MCQ 1511 Mark
The correct order of increasing acidic nature of $\mathrm{SO}_2, \mathrm{SiO}_2, 2 \mathrm{O}_3$ and $\mathrm{Al}_2 \mathrm{O}_3$ is.
- ✓$\mathrm{Al}_2 \mathrm{O}_3<\mathrm{SiO}_2 2 \mathrm{O}_3<\mathrm{SO}_2$.
- B$\mathrm{SO}_2<\mathrm{P}_2 \mathrm{O}_3<\mathrm{SiO}_2<\mathrm{Al}_2 \mathrm{O}_3$.
- C$\mathrm{SiO}_2 \mathrm{Al}_2 \mathrm{O} 3<<\mathrm{P}_2 \mathrm{O}_3<\mathrm{SO}_2$.
- D$\mathrm{SiO}_2 2 \mathrm{O}_3<\mathrm{P}_2 \mathrm{O}_3$.
Answer
View full question & answer→Correct option: A.
$\mathrm{Al}_2 \mathrm{O}_3<\mathrm{SiO}_2 2 \mathrm{O}_3<\mathrm{SO}_2$.
While moving along a group from top to bottom, acidic nature of oxides decreases and along a period from left to right, acidic nature increases.
$\mathrm{Al}_2 \mathrm{O}_3$ is amphoteric. $\mathrm{SiO}_2$ is slightly acidic whereas $\mathrm{P}_2 \mathrm{O}_3$ and $\mathrm{SO}_2$ are the anhydrides of the acids $\mathrm{H}_3 \mathrm{PO}_3$ and $\mathrm{H}_2 \mathrm{SO}_3$.
${\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ {\text{Al}}\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \text{Si}\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \text{P}\ \ \ \ \ \ \ \ \ \ \text{S}\\ \ \ \ \text{Z}\ \ \ \ \ \ \ \ \ \ 13\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ 14\ \ \ \ \ \ \ \ \ \ \ \ \ \ 15\ \ \ \ \ \ \ \ \ 16\\ \ \ \ \ \ \ \ \ \ \ \ \ \text{Al}_2\text{O}_3\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \text{SiO}_2\ \ \ \ \ \ \ \ \ \text{P}_2\text{O}_3\ \ \ \ \ \text{SO}_2}\\\ \ \ \ \ \ \ \ \xrightarrow{\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ }\\\ \ \ \ \ \ \ \ \ \ \ \ \text{atmphoteric}\ \ \ \ \ \ \text{acidic}\ \ \ \ \ \ \text{max.}\ \ \ \ \ \text{ acidic}\\\text{Thus,}\ \ \ \ \ \ \text{Al}_2\text{O}_3\ \ \ \ \ \ <\ \ \text{SiO}_2\ <\ \text{P}_2\text{O}_3\ <\ \text{SO}_2$
$\mathrm{Al}_2 \mathrm{O}_3$ is amphoteric. $\mathrm{SiO}_2$ is slightly acidic whereas $\mathrm{P}_2 \mathrm{O}_3$ and $\mathrm{SO}_2$ are the anhydrides of the acids $\mathrm{H}_3 \mathrm{PO}_3$ and $\mathrm{H}_2 \mathrm{SO}_3$.
${\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ {\text{Al}}\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \text{Si}\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \text{P}\ \ \ \ \ \ \ \ \ \ \text{S}\\ \ \ \ \text{Z}\ \ \ \ \ \ \ \ \ \ 13\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ 14\ \ \ \ \ \ \ \ \ \ \ \ \ \ 15\ \ \ \ \ \ \ \ \ 16\\ \ \ \ \ \ \ \ \ \ \ \ \ \text{Al}_2\text{O}_3\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \text{SiO}_2\ \ \ \ \ \ \ \ \ \text{P}_2\text{O}_3\ \ \ \ \ \text{SO}_2}\\\ \ \ \ \ \ \ \ \xrightarrow{\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ }\\\ \ \ \ \ \ \ \ \ \ \ \ \text{atmphoteric}\ \ \ \ \ \ \text{acidic}\ \ \ \ \ \ \text{max.}\ \ \ \ \ \text{ acidic}\\\text{Thus,}\ \ \ \ \ \ \text{Al}_2\text{O}_3\ \ \ \ \ \ <\ \ \text{SiO}_2\ <\ \text{P}_2\text{O}_3\ <\ \text{SO}_2$
