _2 O _8^{-2}, H _2$
Answer
Correct option: C.
$O _2, H _2$
c
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MCQ 211 Mark
The charge required for reduction of 1 mole of $MnO _2$ of $MnO _4^{-}$:
  • A
    1 F
  • 3 F
  • C
    5 F
  • D
    7 F
Answer
Correct option: B.
3 F
b
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MCQ 221 Mark
The best way to prevent rusting of iron is :
  • A
    By keeping in salt water
  • Cathodic protection
  • C
    By coating with tin
  • D
    By keeping in ordinary water
Answer
Correct option: B.
Cathodic protection
b
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MCQ 231 Mark
The charge (in coulomb) on $Cu ^{2+}$ ion is :
  • A
    96500
  • B
    57900
  • C
    $1.6 \times 10^{-19}$
  • $3.2 \times 10^{-19}$
Answer
Correct option: D.
$3.2 \times 10^{-19}$
d
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MCQ 241 Mark
The carriers of charge in a metallic conductor are :
  • Electron
  • B
    Ion
  • C
    Proton
  • D
    Salt
Answer
Correct option: A.
Electron
a
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MCQ 251 Mark
Electrode potential of a standard hydrogen electrode is :
  • A
    1.0 V
  • 0.0 V
  • C
    1.10 V
  • D
    0.20 V
Answer
Correct option: B.
0.0 V
b
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MCQ 261 Mark
What the emf of a galvanic cell mode of $Zn ^{2+}\left| Zn \left( E ^{\circ}=-0.76 V\right) \& Cu ^{2+}\right| Cu \left( E ^{\circ}=+0.34\right) ?$
  • A
    0.42 V
  • 1.10 V
  • C
    -0.10 V
  • D
    -0.42 V
Answer
Correct option: B.
1.10 V
b
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MCQ 271 Mark
The products obtained from electrolysis of molten NaCl are :
  • A
    $NaOH , H _2$ and $Cl _2$
  • Na and $Cl _2$
  • C
    $Na , NaOH$ and $Cl _2$
  • D
    All of these
Answer
Correct option: B.
Na and $Cl _2$
b
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MCQ 281 Mark
Which of the following will disintegrate when electric current is passed through its aqueous solution?
  • A
    Glucose
  • B
    Urea
  • C
    Sugar
  • Silver nitrate
Answer
Correct option: D.
Silver nitrate
d
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MCQ 291 Mark
Copper can be precipitated with acidic $CuSO _4$ and alkaline $Cu ( CN )_2$. If the same electric current is passed through their solution for the same time, which of the statement is true?
  • A
    Copper deposited from $Cu ( CN )_2$ alkaline copper cyanide will be twice that of acidic $CuSO _4$.
  • B
    The amount of copper deposited from alkaline copper cyanide will be half that of acidic $CuSO _4$.
  • Equal amount of copper deposited from both the solutions.
  • D
    All of the above statements are wrong.
Answer
Correct option: C.
Equal amount of copper deposited from both the solutions.
c
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MCQ 301 Mark
What does the two vertical parallel lines $(|\mid)$ represent in :
$
Zn_{(s)}\left|Zn_{(aq)}^{+2} \| Cu_{(sq)}^{2+}\right| Cu
$
  • A
    Cathode
  • B
    Anode
  • Salt bridge
  • D
    Electrolyte
Answer
Correct option: C.
Salt bridge
c
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MCQ 311 Mark
Colourless solution of different salts are present in four separate test tubes. Which solution will turn blue when a copper rod is dipped in it?
  • A
    $Pb \left( NO _3\right)_2$
  • $AgNO _3$
  • C
    $Zn \left( NO _3\right)_2$
  • D
    $Cd \left( NO _3\right)_2$
Answer
Correct option: B.
$AgNO _3$
b
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MCQ 321 Mark
On charging the lead accumulator cell :
  • A
    $PbO _2$ dissolves
  • B
    $PbSO _4$ deposits on the lead electrode
  • $H _2 SO _4$ is formed again
  • D
    The amount of $H _2 SO _4$ is less
Answer
Correct option: C.
$H _2 SO _4$ is formed again
c
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MCQ 331 Mark
The unit of specific conductivity is :
  • A
    $S cm ^2 mol^{-1}$
  • B
    $S cm ^2$
  • $S m ^{-1}$
  • D
    $cm ^{-1}$
Answer
Correct option: C.
$S m ^{-1}$
c
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MCQ 341 Mark
The Nernst reaction for the electrode reaction is $M _{( aq )}^{ n +}+ ne ^{-} \rightarrow M _{( s )}$ :
  • A
    $E = E ^{\circ}+\frac{ RT }{ nF } \ln \frac{1}{\left[ M ^{ n +}\right]}$
  • $E = E ^{\circ}+\frac{ RT }{ nF } \ln \left[ M ^{ n +}\right]$
  • C
    $E = E ^{\circ}+ RT \ln \left[ M ^{\star+}\right]$
  • D
    $\frac{E}{ E ^{\circ}}=\frac{ RT }{ nF } \ln \left[ M ^{ n +}\right]$
Answer
Correct option: B.
$E = E ^{\circ}+\frac{ RT }{ nF } \ln \left[ M ^{ n +}\right]$
b
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MCQ 351 Mark
Which statement is not true for galvanic cell?
  • A
    The anode is negatively charged
  • B
    The cathode is positively charged
  • Reduction occurs at the anode
  • D
    Reduction takes place at cathode.
Answer
Correct option: C.
Reduction occurs at the anode
c
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M.C.Q (1 Marks) - Chemistry STD 12 Science Questions - Vidyadip