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106 questions · 101 auto-graded MCQ + 5 self-marked written.

MCQ 11 Mark
Identify Swartz reaction from the following.
  • A
    $R - OH + HX \underset{\text { condition }}{\stackrel{\text { Suitable }}{\longrightarrow}} R - X + H _2 O$
  • $R - Cl + AgF \stackrel{\Delta}{\longrightarrow} R - F + AgCl$
  • C
    $R - OH + PCl _5 \longrightarrow R - Cl + HCl + POCl _3$
  • D
    non of these
Answer
Correct option: B.
$R - Cl + AgF \stackrel{\Delta}{\longrightarrow} R - F + AgCl$
B
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MCQ 21 Mark
Which among the following is NOT an example of Wurtz reaction?
  • A
    $CH _3 Br + C _2 H _5 Br \underset{\text { dry ether }}{\longrightarrow} C _2 H _6+ C _3 H _8+ C _4 H _{10}$

  • Image
  • C
    $2 CH _3 Br +2 Na \stackrel{\text { dry ether }}{\longrightarrow} C _2 H _6+2 NaBr$
  • D
    $2 C _2 H _5 Br +2 Na \stackrel{\text { dry ether }}{\longrightarrow} C _4 H _{10}+2 NaBr$
Answer
Correct option: B.

Image
B
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MCQ 31 Mark
Which among the following examples of halogen derivatives does NOT correctly match with its type of compound?
  • A
    Halo alkane $\quad: \quad$ Methyl chloride
  • B
    Benzylic halide $\quad: \quad$ Benzyl chloride
  • C
    Haloarene : Chlorobenzene
  • Allylic halide $\quad: \quad$ 1-chloroethene
Answer
Correct option: D.
Allylic halide $\quad: \quad$ 1-chloroethene
D
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MCQ 41 Mark
Which among the following compounds has chiral carbon atom?
  • A
    $\left( CH _3 CH _2\right)_2 CHCl$
  • $CH _3 CH ( Cl ) CH _2 CH _3$
  • C
    $\left( CH _3\right)_3- CCl$
  • D
    $\left( CH _3\right)_2- CHCl$
Answer
Correct option: B.
$CH _3 CH ( Cl ) CH _2 CH _3$
B
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MCQ 51 Mark
Which of the following compounds has difficulty in breaking $C - X$ bond ?
  • A
    2,4,6-trinitrochlorobenzene
  • $m$ - nitrochlorobenzene
  • C
    0 - nitrochlorobenzene
  • D
    $P$ - nitrochlorobenzene
Answer
Correct option: B.
$m$ - nitrochlorobenzene
B
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MCQ 61 Mark
The correct order of reactivity for reactions involving cleavage of $C - X$ bond in following compounds is 
Image
  • A
    I $>$ II $>$ III
  • III $>$ II $>$ I
  • C
    II $>$ III $>$ I
  • D
    I $>$ III $>$ II
Answer
Correct option: B.
III $>$ II $>$ I
B
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MCQ 71 Mark
Identify optically active substance from the following.
  • $CH _3 CH ( Br ) CH _2 CH _3$
  • B
    $\left( CH _3\right)_2 C ( Br ) CH _3$
  • C
    $CH _3\left( CH _2\right)_3 CH _2 Br$
  • D
    $\left( CH _3\right)_2 CH CH ( Br ) CH \left( CH _3\right)_2$
Answer
Correct option: A.
$CH _3 CH ( Br ) CH _2 CH _3$
A
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MCQ 81 Mark
Identify tertiary alkyl halide from the following.
  • A
    $\left( CH _3\right)_3- C - CH _2- Br$
  • B
    $CH _3-\left( CH _2\right)_4- CH _2- Br$
  • C
    $\left( CH _3\right)_2- CH - CH _2- Br$
  • $\left( CH _3\right)_3- C - Br$
Answer
Correct option: D.
$\left( CH _3\right)_3- C - Br$
D
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MCQ 91 Mark
 { Identify the alkyl halide that undergoes } $SN ^2 $ { reaction most fastly. }
  • A
    Image
  • Image
  • C
    Image
  • D
    Image
Answer
Correct option: B.
Image
B
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MCQ 101 Mark
Identify product $P$ in the following reaction.
$C _2 H _5- Mg - Br + NH _3 \longrightarrow P$
  • $C _2 H _6$
  • B
    $HC \equiv CH$
  • C
    $H _2 C = CH _2$
  • D
    $C _2 H _5 Br$
Answer
Correct option: A.
$C _2 H _6$
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MCQ 111 Mark
Identify Finkelstein reaction from the following
  • A
    $C _2 H _5 Cl + KCN \stackrel{\Delta}{\longrightarrow} C _2 H _5 CN + KCl$
  • B
    $C _2 H _5 Cl + AgF \stackrel{\Delta}{\longrightarrow} C _2 H _5 F + AgCl$
  • $C _2 H _5 Cl + NaI \stackrel{\text { acetone }}{\longrightarrow} C _2 H _5 I + NaCl$
  • D
    $C _2 H _5 Cl + NaOH \longrightarrow C _2 H _5 OH + NaCl$
Answer
Correct option: C.
$C _2 H _5 Cl + NaI \stackrel{\text { acetone }}{\longrightarrow} C _2 H _5 I + NaCl$
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MCQ 121 Mark
Choose the false statement from following.
  • A
    Good yield of alkyl halide may be obtained by heating alcohols with $NaI$ in 95\% $H _3 PO _4$.
  • B
    Constant boiling $HBr (48 \%)$ is used for the preparation of alkyl bromides from alcohols.
  • C
    Tertiary alcohol readily react with conc. $HCl$ in absence of zinc chloride.
  • The order of reactivity of alcohols with a given halo acid $1^{\circ}>2^{\circ}>3^{\circ}$
Answer
Correct option: D.
The order of reactivity of alcohols with a given halo acid $1^{\circ}>2^{\circ}>3^{\circ}$
D
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MCQ 131 Mark
WLive Which of the following reactions is used to prepare toluene from bromobenzene?
  • A
    Wurtz reaction
  • B
    Fittig reaction
  • Wurtz-Fittig reaction
  • D
    Swartz reaction
Answer
Correct option: C.
Wurtz-Fittig reaction
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MCQ 141 Mark
What is the product formed when aniline is treated with $NaNO _2+ HCl$ previous to hydrolysis?
  • Benzene diazonium chloride
  • B
    Phenol $+ N _2 \uparrow$
  • C
    Benzene
  • D
    Phenol
Answer
Correct option: A.
Benzene diazonium chloride
A
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MCQ 151 Mark
Which among the following statements is NOT correct about $SN ^2$ reaction mechanism?
  • A
    Rate of reaction is dependent on the concentration of nucleophile.
  • B
    Nucleophile attacks the carbon atom from the side opposite to halogen.
  • C
    Bond formation and bond breaking occurs simultaneously.
  • $SN ^2$ mechanism is observed in tertiary alkyl halides.
Answer
Correct option: D.
$SN ^2$ mechanism is observed in tertiary alkyl halides.
D
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MCQ 161 Mark
Which among the following compounds is used in Swartz reaction?
  • AgF
  • B
    KCN
  • C
    $AgCN$
  • D
    $Nal$
Answer
Correct option: A.
AgF
A
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MCQ 171 Mark
Identify chiral molecule from the following.
  • A
    $\left( CH _3\right)_2- CH - CH ( Cl )- CH -\left( CH _3\right)_2$
  • $CH _3 CH ( Cl ) CH _2 CH _3$
  • C
    $CH _3 CH ( Cl ) CH _3$
  • D
    $\left( CH _3\right)_3- C - Cl$
Answer
Correct option: B.
$CH _3 CH ( Cl ) CH _2 CH _3$
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MCQ 181 Mark
Which among the following compounds is vinylic halide?
  • A
    2-chloropropane
  • B
    2-Bromo-2-methylpropane
  • C
    Bromoethane
  • 1-chloroethene
Answer
Correct option: D.
1-chloroethene
D
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MCQ 191 Mark
Which among the following compounds converts alkyl halides to nitro alkanes?
  • A
    alc. Potassium cyanide
  • B
    Potassium nitrite
  • C
    alc. Silver cyanide
  • Silver nitrite
Answer
Correct option: D.
Silver nitrite
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MCQ 201 Mark
Which among the following compounds have highest boiling point ?
  • $CH _3 CH ( Cl ) CH _2 CH _3$
  • B
    $CH _3 Cl$
  • C
    $CH _3 CH _2 CH _2 Cl$
  • D
    $CH _3 CH _2 Cl$
Answer
Correct option: A.
$CH _3 CH ( Cl ) CH _2 CH _3$
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MCQ 211 Mark
Which among the following is a Lucas reagent?
  • A
    $H _2 / Ni$
  • $HCl / ZnCl _2$
  • C
    $Na - Hg / H _2 O$
  • D
    $Zn - Hg / HCl$
Answer
Correct option: B.
$HCl / ZnCl _2$
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MCQ 221 Mark
Which among the following reactions does not occur?
  • A
    $C _2 H _5 Br + KNO _2 \longrightarrow C _2 H _5- O - N = O + KBr$
  • B

    Image
  • C
    $C _2 H _5 Br + AgCN \longrightarrow C _2 H _5 NC + AgBr$
  • $C _2 H _5 Br + KCN \longrightarrow C _2 H _5 NC + KBr$
Answer
Correct option: D.
$C _2 H _5 Br + KCN \longrightarrow C _2 H _5 NC + KBr$
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MCQ 231 Mark
Which among the following compounds undergoes $\mathrm{SN}^2$ reaction fastly ?
  • A
    Image
  • Image
  • C
    Image
  • D
    Image
Answer
Correct option: B.
Image
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MCQ 241 Mark
Which of the following is used as source of dichlorocarbene
  • A
    tetrachloromethane
  • chloroform
  • C
    iodoform
  • D
    $\text{DDT}$
Answer
Correct option: B.
chloroform
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MCQ 261 Mark
Choose the compound from the following that will react fastest by $S _{ N } 1$ mechanism.
  • A
    1-iodobutane
  • B
    1-iodopropane
  • 2-iodo-2 methylbutane
  • D
    2-iodo-3-methylbutane
Answer
Correct option: C.
2-iodo-2 methylbutane
2-iodo-2 methylbutane
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MCQ 271 Mark
Butanenitrile may be prepared by heating
  • A
    propanol with KCN
  • B
    butanol with KCN
  • C
    n-butyl chloride with KCN
  • n-propyl chloride with KCN
Answer
Correct option: D.
n-propyl chloride with KCN
n-propyl chloride with KCN
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Question 281 Mark
An alkyl chloride on Wurtz reaction gives 2,2,5,5-tetramethylhexane. The same alkyl chloride on reduction with zinc-copper couple in alchol give hydrocarbon with molecular
formula $C_5H_{12}.$ What is the structure of alkyl chloride

Image
Answer
a
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MCQ 291 Mark
Identify the chiral molecule from the following.
  • A
    1-Bromobutane
  • B
    1,1- Dibromobutane
  • C
    2,3- Dibromobutane
  • 2-Bromobutane
Answer
Correct option: D.
2-Bromobutane
2-Bromobutane
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MCQ 301 Mark
The best method for preparation of alkyl fluorides is
  • A
    Finkelstein reaction
  • Swartz reaction
  • C
    Free radical fluorination
  • D
    Sandmeyer’s reaction
Answer
Correct option: B.
Swartz reaction
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MCQ 311 Mark
Which of the following is likely to undergo racemization during alkaline hydrolysis?

Image

  • Only I
  • B
    only II
  • C
    II and IV
  • D
    Only IV
Answer
Correct option: A.
Only I
Only I
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Question 321 Mark
$CH _3- CH = CH _2 \underset{\text { peroxide }}{\stackrel{\text { HI }}{\longrightarrow}}$

The major product of the above reaction is,

Image

Answer
c
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MCQ 331 Mark
The correct order of increasing reactivity of C-X bond towards nucleophile in the following compounds is

Image

  • A
    I < II < III < IV
  • B
    II < I < III < IV
  • C
    III < IV < II < I
  • IV < III < I < II
Answer
Correct option: D.
IV < III < I < II
IV < III < I < II
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MCQ 341 Mark
Identify the reagent $A$ in the following conversion : Alkyl halide $\xrightarrow{A}$ Alkyl nitrite
  • A
    $KNO _3$
  • B
    $NaNO _3$
  • C
    $Ag NO _2$
  • $KNO _2$
Answer
Correct option: D.
$KNO _2$
(d) : Alkyl halide $\xrightarrow{ KNO _3}$ Alkyl nitrite
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MCQ 351 Mark
Identify the chiral molecule from following.
  • A
    2-Bromopropane
  • B
    2-Bromo-2-methylbutane
  • 2-Bromo-3-methylbutane
  • D
    3-Bromopentane
Answer
Correct option: C.
2-Bromo-3-methylbutane
(c) :
Image
${ }^*$Represents chiral centre having four different groups attached to carbon.
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MCQ 361 Mark
Which among the following is haloalkyne?
  • Chloroethyne
  • B
    3-Chlorobut-1-yne
  • C
    1-Chloropent-2-yne
  • D
    4-Chloropent-2-yne
Answer
Correct option: A.
Chloroethyne
(a) : $\mathrm{HC} \equiv \mathrm{C}-\mathrm{Cl}$
Chloroethyne
In haloalkyne, halogen atom is bonded to an alkynyl group.
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MCQ 371 Mark
Which of the following is a structural formula of DDT?
  • A
    Image
  • B
  • D
    Image
Answer
Correct option: C.
(c) : DDT is dichlorodiphenyltrichloroethane.
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MCQ 381 Mark
Which among the following is not a true statement for enantiomers?
  • A
    Enantiomers have identical refractive index.
  • B
    Enantiomers have same chemical properties.
  • Enantiomers are superimposable mirror images of each other.
  • D
    Enantiomers have equal but opposite optical rotation.
Answer
Correct option: C.
Enantiomers are superimposable mirror images of each other.
(c): Enantiomers are the optical isomers which are non-superimposable mirror images of each other.
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MCQ 391 Mark
What is IUPAC name of the following compound?
Image
  • A
    3-Bromo-4-ethylbut-3-ene
  • 3-Bromo-4-methylhex-3-ene
  • C
    4-Bromo-3-methylhex-3-ene
  • D
    4-Bromo-4-ethyl-3-methylbut-3-ene
Answer
Correct option: B.
3-Bromo-4-methylhex-3-ene
(b) :
Image
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MCQ 401 Mark
Identify the product obtained when bromoethane is heated with excess of alcoholic ammonia under pressure.
  • A
    Ethene
  • Ethanamine
  • C
    Nitroethane
  • D
    Ethanol
Answer
Correct option: B.
Ethanamine
(b): $C _2 H _5 Br + NH _3 \xrightarrow{\text { alc. }} C _2 H _5 NH _2+ HBr$
$\quad$$\quad$Bromoethane$\quad$Excess$\quad$$\quad$Ethanamine
When primary alkyl halide is treated with excess of alcoholic ammonia, then primary amine is obtained as the major product.
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MCQ 411 Mark
Identify tertiary alkyl halide from the following.
  • A
    $\left( CH _3\right)_3 C - CH _2- Br$
  • $\left( CH _3\right)_3 C - Br$
  • C
    $CH _3-\left( CH _2\right)_4- CH _2- Br$
  • D
    $\left( CH _3\right)_2- CH - CH _2- Br$
Answer
Correct option: B.
$\left( CH _3\right)_3 C - Br$
(b) : The alkyl halide in which a halogen atom is directly attached to tertiary carbon atom is known as tertiary alkyl halide. The other three are primary alkyl halides.
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MCQ 421 Mark
Which of the following is obtained by the following reaction? $ 2 C _2 H _5 Br +2 Na \xrightarrow{\text { Dry ether }}$
  • Butane
  • B
    Propane
  • C
    Ethane
  • D
    Methane
Answer
Correct option: A.
Butane
(a): $CH _3 CH _2 Br +2 Na + BrCH _2 CH _3 \xrightarrow{\text { Dry ether }}$
$
\underset{\text { Butane }}{ CH _3 CH _2 CH _2 CH _3+2 NaBr }
$
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MCQ 431 Mark
What is the IUPAC name of the following compound?
Image
  • 2-Bromo-4,4,6-trimethyl octane
  • B
    3-Bromo-5,5,7-trimethyl octane
  • C
    2-Bromo-4,4,6-trimethyl nonane
  • D
    3-Bromo-5,5,7-trimethyl nonane
Answer
Correct option: A.
2-Bromo-4,4,6-trimethyl octane
(a) 2-Bromo-4,4,6-trimethyl octane
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MCQ 441 Mark
Which reaction is useful in exchange of halogen in alkyl chloride by iodide?
  • A
    Wurtz reaction
  • Finkelstein reaction
  • C
    Reimer-Tiemann reaction
  • D
    Williamson synthesis
Answer
Correct option: B.
Finkelstein reaction
(b): Iodoalkanes can be easily prepared from the corresponding chloroalkanes by heating the chloroalkane with sodium iodide in acetone or methanol. This reaction is called Finkelstein reaction.
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MCQ 451 Mark
The reaction in which two molecules of chlorobenzene reacts with metallic sodium in presence of dry ether forming diphenyl is an example of
  • Wurtz-Fittig reaction
  • B
    Wurtz reaction
  • C
    Rosenmund reaction
  • D
    Balz-Schiemann reaction.
Answer
Correct option: A.
Wurtz-Fittig reaction
(a): When a mixture of an alkyl halide and aryl halide gives an alkylarene on treatment with sodium in dry ether, the reaction is called Wurtz-Fittig reaction.
When only haloarenes are treated with sodium, aryls are formed. This reaction is called Fittig reaction.
Image
Note : Option (a) should be Fittig reaction in place of Wurtz-Fittig reaction.
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MCQ 461 Mark
In case of $R, S$ configuration the group having highest priority is
  • A
    $- NO _2$
  • B
    $- NH _2$
  • C
    $- CN$
  • $- OH$
Answer
Correct option: D.
$- OH$
(d) : Atomic mass of oxygen is more than that of $C$ and $N$.
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MCQ 471 Mark
Arenes on treatment with chlorine in presence of ferric chloride as a catalyst undergo what type of reaction?
  • Electrophilic substitution
  • B
    Nucleophilic substitution
  • C
    Electrophilic addition
  • D
    Nucleophilic addition
Answer
Correct option: A.
Electrophilic substitution
(a) :
Image
This is an electrophilic substitution reaction.
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MCQ 481 Mark
In assigning $R, S$-configuration which among the following groups has highest priority?
Answer
Correct option: A.
$- SO _3 H$
(a) $- SO _3 H$
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MCQ 491 Mark
The conversion of ethyl bromide to ethyl iodide using sodium iodide and dry acetone, this reaction is known as
  • A
    Swarts reaction
  • Finkelstein reaction
  • C
    Sandmeyer reaction
  • D
    Stephen reaction
Answer
Correct option: B.
Finkelstein reaction
(b) : Finkelstein reaction is used for the preparation of alkyl iodides from alkyl chlorides or bromides using sodium or potassium iodide and acetone.
$
\underset{\text { Ethyl bromide }}{ CH _3 CH _2 Br + KI \xrightarrow{\text { Acetone }}} \underset{\text { Ethyl iodide }}{ CH _3 CH _2 I }+ KBr
$
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MCQ 501 Mark
While assigning $R, S$ configuration the correct order of priority of groups attached to chiral carbon atom is
  • A
    $CONH _2> COCH _3> CH _2 OH > CHO$
  • $CONH _2> COCH _3> CHO > CH _2 OH$
  • C
    $COCH _3> CONH _2> CHO > CH _2 OH$
  • D
    $CHO > CH _2 OH > COCH _3> CONH _2$
Answer
Correct option: B.
$CONH _2> COCH _3> CHO > CH _2 OH$
(b) : The order of priority is
$
CONH _2> COCH _3> CHO > CH _2 OH
$
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MCQ 511 Mark
The compound which is not formed when a mixture of $n$-butyl bromide and ethyl bromide treated with sodium metal in presence of dry ether is
  • A
    butane
  • B
    octane
  • C
    hexane
  • ethane.
Answer
Correct option: D.
ethane.
(d) :
Image
Image
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MCQ 521 Mark
If ' $n$ ' represents total number of asymmetric carbon atoms in a compound, the possible number of optical isomers of the compound is
  • A
    $2 n$
  • B
    $n^2$
  • $2^n$
  • D
    $2 n+2$
Answer
Correct option: C.
$2^n$
(c) : When the molecule cannot be divided into two equal halves i.e., unsymmetrical and $n$ is the number of asymmetric carbon atoms, then total number of optical isomers $=2^n$.
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MCQ 531 Mark
Chlorination of ethane is carried out in presence of
  • A
    anhydrous $AlBr _3$
  • B
    mercuric chloride
  • ultraviolet light
  • D
    zinc chloride.
Answer
Correct option: C.
ultraviolet light
(c) Ultraviolet light 
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MCQ 541 Mark
Which among the following functional groups has been given the highest priority while assigning $R-S$ configuration?
Answer
Correct option: B.
$- CN$
(b) : As the first atom is same in all the four groups, the priority will be decided by the second atom. Hence $- CN$ will be given highest priority because $N$ has the highest atomic number.
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MCQ 551 Mark
Benzene can be conveniently converted into n-propyl benzene by
  • A
    Friedel-Crafts alkylation with $n$-propyl chloride
  • Friedel-Crafts acylation with propionyl chloride followed by Wolff-Kishner reduction
  • C
    Friedel-Crafts acylation with propionyl chloride followed by catalytic hydrogenation
  • D
    Friedel-Crafts acylation with propionyl chloride followed by reduction with $LiAlH _4$.
Answer
Correct option: B.
Friedel-Crafts acylation with propionyl chloride followed by Wolff-Kishner reduction
(b) :
Image
Image
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MCQ 561 Mark
' $X$ ' is an optically active alkane having lowest molecular mass. Predict the structure of the major product obtained on monochlorination of ' $X$ '.

  • Image

  • B

    Image

  • C

    Image

  • D

    Image

Answer
Correct option: A.

Image

(a) :
Image
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MCQ 581 Mark
Alkaline hydrolysis of which among the following compounds leads to the formation of a racemate?
  • 1-Bromo-1-phenylethane
  • B
    1-Chloro-3-methylbutane
  • C
    Bromoethane
  • D
    1-Chloropropane
Answer
Correct option: A.
1-Bromo-1-phenylethane
(a) : 1-Bromo-1-phenylethane has one chiral carbon. It follows $S _{ N } 1$ mechanism.
Image
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MCQ 591 Mark
UPAC name of the following compound is
Image
  • 3-Bromo-3, 4-dimetbyiheptane
  • B
    3,4-dimethyl-3-bromoheptane
  • C
    5-Bromo-4,5-dimethylheptane
  • D
    4,5-dimethyl-5-bromoheptane
Answer
Correct option: A.
3-Bromo-3, 4-dimetbyiheptane
3-Bromo-3, 4-dimetbyiheptane
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MCQ 601 Mark
The preparation of alkyl fluoride from alkyl chlor ide, in presence of metallic fluorides is known as
  • A
    Williamson’s reaction
  • B
    Finkeistein reaction
  • Swarts reaction
  • D
    Wurlz reaction
Answer
Correct option: C.
Swarts reaction
Swarts reaction
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MCQ 611 Mark
Identify the product D in the following sequence of reactions :
Image
  • A
    2, 2-dimethyl butane
  • 2, 3-dimethyl butane
  • C
    hexane
  • D
    2, 4-dimethylpentane
Answer
Correct option: B.
2, 3-dimethyl butane
2, 3-dimethyl butane
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MCQ 621 Mark
Carbon tetrachloride is used as
  • A
    anaesthetic
  • B
    antiseptic
  • dry cleaning agent
  • D
    fire extinguisher
Answer
Correct option: C.
dry cleaning agent
dry cleaning agent
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MCQ 631 Mark
But-l-ene on reaction with HCI in the presence of sodium peroxide yields
  • A
    n-butyl chloride
  • B
    isobutyl chloride
  • secondary butyl chloride
  • D
    tertiary butyl chloride
Answer
Correct option: C.
secondary butyl chloride
secondary butyl chloride
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MCQ 641 Mark
Which of the following carbocations is least stable ?
  • A
    Image
  • B
    $CH _3- CH _2-{ }^{+} CH - CH _2- CH _3$
  • $CH _3- CH _2-{ }^{+} CH _2$
  • D
    Image
Answer
Correct option: C.
$CH _3- CH _2-{ }^{+} CH _2$
$CH _3- CH _2-{ }^{+} CH _2$
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MCQ 651 Mark
Chlorobenzene can be obtained by benzene diazonium chloride by
  • A
    Friedel Craft’s reaction
  • B
    Wurtz reaction
  • Gatterman’s reaction
  • D
    Fittig reaction
Answer
Correct option: C.
Gatterman’s reaction
Gatterman’s reaction
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MCQ 661 Mark
The halogen atom in aryl halides is
  • o- and p-di reefing
  • B
    m-directing
  • C
    o, m and p-di reefing
  • D
    only m-directing
Answer
Correct option: A.
o- and p-di reefing
o- and p-di reefing
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MCQ 671 Mark
Which of the following groups has highest priority according to R, S convention?
  • A
    $CH _2 OH$
  • B
    $COOH$
  • C
    $COCH _3$
  • $COOCH _3$
Answer
Correct option: D.
$COOCH _3$
$COOCH _3$
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MCQ 681 Mark
Which one of the following alkane is NOT formed in Wurtz reaction ?
  • Methane
  • B
    Ethane
  • C
    Propane
  • D
    Butane
Answer
Correct option: A.
Methane
Methane
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MCQ 691 Mark
In which of the following pairs both are nucleophiles ?
  • A
    $BF _3, AlCl _3$
  • B
    $NO ^{+}{ }_2, Cl ^{-}$
  • $CN ^{-}, NH _3$
  • D
    $Br ^{+}, BC1 _3$
Answer
Correct option: C.
$CN ^{-}, NH _3$
$CN ^{-}, NH _3$
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MCQ 701 Mark
The total number of electrons present in the central carbon atom of a free radical is
  • 7
  • B
    8
  • C
    9
  • D
    6
Answer
Correct option: A.
7
7
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MCQ 711 Mark
Which one of the following is NOT used to prepare alkyl halide from an alcohol ?
  • A
    $SOCl _2$
  • B
    $PC1 _3$
  • C
    $HC1 + ZnCl _2$
  • $NaCl$
Answer
Correct option: D.
$NaCl$
$NaCl$
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MCQ 721 Mark
The hydrogen halide which does not obey Markownikv rule in presence of peroxide is
  • A
    HC1
  • HBr
  • C
    HF
  • D
    HI
Answer
Correct option: B.
HBr
HBr
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MCQ 731 Mark
The optically inactive compound is
  • A
    Glucose
  • B
    Lactic acid
  • C
    2-Chlorobutane
  • 2-Chloropropane
Answer
Correct option: D.
2-Chloropropane
2-Chloropropane
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MCQ 741 Mark
Carbon atom in methyl carbocation contains how many pairs of electrons?
  • A
    8
  • 4
  • C
    3
  • D
    5
Answer
Correct option: B.
4
4
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MCQ 771 Mark
The most reactive alkyl halide towards $SN 2$ reac - tion is
  • $CH _3 X$
  • B
    $R _3 CX$
  • C
    $R _2 CHX$
  • D
    $RCH _2 X$
Answer
Correct option: A.
$CH _3 X$
$CH _3 X$
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MCQ 781 Mark
Which one of the following when heated with metallic sodium will not give the corresponding alkane ?
  • A
    Image
  • B
    $CH _3- CH _2- CH _2- Cl$
  • C
    Image
  • D
    $CH _3- CH _2- CH _2- CH _2- Cl$
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MCQ 791 Mark
It is difficult to break $C - Cl$ bond in $CH _2= CH - Cl$ due to
  • A
    Hyper conjugation
  • Resonance
  • C
    Electromeric effect
  • D
    Inductive effect
Answer
Correct option: B.
Resonance
Resonance
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MCQ 801 Mark
Which alkyl halide among the following com $\neg$ pounds has the highest boiling point?
  • A
    $\left( CH _3\right)_3 CCl$
  • B
    $CH _3 CH \left( CH _3\right) CH _2 Cl$
  • C
    $CH _3 CH _2 CH _2 CH _2 Cl$
  • $CH _3 CH \left( CH _3\right) CH _2 Cl$
Answer
Correct option: D.
$CH _3 CH \left( CH _3\right) CH _2 Cl$
$CH _3 CH \left( CH _3\right) CH _2 Cl$
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MCQ 821 Mark
In its nucleophilic substitution reaction, aryl halide resembles
  • Vinyl chloride
  • B
    allyl chloride
  • C
    Benzyl chloride
  • D
    ethyl chloride
Answer
Correct option: A.
Vinyl chloride
Vinyl chloride
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MCQ 831 Mark
The geometry of carbon lum ion is
  • A
    Tetrahedral
  • planar
  • C
    linear
  • D
    pyramidal
Answer
Correct option: B.
planar
planar
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MCQ 851 Mark
Racemate is
  • A
    optically active
  • B
    optically dextro rotatory
  • optically inactive
  • D
    optically laevorotatory
Answer
Correct option: C.
optically inactive
optically inactive
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MCQ 861 Mark
The order of reactivity in nucleophilic substitution reaction is
  • A
    $CH _3 F < CH _3 C 1< CH _3 I < CH _3 Br$
  • $CH _3 F < CH _3 C1 < CH _3 Br < CH _3 I$
  • C
    $CH _3 F < CH _3 Br < CH _3 C1 < CH _3 I$
  • D
    $CH _3 I < CH _3 Br < CH _3 C 1< CH _3 F$
Answer
Correct option: B.
$CH _3 F < CH _3 C1 < CH _3 Br < CH _3 I$
$CH _3 F < CH _3 C1 < CH _3 Br < CH _3 I$
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MCQ 871 Mark
p, $p ^{\prime}$-dichlorodiphenyl trichloroethane is used as
  • insecticide
  • B
    anaesthetic
  • C
    antiseptic
  • D
    refrigerant
Answer
Correct option: A.
insecticide
insecticide
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MCQ 881 Mark
Iodoform is used as
  • A
    an anaesthetic
  • an antiseptic
  • C
    an analgesic
  • D
    an antibiotic
Answer
Correct option: B.
an antiseptic
an antiseptic
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MCQ 891 Mark
The above reaction is known as

Image
  • A
    Wurtz-Fittig reaction
  • Friedel Craft's reaction
  • C
    Sandmeyer's reaction
  • D
    Swarts reaction
Answer
Correct option: B.
Friedel Craft's reaction
Friedel Craft's reaction
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MCQ 911 Mark
Which of the following compounds shows optical activity ?
  • A
    n-butyl chloride
  • B
    isobutyl chloride
  • sec-butyl chloride
  • D
    t-butyl chloride
Answer
Correct option: C.
sec-butyl chloride
sec-butyl chloride
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MCQ 921 Mark
Which of the following compounds is not optically active ?
  • A
    Lactic acid
  • B
    Secondary butyl chloride
  • n-propyl iodide
  • D
    Glucose
Answer
Correct option: C.
n-propyl iodide
n-propyl iodide
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MCQ 931 Mark
A racemic mixture consists of
  • A
    equal amount of d and I isomers
  • B
    unequal amounts of $d$ and / isomers
  • C
    unknown amounts of $d$ and / isomers
  • D
    only d isomers
Answer
equal amount of $d$ and I isomers
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MCQ 941 Mark
A compound with the molecular formula $CH _2 OH ( CHOH )_3 CH _2 OH$ has optically active forms
  • A
    3
  • B
    4
  • C
    6
  • 8
Answer
Correct option: D.
8
8
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MCQ 951 Mark
The optically inactive compound is
  • A
    glucose
  • B
    lactic acid
  • isopropyl alcohol
  • D
    2-bromo butane
Answer
Correct option: C.
isopropyl alcohol
isopropyl alcohol
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MCQ 961 Mark
Which of the following characteristic properties of the enantiomers is correct?
  • A
    The enantiomers possess same physical and chemical properties
  • B
    The enantiomers are optically active compounds
  • C
    The enantiomers have different optical rotations
  • All of these
Answer
Correct option: D.
All of these
All of these
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MCQ 981 Mark
The stability order of carbocation is
  • A
    $2^{\circ}>3^{\circ}>1^{\circ}$
  • $3^{\circ}>2^{\circ}>1^{\circ}$
  • C
    $3^{\circ}>1^{\circ}>2^{\circ}$
  • D
    $1^{\circ}>3^{\circ}>2^{\circ}$
Answer
Correct option: B.
$3^{\circ}>2^{\circ}>1^{\circ}$
$3^{\circ}>2^{\circ}>1^{\circ}$
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MCQ 991 Mark
Which of the following is most reactive towards nucleophilic substitution reaction ?
  • A
    $CH _2= CH - Cl$
  • B
    $CH _3 CH = CHCl$
  • C
    $C _6 H _5 Cl$
  • $ClCH _2- CH = CH _2$
Answer
Correct option: D.
$ClCH _2- CH = CH _2$
$ClCH _2- CH = CH _2$
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MCQ 1001 Mark
Which of the following undergoes nucleophilic substitution exclusively by $S_N 2$ mechanism ?
  • A
    ethyl chloride
  • B
    isopropyl chloride
  • C
    chlorobenzene
  • benzyl chloride
Answer
Correct option: D.
benzyl chloride
benzyl chloride
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MCQ 1011 Mark
Which of the following is not a nucleophile?
  • A
    Ammonia
  • B
    Ammonium ion
  • C
    Primary amine
  • Secondary amine
Answer
Correct option: D.
Secondary amine
Secondary amine
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MCQ 1021 Mark
Which of the following is correct about $S_{ N } 2$ mechanism?
  • A
    Two step reaction
  • Complete inversion of configuration
  • C
    Formation of carbonium ion
  • D
    Favoured by polar solvent
Answer
Correct option: B.
Complete inversion of configuration
Complete inversion of configuration
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MCQ 1031 Mark
The one step exothermic reaction is
  • A
    $S_N 1$
  • $S_N 2$
  • C
    $S _{ N }$
  • D
    $S 2_{ N }$
Answer
Correct option: B.
$S_N 2$
$S_N 2$
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MCQ 1041 Mark
In $S _{ N } 2$ reaction, the hydrolysis of alkyl halide shows
  • A
    the retention of configuration
  • the inversion of configuration
  • C
    both retention and inversion of configuration
  • D
    no change in the configuration
Answer
Correct option: B.
the inversion of configuration
the inversion of configuration
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MCQ 1051 Mark
The rate of $S_N 2$ reaction depends on the concentra $\neg$ tion of
  • A
    only the substrate
  • B
    only the reagent
  • both the substrate and the reagent
  • D
    neither the substrate nor the reagent
Answer
Correct option: C.
both the substrate and the reagent
both the substrate and the reagent
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MCQ 1061 Mark
$CH _3- CH = CH _2 \xrightarrow[\text { peroxide }]{ HI }$
The major product of the above reaction is,
  • A
    $I - CH _2- CH = CH _2$
  • $CH _3- CH _2- CH _2 I$
  • C
    Image
  • D
    Image
Answer
Correct option: B.
$CH _3- CH _2- CH _2 I$
$CH _3- CH _2- CH _2 I$
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