Question 12 Marks
Suppose a pure Si crystal has $5 \times 10^{28}$ atom $m ^{-3}$. It is doped by 1 ppm concentration of pentavalert As. Calculate the number of electrons and holes. (Given that $n_i=1.5 \times 10^{16} m^{-13}$ )
Answer
View full question & answer→→ number of atoms in pure $S i=5 \times 10^{28} m^{-3}$
→ Concentration of $As =1 ppm$
Impurity proportion is kept as 1 in $10^6$ pure atoms.
$
\text { Total atoms of As }=\frac{5 \times 10^{28}}{10^6}=5 \times 10^{22} m^{-3}
$
→ As is pentavalent impurity. Thus As is donating one extra electron. So electron number density due to As atom,
$
n_e=n_{D}=5 \times 10^{22} m^{-3}
$
→ Now $n_i^2=n_e n_h$
$
\begin{array}{l}
\therefore n_h=\frac{n_i^2}{n_e} \\
\therefore n_h=\frac{\left(1.5 \times 10^{16}\right)^2}{5 \times 10^{22}} \\
=\frac{2.25 \times 10^{32}}{5 \times 10^{22}} \\
\therefore n_h \\
\therefore n_h=4.5 \times 10^9 m^{-3}
\end{array}
$
→ Concentration of $As =1 ppm$
Impurity proportion is kept as 1 in $10^6$ pure atoms.
$
\text { Total atoms of As }=\frac{5 \times 10^{28}}{10^6}=5 \times 10^{22} m^{-3}
$
→ As is pentavalent impurity. Thus As is donating one extra electron. So electron number density due to As atom,
$
n_e=n_{D}=5 \times 10^{22} m^{-3}
$
→ Now $n_i^2=n_e n_h$
$
\begin{array}{l}
\therefore n_h=\frac{n_i^2}{n_e} \\
\therefore n_h=\frac{\left(1.5 \times 10^{16}\right)^2}{5 \times 10^{22}} \\
=\frac{2.25 \times 10^{32}}{5 \times 10^{22}} \\
\therefore n_h \\
\therefore n_h=4.5 \times 10^9 m^{-3}
\end{array}
$



