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M.C.Q (1 Marks)

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MCQ 11 Mark
$\mathrm{H}_2 \mathrm{O}_2+\mathrm{O}_3 \rightarrow \mathrm{H}_2 \mathrm{O}+2 \mathrm{O}_2$, in this reaction :
  • A
    $\mathrm{H}_2 \mathrm{O}_2$ is bleached.
  • $\mathrm{H}_2 \mathrm{O}_2$ is oxidised.
  • C
    $\mathrm{H}_2 \mathrm{O}_2$ is dehydrated.
  • D
    $\mathrm{H}_2 \mathrm{O}_2$ is neither oxidised nor reduced.
Answer
Correct option: B.
$\mathrm{H}_2 \mathrm{O}_2$ is oxidised.
Oxidation half reactions is,
$\mathrm{H}_2 \mathrm{O}_2 \rightarrow 2 \mathrm{H}^{+}+\mathrm{O}_2+2 \mathrm{e}^{-}$
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MCQ 21 Mark
What is the oxidation number of lithium in $\ce{LiCl}\ ?$
  • A
    $+3$
  • B
    $−1$
  • $+1$
  • D
    $0$
Answer
Correct option: C.
$+1$
Oxidation number of $\ce{Li}$ in $\ce{LiCl } : x − 1 = 0$
$\Rightarrow x = +1$
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MCQ 31 Mark
In $\mathrm{Ni}(\mathrm{CO})_4,$ the oxidation state of $\ce{Ni}$ is?
  • $4$
  • B
    Zero
  • C
    $2$
  • D
    $8$
Answer
Correct option: A.
$4$
In nickel tetracarbonyl, the oxidation state for nickel is assigned as zero. The formula conforms to the $18-$ electron rule. The molecule is tetrahedral, with four carbonyl $($carbon monoxide$)$ ligands attached to nickel.
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MCQ 41 Mark
Which of the following elements does not show disproportionation tendency?
  • A
    $\ce{Cl}$
  • B
    $\ce{Br}$
  • $\ce{F}$
  • D
    $\ce{I}$
Answer
Correct option: C.
$\ce{F}$
Being the most electronegative element, $F$ can only be reduced and hence it always shows an oxidation number of $-1$. Further, due to the absence of $d-$ orbitals, it cannot be oxidized and hence it does not show $+ve$ oxidation numbers. In other words, $F$ cannot be simultaneously oxidized as well as reduced and hence does not show disproportionation reactions. Thus, option $(c)$ is correct.
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MCQ 51 Mark
Which of the following is not an example of redox reaction?
  • A
    $\text{CuO}+\text{H}_2\xrightarrow{ \ \ \ \ \ \ \ \ \ }\text{Cu}+\text{H}_2\text{O}$
  • B
    $\text{Fe}_2\text{O}_3+3\text{CO}\xrightarrow{ \ \ \ \ \ \ \ \ \ }2\text{Fe}+3\text{CO}_2$
  • C
    $2\text{K}+\text{F}_2\xrightarrow{ \ \ \ \ \ \ \ }2\text{KF}$
  • $\text{BaCl}_2+\text{H}_2\text{SO}_4\xrightarrow{ \ \ \ \ \ \ \ \ }\text{BaSO}_4+2\text{HCl}$
Answer
Correct option: D.
$\text{BaCl}_2+\text{H}_2\text{SO}_4\xrightarrow{ \ \ \ \ \ \ \ \ }\text{BaSO}_4+2\text{HCl}$
$\text{BaCl}_2+\text{H}_2\text{SO}_4\xrightarrow{ \ \ \ \ \ \ \ \ }\text{BaSO}_4+2\text{HCl}$ is not a redox reaction. It is an example of double displacement reactions.
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MCQ 61 Mark
Which of the following metal displacement reaction will not take place and why?
  • $\text{Cu}+\text{Mg}^{2+}\xrightarrow{ \ \ \ \ \ \ \ }$
  • B
    $\text{Mg}+\text{Cu}^{2+}\xrightarrow{ \ \ \ \ \ \ \ }$
  • C
    $\text{Pb}+\text{Ag}^+\xrightarrow{ \ \ \ \ \ \ \ }$
  • D
    $\text{Zn}+\text{Cu}^{2+}\xrightarrow{ \ \ \ \ \ \ \ }$
Answer
Correct option: A.
$\text{Cu}+\text{Mg}^{2+}\xrightarrow{ \ \ \ \ \ \ \ }$
Will not take place because $'\text{Cu}\ '$ is less reactive than $\text{Mg}.$
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MCQ 71 Mark
In which of the following groups of iodine compounds shows increasing order of oxidation states :
  • $\ce{HlO_4, ICl, I_2, Hl}$
  • B
    $\ce{Hl, I_2, IC, HIO_4}$
  • C
    $\ce{I_2, HI, HIO_4 , HI}$
  • D
    $\ce{ICl HIO_4,HI, I_2}$
Answer
Correct option: A.
$\ce{HlO_4, ICl, I_2, Hl}$
$\mathrm{HI}(-1), \mathrm{I}_2(\mathrm{O}), \mathrm{ICl}(+1), \mathrm{HIO}_4(+7)$
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MCQ 81 Mark
The formation of nitrous oxide from nitrogen and oxygen is the example for
  • A
    Decomposition reaction.
  • B
    Chemical combination of one element and one compound.
  • C
    Chemical combination of two compounds.
  • Chemical combination of two elements.
Answer
Correct option: D.
Chemical combination of two elements.
The formation of nitrous oxide from nitrogen and oxygen is the example for chemical combination of two elements.
$\text{N}_2\text{O}\rightleftarrows\text{N}_2+\text{O}.$
$\text{N}_2\text{O}\rightleftarrows\text{N}_2+\text{O}_2$
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MCQ 91 Mark
Oxidation number of $C$ in $\text{HNC}$ is $ ..........$
  • $+2$
  • B
    $−3$
  • C
    $+3$
  • D
    Zero
Answer
Correct option: A.
$+2$
Oxidation number of hydrogen is $+1.$
As nitrogen is more electronegative than carbon so its oxidation number is $-3$.
Net charge on compound is zero.
Now we can find oxidation number of carbon:
Let oxidation number of carbon is $x,$
$1 + (−3) + x = 0$
$x = +2$
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MCQ 101 Mark
Which of the following is a redox reaction $($disproportionation reaction$).$
  • A
    $\text{PCl}_3+3\text{H}_2\text{O}\xrightarrow{ \ \ \ \ \ \ \ \ \ \ \ }\text{H}_3\text{PO}_3+3\text{HCL}$
  • B
    $\text{CO}^{3+}+6\text{NO}_2^-\xrightarrow{\ \ \ \ \ \ \ \ \ }[\text{CO(NO}_2)_6]^{3-}$
  • C
    $\text{Hg}_2\text{CrO}_4+2\text{OH}^-\xrightarrow{ \ \ \ \ \ \ \ \ }\text{Hg}_2\text{O}+\text{CrO}_4^{2-}+\text{H}_2\text{O}$
  • $3\text{Br}_2+6\text{OH}^-\xrightarrow{ \ \ \ \ \ \ \ }5\text{Br}^-+\text{BrO}_3^-+3\text{H}_2\text{O}$
Answer
Correct option: D.
$3\text{Br}_2+6\text{OH}^-\xrightarrow{ \ \ \ \ \ \ \ }5\text{Br}^-+\text{BrO}_3^-+3\text{H}_2\text{O}$
$\because$ Oxidation state of $\ce{Br_2}$ is increasing from $0$ to $+5,$ decreasing from $0$ to $-1$.
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MCQ 111 Mark
Plumbous ion is represented as :
  • $ \mathrm{Pb}^{+2}$
  • B
    $ \mathrm{~Pb}^{+4}$
  • C
    $ \mathrm{~Pb}^{+3} $
  • D
    $\mathrm{~Pb}^{+1}$
Answer
Correct option: A.
$ \mathrm{Pb}^{+2}$
$\mathrm{~Pb}^{2+}=$ Plumbous ion
$\mathrm{~Pb}^{4+}=$ Plumbic ion
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MCQ 121 Mark
What is the oxidation state of $\text{Mn}$ in the compound $\ce{K_2​MnO_4}\ ?$​
  • A
    $3$
  • B
    $4$
  • C
    $5$
  • $6$
Answer
Correct option: D.
$6$
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MCQ 131 Mark
In which of the following, the highest oxidation state is not possible?
  • A
    $\left[\mathrm{XeO}_6\right]^{4-}$
  • $\mathrm{XeF}_8$
  • C
    $\mathrm{OsO}_4$
  • D
    $\mathrm{RuO}_4$
Answer
Correct option: B.
$\mathrm{XeF}_8$
$\ce{Xe}$ shows $+8$ oxidation state in $\mathrm{XeF}_8$ but it does not exist because of steric hindrance of $8F$ atoms.
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MCQ 141 Mark
What is the oxidation number of $O$ in a diatomic molecule $\ce{(O_2)}\ ?$
  • A
    $+2$
  • B
    $±2$
  • C
    $+8$
  • $0$
Answer
Correct option: D.
$0$
The oxidation state of any element in its native state is zero.
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MCQ 151 Mark
The reaction, $\text{2H}_2\text{O(I)}\xrightarrow{\ \ \ \ \Delta\ \ \ }\text{2H}_2\text{(g)}+\text{O}_2\text{(g)}$ is an example of :
  • A
    Addition reaction.
  • Decomposition reaction.
  • C
    Displacement reaction.
  • D
    None of these.
Answer
Correct option: B.
Decomposition reaction.
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MCQ 161 Mark
The given reactions such as :
$i. \mathrm{Zn}+2 \mathrm{HCl} \rightarrow \mathrm{ZnCl}_2+\mathrm{H}_2$
$ii. \mathrm{Fe}+2 \mathrm{HCl} \rightarrow \mathrm{FeCl}_2+\mathrm{H}_2$
Are represented as :
  • A
    Displacement of zinc and iron metals.
  • B
    Displacement of only zinc metals.
  • C
    Displacement of only iron metals.
  • Displacement of hydrogen.
Answer
Correct option: D.
Displacement of hydrogen.
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MCQ 171 Mark
Identify disproportionation reaction :
  • A
    $\text{CH}_4+2\text{O}_2\xrightarrow{ \ \ \ \ \ \ \ \ }\text{CO}_2+2\text{H}_2\text{O}$
  • B
    $\text{CH}_4+4\text{Cl}_2\xrightarrow{ \ \ \ \ \ \ \ \ }\text{CCl}_4+4\text{HCl}$
  • C
    $2\text{F}_2+2\text{OH}^-\xrightarrow{ \ \ \ \ \ \ \ \ }2\text{F}^-+\text{OF}_2+\text{H}_2\text{O}$
  • $2\text{NO}_2+2\text{OH}^-\xrightarrow{ \ \ \ \ \ \ \ \ }\text{NO}^-_2+\text{NO}^-_3+\text{H}_2\text{O}$
Answer
Correct option: D.
$2\text{NO}_2+2\text{OH}^-\xrightarrow{ \ \ \ \ \ \ \ \ }\text{NO}^-_2+\text{NO}^-_3+\text{H}_2\text{O}$
Reactions in which the same substance is oxidized as well as reduced are called disproportionation reactions.
Writing the $O.N$. of each element above its symbol in the given reactions,
  1. $\stackrel{-4+1}{\text{CH}}_4+\stackrel{0}{\text{2O}}_2\xrightarrow{ \ \ \ \ \ \ \ \ }\stackrel{+4-2}{\text{CO}}_2+\stackrel{+1-2}{\text{2H}}_2\text{O}$
  2. $\stackrel{-4+1}{\text{CH}}_4+\stackrel{0}{\text{4Cl}}_2\xrightarrow{ \ \ \ \ \ \ \ \ }\stackrel{+4-1}{\text{CCl}}_4+\stackrel{+1-1}{\text{4HCl}}\text{}$
  3. $2\stackrel{0}{\text{F}}_2+\stackrel{-2+1}{\text{2OH}^-}\xrightarrow{ \ \ \ \ \ \ \ \ }\stackrel{-1}{\text{2F}^-+}\stackrel{+2-1}{\text{OF}_2}+\stackrel{+1-2}{\text{H}_2\text{O}}$
  4. $\stackrel{+4-2}{\text{2NO}_2}+\stackrel{-2+1}{\text{2OH}^-}\xrightarrow{ \ \ \ \ \ \ \ \ }\stackrel{+3-2}{\text{NO}^-_2}+\stackrel{+5-2}{\text{NO}^-_3}+\stackrel{+1-2}{\text{H}_2\text{O}}$
Thus, in reaction $(d), N$ is both oxidized as well as reduced since the $O . N $. of $N$ increases from $+4$ in $\mathrm{NO}_2$ to $+5$ in $ \mathrm{NO}^{-}3$ and decreases from $+4$ in $\mathrm{NO}_2$ to $+3$ in $\mathrm{NO}^{-} 2$.
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MCQ 181 Mark
Which among the following shows maximum oxidation state?
  • A
    $V$
  • B
    $Fe$
  • $Mn$
  • D
    $Cr$
Answer
Correct option: C.
$Mn$
Metal Maximum Oxidation state
$V$ $+3$
$Cr$ $+6$
$Fe$ $+3$
$Mn$ $+7$
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MCQ 191 Mark
What is the oxidation state of central atom in $\ce{Ca[PtCl_4​]}\ ?$
  • A
    $1$
  • $2$
  • C
    $3$
  • D
    $4$
Answer
Correct option: B.
$2$
$\mathrm{Ca}\left[\mathrm{PtCl}_4\right] \Leftrightarrow \mathrm{Ca}^{+2}[\mathrm{PtCl} 4]^{2-}$
$\text { Take }[\mathrm{PtCl} 4]^{2-} \text {. Central atom }=\mathrm{Pt} \text {. }$
Let $x$ be the oxidation no. of $\ce{Pt},$
$\ce{Cl}$ oxidation no. is $−1.$
$x + 4(−1) = −2$
$x − 4 = −2$
$x = 2$
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MCQ 201 Mark
The oxidation state of the underlined element in the given compound is : $\ce{BaCl_2}​$
  • $+2$
  • B
    $-2$
  • C
    $0$
  • D
    None of these
Answer
Correct option: A.
$+2$
$\ce{BaCl_2}$
$\Rightarrow x + (−2) = 0$
$\Rightarrow x = 2$
As chlorine needs only one electron to get octet.
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MCQ 211 Mark
The oxidation numbers of the sulphur atoms in peroxy monosulphuric acid $\ce{(H_2 SO_5​)}$ and peroxydisulphuric and $\ce{(H_2S_2O_8)}$​ are respectively.
  • A
    $+8$ and $+7$
  • B
    $+3$ and $+3$
  • $+6$ and $+6$
  • D
    $+4$ and $+6$
Answer
Correct option: C.
$+6$ and $+6$
By looking the structure of $\ce{H_2 SO_5},$ we can observe that there are two oxygen atoms which are linked by peroxide linkage so their oxidation numbers are $-1.$
Rest oxygen atoms attached normally so their oxidation state is $-2.$
The oxidation number of hydrogen is $+1.$
So oxidation number of sulphur is
$2(+1) + x + 2(−1) + 3(−2) = 0, x = +6$
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MCQ 221 Mark
In which of the following compounds, is the oxidation number of sulphur is the least?
  • A
    $ \mathrm{SO}_2 $
  • B
    $ \mathrm{SO}_3 $
  • $ \mathrm{Na}_2 \mathrm{~S}_4 \mathrm{O}_8 $
  • D
    $ \mathrm{H}_2 \mathrm{SO}_4 $
Answer
Correct option: C.
$ \mathrm{Na}_2 \mathrm{~S}_4 \mathrm{O}_8 $
The oxidation number of sulphur in $\ce{SO_2​,SO_3,Na_2 SO_4}$​ and $\ce{H_2​SO_4}$​ are $+4,+6,+2.5$ and $+6$ respectively.
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MCQ 231 Mark
In the electrochemical series, metals are arranged in order of their tendency to :
  • A
    Release halogens from their salts.
  • B
    Become reduced.
  • C
    React with water.
  • Lose electrons.
Answer
Correct option: D.
Lose electrons.
In the electrochemical series, metals are arrange in order of their tendency to lose electrons.
Oxidation potential increases down the group. $($tendency to lose electron increases$).$
Reduction potentials decreases down the group. $($tendency to gain $e−$ decreases$).$
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MCQ 241 Mark
The oxidation numbers of sulphur in $\ce{S_8, S_2 , F_2}$ and $\ce{F_2S}$ respectively, are :
  • A
    $0, +1$ and $−2$
  • B
    $+2, +1$ and $−2$
  • $0, +1$ and $+2$
  • D
    $−2, +1$ and $−2$
Answer
Correct option: C.
$0, +1$ and $+2$
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MCQ 251 Mark
Oxygen has an oxidation state of $+2$ in.
  • A
    $\ce{H_2O_2}$
  • $\ce{OF_2}$
  • C
    $\ce{SO_2}$
  • D
    $\ce{H_2O}$
Answer
Correct option: B.
$\ce{OF_2}$
Oxidation state of oxygen is always $-2$ except in peroxides,superoxides and when it reacts with fluorine.
In $\ce{H_2​O_2},$ oxidation state of $H$ is $+1,$ so oxidation state of oxygen is $-1.$
In $\ce{OF_2}$​, oxidation state of $F$ is $-1,$ so oxidation state of oxygen is $+2.$
In $\ce{SO_2}$ and $\ce{H_2​O}$, oxidation state of oxygen is $-2.$
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MCQ 261 Mark
Metals exhibit $........$ oxidation states in their compounds.
  • Positive.
  • B
    Negative.
  • C
    Neutral.
  • D
    None of these.
Answer
Correct option: A.
Positive.
As metals have great tendency in donating electrons it will have positive oxidation states.
For example $\ce{Na}$ is metal has atomic number $11$
So electronic configuration is $2, 8, 1$
So after donating one electron its octet get completed and become stable and becomes $\ce{Na}^+$
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MCQ 271 Mark
Oxidation state of nitrogen in $\ce{NH_2OH}$ is :
  • A
    $−3$
  • $−1$
  • C
    $+2$
  • D
    $3$
Answer
Correct option: B.
$−1$
Let $x$ be the oxidation state of $N$ in $\ce{NH_2​OH}$.
Since the overall charge on the complex is $0,$ the sum of oxidation states of all elements in it should be equal to $0.$
Therefore, $x + 2 − 1 = 0$ or, $x = −1$.
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MCQ 281 Mark
The oxidation number of chromium in $\ce{CrO_5}$​ is :
  • $+6$
  • B
    $+5$
  • C
    $+10$
  • D
    $0$
Answer
Correct option: A.
$+6$
The oxidation number of chromium in chromium pentaoxide is $6.$
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MCQ 301 Mark
The sum of oxidation number of all the atoms in a neutral molecule must be zero.
  • True.
  • B
    False.
  • C
    Ambiguous.
  • D
    None of these.
Answer
Correct option: A.
True.
The sum of oxidation number of all the atoms in a neutral molecule must be zero.
For example, neutral molecules such as $\mathrm{O}_2, \mathrm{P}_4, \mathrm{O}_3, \mathrm{~S}_8$ and $\mathrm{KMnO}_4$ have the sum of oxidation number of all the atoms equal to zero.
For an ion, the sum of oxidation number of all the atoms is equal to the charge on the ion.
For example, in cyanide ion $\ce{(CN}^-$), the sum of oxidation number of all the atoms is equal to $−1.$
In ammonium ion $\ce{(NH_4}​)+,$ the sum of oxidation number of all the atoms is equal to $+1.$
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MCQ 311 Mark
Which titrant is used in the Iodometric titration which involves $\ce{I_2} ?$
  • A
    $\mathrm{KMnO}_4 $
  • B
    $ \mathrm{~K}_2 \mathrm{Cr}_2 \mathrm{O}_7 $
  • $ \mathrm{Na}_2 \mathrm{S}_2 \mathrm{O}_3$
  • D
    All of them
Answer
Correct option: C.
$ \mathrm{Na}_2 \mathrm{S}_2 \mathrm{O}_3$
Iodometry is one of the most important redox titration methods. Iodine reacts directly, fast and quantitively with many organic and inorganic substances.
Thanks to its relatively low, $\ce{pH}$ independent redox potential, and reversibility of the iodine/ iodide reaction, iodometry can be used both to determine amount of reducing agents $($by direct titration with iodine$)$ and of oxidizing agents $($by titration of iodine with thiosulfate$).$
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MCQ 321 Mark
In $\ce{MgCl_2}​,$ the oxidation number of chlorine is :
  • A
    $+1$
  • B
    $+2$
  • $−1$
  • D
    $0$
Answer
Correct option: C.
$−1$
In $\ce{MgCl_2},$​ oxidation number of $\ce{Cl}$ is :
$\Rightarrow 2 + 2x = 0$
$\Rightarrow x = −1.$
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MCQ 331 Mark
The oxidation state of $\ce{Cr}$ in $\mathrm{K}_2 \mathrm{Cr}_2 \mathrm{O}_7$ is :
  • A
    $+4$
  • B
    $+3$
  • $+6$
  • D
    $+5$
Answer
Correct option: C.
$+6$
$\mathrm{K}_2 \mathrm{Cr}_2 \mathrm{O}_7$​
Let the oxidation state of $\ce{Cr}$ is $x.$
$2(+1) + 2x + 7(−2) = 0$
$+2 + 2x − 14 = 0$
$2x − 12 = 0$
$2x = 12$
$x = +6$
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MCQ 341 Mark
In the given reaction, $\mathrm{CH}_2=\mathrm{CH}_2(\mathrm{~g})+\mathrm{H}_2(\mathrm{~g}) \rightarrow \mathrm{CH}_3-\mathrm{CH}_3(\mathrm{~g})$ ethene undergoes :
  • Reduction process.
  • B
    Oxidation process.
  • C
    Addition process.
  • D
    All of these.
Answer
Correct option: A.
Reduction process.
$\mathrm{CH}_2=\mathrm{CH}_2+\mathrm{H}-\mathrm{H} \rightarrow \mathrm{H}_3 \mathrm{C}-\mathrm{CH}_3$
$($Addition of hydrogen$)$
Because of the addition of hydrogen, there occurs reduction of ethylene.
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MCQ 351 Mark
Tailing of mercury is $ .......... $ redox change.
  • A
    Intramolecular.
  • Intermolecular.
  • C
    Disproportion.
  • D
    None.
Answer
Correct option: B.
Intermolecular.
When ozone is passed through mercury, mercurous oxide $\ce{(Hg_2​O)}$ is formed.
Due to this, mercury loses its meniscus and starts sticking to the glass.
This phenomenon is known as Tailing of mercury.
$2 \mathrm{Hg}+\mathrm{O}_3 \rightarrow \mathrm{Hg}_2 \mathrm{O}+\mathrm{O}_2$.
In this reaction, the oxidation number of mercury changes from $0$ to $+1$. Thus, it is oxidized.
The oxidation number of oxygen changes from 0 to $-2$. Thus, it is reduced.
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MCQ 361 Mark
The half $-$ cell reaction is the one that :
  • Takes place at one electrode.
  • B
    Consumes half a unit of electricity.
  • C
    Involves half a mole of electrolyte.
  • D
    Goes half way to completion.
Answer
Correct option: A.
Takes place at one electrode.
A half reaction is either the oxidation or reduction reaction component of a redox reaction. A half reaction is obtained by considering the change in oxidation states of individual substances involved in the redox reaction. Half $-$ reactions are often used as a method of balancing redox reactions.
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MCQ 371 Mark
The oxidation state of the most electronegative element in the products of the reaction between $\mathrm{BaO}_2$ and $\mathrm{H}_2 \mathrm{SO}_4$ are :
  • A
    $0$ and $−1$
  • $−1$ and $−2$
  • C
    $−2$ and $0$
  • D
    $−2$ and $+1$
Answer
Correct option: B.
$−1$ and $−2$
$\mathrm{BaO}_2+\mathrm{H}_2 \mathrm{SO}_4 \rightarrow \mathrm{BaSO}_4+\mathrm{H}_2 \mathrm{O}_2$
The most electronegative element in the product is oxygen.
The oxidation state of oxygen in $\mathrm{BaSO}_4$ is $-2$ and in $\mathrm{H}_2 \mathrm{O}_2$ is $-1 .$
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MCQ 381 Mark
Heat is released in :
  • Exothermic reactions.
  • B
    Endothermic reactions.
  • C
    Both $A$ and $B.$
  • D
    None of these.
Answer
Correct option: A.
Exothermic reactions.
Heat is released in exothermic reactions.
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MCQ 391 Mark
When $P$ reacts with caustic soda, the products are $\ce{PH_3}$​ and $\ce{NaH_2​PO_2}$. The reaction is an example of.
  • A
    Oxidation.
  • B
    Reduction.
  • Both oxidation and reduction.
  • D
    Neutralisation.
Answer
Correct option: C.
Both oxidation and reduction.
$\mathrm{P}_4+3 \mathrm{NaOH}+3 \mathrm{H}_2 \mathrm{O} \rightarrow \mathrm{PH}_3+3\mathrm{NaH}_2 \mathrm{PO}_2$
In reactant $P$ is present in $(0)$ oxidation state and in $\ce{PH_3}$ , it is present in $(-3)$ oxidation state and in $\ce{NaH_2​PO_2}$​ it is present in $(+1)$ oxidation state.
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MCQ 401 Mark
The rods of transition metals such as copper and zinc where potential difference is generated, are termed as :
  • Electrodes.
  • B
    Cathodes.
  • C
    Anodes.
  • D
    None of these.
Answer
Correct option: A.
Electrodes.
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MCQ 411 Mark
Standard reduction frotential of $\text{X, Y, Z}$ are ${-1.2v, +0.5v, -3.0v}$ respectively, the reducing power of the metals will be :
  • $\text{Y > Z > X}$
  • B
    $\text{Y > X > Z}$
  • C
    $\text{Z > X > Y}$
  • D
    $\text{X > Y > Z}$
Answer
Correct option: A.
$\text{Y > Z > X}$
$'Z\ '$ is best because it has lowest standard reduction potential whereas $'Y\ '$ is weakest due to highest standard reduction potential.
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MCQ 421 Mark
A redox reaction is one in which :
  • A
    Both the substance are reduced.
  • B
    Both the substance are oxidised.
  • One substance is reduced and other is oxidised.
  • D
    All of the above.
Answer
Correct option: C.
One substance is reduced and other is oxidised.
In a redox reaction both oxidation and reduction is happening together.
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MCQ 431 Mark
What is the oxidation number of $\ce{Si}$ in the compound $\ce{CaSiO_3} \ ?$
  • A
    $−4$
  • B
    $+2$
  • C
    $−2$
  • $+4$
Answer
Correct option: D.
$+4$
$\ce{CaSiO_3}$
Total charge present $= 0.$
Oxidation no. of Oxygen is $−2.$
Oxidation no. od Calcium is $+2.$
Let, oxidation no. of Slilicon be $X.$
So, $[+2] + x + 3[−2] = 0$
$2 + x − 6 = 0$
$x = 4$
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MCQ 441 Mark
The difference in the oxidation numbers of the two types of sulphur atoms in $\mathrm{Na}_2 \mathrm{~S}_4 \mathrm{O}_6$ is :
  • $5$
  • B
    $4$
  • C
    $3$
  • D
    $6$
Answer
Correct option: A.
$5$
In $\mathrm{Na}_2\mathrm{~S}_4 \mathrm{O}_6,$​ the oxidation number of end sulphur atoms is $+5$ each and the oxidation number of middle sulphur atoms is $0$ each.
The difference in the oxidation numbers of the two types of sulphur atoms is $5 − 0 = 0.$
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MCQ 451 Mark
Consider the given standard electrode potentials :
$\ce{i}.\frac{\text{K}^+}{\text{K}}=-3.02\text{V}$
$\ce{ii}.\frac{\text{Cu}^{2+}}{\text{Cu}}=+0.34\text{V}$
$\ce{iii}.\frac{\text{Hg}^{2+}}{\text{Hg}}=0.92\text{V}$
$\ce{iv}.\frac{\text{Cr}^{3+}}{\text{Cr}}=-0.74\text{V}$
Decreasing order of reducing power of these elements is :
  • A
    $\text{I > II > III > IV}$
  • B
    $\text{I > IV > III > II}$
  • $\text{I > IV > II > III}$
  • D
    $\text{III > II > IV > I}$
Answer
Correct option: C.
$\text{I > IV > II > III}$
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MCQ 461 Mark
Which of the following pairs of ions cannot coexist in aqueous solution?
  • $\text{Cr}^{2+}$ and $ \ \text{MnO}_4^-$
  • B
    $\text{Fe}^{3+}$ and $\ \text{Cr}_2\text{O}_7^{2-}$
  • C
    $\text{Cr}^{2+}$ and $\ \text{I}_3^-$
  • D
    $\text{Mn}^{2+}$ and $\ \text{Cl}^-$
Answer
Correct option: A.
$\text{Cr}^{2+}$ and $ \ \text{MnO}_4^-$
It is because $\text{Cr}^{2+}$ is strongly reducing, it will get oxidised by $\text{MnO}_4^-$ to $\text{Cr}^{3+}$
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MCQ 471 Mark
In the chemical reaction, $\mathrm{K}_2 \mathrm{Cr}_2 \mathrm{O}_7+\mathrm{xH}_2 \mathrm{SO}_4+\mathrm{ySO}_2 \rightarrow \mathrm{K}_2 \mathrm{SO}_4+\mathrm{Cr}_2\left(\mathrm{SO}_4\right)_3+\mathrm{zH}_2 \mathrm{O}$
the value of $x + y + z$
  • A
    $6$
  • $5$
  • C
    $7$
  • D
    $3$
Answer
Correct option: B.
$5$
The balanced redox reaction is : $\mathrm{K}_2 \mathrm{Cr}_2 \mathrm{O}_7+\mathrm{xH}_2 \mathrm{SO}_4+\mathrm{3SO}_2 \rightarrow \mathrm{K}_2 \mathrm{SO}_4+\mathrm{Cr}_2\left(\mathrm{SO}_4\right)_3+\mathrm{zH}_2 \mathrm{O}$
$x = 1, y = 3, z = 1$
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MCQ 481 Mark
Which of the following compounds we use in our laboratory as a standard solution $($titrant$) \ ?$
  • A
    $\mathrm{KMnO}_4 $
  • B
    $ \mathrm{~K}_2 \mathrm{Cr}_2 \mathrm{O}_7 $
  • C
    $ \mathrm{Na}_2 \mathrm{S}_2 \mathrm{O}_3 $​
  • All of these
Answer
Correct option: D.
All of these
A reagent, called the titrant or titrator is prepared as a standard solution.
A known concentration and volume of titrant reacts with a solution of analyte or titrand to determine concentration.
$\mathrm{KMnO}_4, \mathrm{~K}_2 \mathrm{Cr}_2 \mathrm{O}_7, \mathrm{Na}_2 \mathrm{~S}_2 \mathrm{O}_3$​ etc. are compounds we use in our laboratory as a standard solution.
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MCQ 491 Mark
Which is the best description of behaviour of bromine in the given equation? $\mathrm{H}_2 \mathrm{O}+\mathrm{Br}_2 \rightarrow \mathrm{HBr}+\mathrm{HOBr}$
  • A
    Proton acceptor.
  • Both oxidised and reduced.
  • C
    Oxidised.
  • D
    Reduced.
Answer
Correct option: B.
Both oxidised and reduced.
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MCQ 501 Mark
When tin $(IV)$ chloride is treated with excess of conc. hydrochloric acid, the complex ion $\ce{(SnCl_6)}^{2−}$ is formed. The oxidation state of tin in this complex ion is?
  • $+4$
  • B
    zero
  • C
    $−2$
  • D
    $−4$
Answer
Correct option: A.
$+4$
Let oxidation state of $\text{Sn}$ is $x$ and we know oxidation of $\text{Cl}$ is $−1,$ so $x + 6(−1) = −2, x = +4.$
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