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Question 15 Marks
Copy and complete the following table relating to important industrial processes output refers to the product of the process not the intermediate steps.
Name of processInputs CatalystEquation for catalysed reactionOutput
Haber processHydrogen        +
Ammonia
+
Air
Nitric acid
Answer
Name of processInputsCatalystEquation for catalysed reactionOutput
Haber processHydrogen +
Nitrogen
Iron $Na _2( g )+3 H _2 \stackrel{ Fe , Al _2 O _3}{\rightleftharpoons} 2 NH _3( g )$Ammonia
Ostwald processAmmonia
+
Air
Platinum$4 NH _3+5 O _2 \xrightarrow[800^{\circ} C ]{\text { Platinurn gange }} 4 NO +6 H _2 O +$ HeatNitric acid
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Question 25 Marks
Give two chemical tests to distinguish between dilute nitric acid and hydrochloric acid.
Answer
Dilute nitric acid Dilute hydrochloric acid
1. On reacting copper metal with nitric acid brown fumes of nitrogen dioxide.
$Cu +4 HNO _3 \longrightarrow Cu \left( NO _3\right)_2+2 NO _2+2 H _2 O$
1.On treating copper metal with HCl
We dont observe any reaction.
2. Brown ring test : Nitric acid in a test tube is taken and then and then freshly prepared ferrous sulphate solution is added. Concentrated $H_2SO_4$​​​​​​​ is then added carefully down the sides of the test tube, dark brown ring is formed at the juctions of two layers.
$\ce{6FeSO4 + 3H2SO4 + 2HNO3 -> 3Fe2(SO4)3 + 2NO + 4H2O }$


$\ce{FeSO4 + NO + 5H2O -> \underset{\text{Hydrated nitrosoferrous Sulphate (brown ring)}}{[Fe(No)(H2O)5]SO4}}$
2. No brown ring test is observed in the caseof hydrochloric acid.
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Question 35 Marks
Describe the Ostwalds process for the manufacture of nitric acid with labeled diagram.
Answer

Ostwald process :-
The nitric acid is manufactured by Ostwald process, ln ostwald process ammonia gas and air are taken in 1:10 ratio, Pt gauge is used as a catalyst in ostwald process. Following steps are involved in Ostwalds process for the manufacture of nitric acid.
1. Oxidation of ammonia in catalytic chamber.
$\ce{4NH3 +5O2 ->[Platinum gauge][800°C] 4NO + 6H2O +Heat}$
2. Oxidation of nitric acid in oxidation chamber.
$\ce{2NO + O2 ->[50°C] 2NO2}$
3. Absorption of nitrogen dioxide in water.
$\ce{4NO2 + O2 +2H2O -> 4HNO3}$
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[5 Mark Question Answer] - Chemistry STD 10 Questions - Vidyadip