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Question 11 Mark
Which of the following reactions will get affected by increasing the pressure? Also, mention whether change will cause the reaction to go into forward or backward direction.
$\text{2H}_2\text{ (g) + CO}\text{ (g)}\rightleftharpoons\text{CH}_3\text{OH (g)}$
Answer
Only those reactions will be affected by increasing the pressure in which the number of moles of the gaseous reactants and products are different (np ≠ nr) (gaseous). With the exception of the reaction (1); all the reamaining five reactions will get affected by increasing the pressure. In general,
  • The reaction will go to the left if n> nr.
  • The reaction will go to the right if nr > np.
    Keeping this in mind,
Increase in pressure will favour forward reaction because np (1) < nr (2)
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Question 21 Mark
Does the number of moles of reaction products increase, decrease or remain same when each of the following equilibria is subjected to a decrease in pressure by increasing the volume?
$\text{3Fe}\text{ (S) + }\text{4H}_2\text{O (g)}\rightleftharpoons\text{Fe}_3\text{O}_4\text{ (S) + 4H}_2\text{ (g)}$
Answer
The number of moles of reaction products remains the same.
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Question 31 Mark
Predict if the solutions of the following salts are neutral, acidic or basic:
NaCN
Answer
$\text{NaCN}$ $+$ $\text{H}_2\text{O}$ $\leftrightarrow$ $\text{HCN}$ $+$ $\text{NaOH}$
        $\text{Weak acid}$   $\text{Strong base}$

Therefore, it is a basic solution.

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Question 41 Mark
Predict if the solutions of the following salts are neutral, acidic or basic:

NH4NO3

Answer
$\text{NH}_4\text{NO}_3$ $+$ $\text{H}_2\text{O}$ $\leftrightarrow$ $\text{NH}_4\text{OH}$ $+$ $\text{HNO}_3$
        $\text{Weak base}$   $\text{Strong acid}$

Therefore, it is an acidic solution.

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Question 51 Mark
Predict if the solutions of the following salts are neutral, acidic or basic:
KBr
Answer
$\text{KBr}$ $+$ $\text{H}_2\text{O}$ $\leftrightarrow$ $\text{KOH}$ $+$ $\text{HBr}$
        $\text{Strong base}$   $\text{Strong acid}$

Therefore, it is a neutral solution.

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Question 61 Mark
Predict if the solutions of the following salts are neutral, acidic or basic:
KF
Answer
$\text{KF}$ $+$ $\text{H}_2\text{O}$ $\leftrightarrow$ $\text{KOH}$ $+$ $\text{HF}$
        $\text{Strong base}$   $\text{weak acid}$

Therefore, it is a basic solution.

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Question 71 Mark
Does the number of moles of reaction products increase, decrease or remain same when each of the following equilibria is subjected to a decrease in pressure by increasing the volume?
$\text{CaO}\text{ (S) + }\text{CO}_2\text{ (g)}\rightleftharpoons\text{CaCO}_3\text{ (S)}$
Answer
The number of moles of reaction products will decrease.
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Question 81 Mark
A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of the container is suddenly increased.
What is the initial effect of the change on vapour pressure?
Answer
On increasing the volume of the container, the vapour pressure will initially decrease because the same amount of vapours are now distributed over a larger space.
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Question 91 Mark
What is Kc for the following equilibrium when the equilibrium concentration of each substance is:
[SO2]= 0.60M, [O2] = 0.82M and [SO3] = 1.90M?
2SO2(g) + O2(g) ⇌ 2SO3(g)
Answer
2SO2(g) + O2(g) ⇌ 2SO3(g)
Applying law of chemical equilibrium.
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Question 101 Mark
Calculate the hydrogen ion concentration in the following biological fluids whose pH are given below:
Human blood, 7.38
Answer
Human blood, 7.38:
$\text{pH}=7.38=-\log[\text{H}^+]$
$\therefore\ [\text{H}^+]=4.17\times10^{-8}\text{M}$
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Question 111 Mark
Predict if the solutions of the following salts are neutral, acidic or basic:

NaNO2

Answer
$\text{NaNO}_2$ $+$ $\text{H}_2\text{O}$ $\leftrightarrow$ $\text{Na}\text{OH}$ $+$ $\text{HNO}_2$
        $\text{Strong base}$   $\text{weak acid}$

Therefore, it is a basic solution.

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Question 121 Mark
Predict if the solutions of the following salts are neutral, acidic or basic:
NaCl
Answer
$\text{NaCl}$ $+$ $\text{H}_2\text{O}$ $\leftrightarrow$ $\text{NaOH}$ $+$ $\text{HCl}$
        $\text{Strong base}$   $\text{Strong acid}$

Therefore, it is a neutral solution.

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Question 131 Mark
For the following equilibrium, $\text{K}_{\text{c}}=6.3\times10^{14}\text{ at }1000\text{K}$
$\text{NO(g) + O}_3\text{(g)}\rightleftharpoons\text{NO}_2\text{(g) + O}_2\text{(g)}$
Both the forward and reverse reactions in the equilibrium are elementary bimolecular reactions. What is Kc, for the reverse reaction?
Answer
For the reverse reaction $\text{K}_{\text{c}}=\frac{1}{\text{K}_{\text{c}}}=\frac{1}{6.3\times10^{14}}=1.59\times10^{-15.}$
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Question 141 Mark
What will be the conjugate bases for the Brönsted acids: HF, H2SO4 and $\text{HCO}_3^-$?
Answer
The table below lists the conjugate bases for the given Bronsted acids.
$\text{Bronsted acid Conjugate base}$
$\text{HF}$ $\text{F}^-$
$\text{H}_2\text{SO}_4$ $\text{HSO}_4^-$
$\text{HCO}_3^-$ $\text{CO}_3^{2-}$
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Question 151 Mark
Which of the following reactions will get affected by increasing the pressure? Also, mention whether change will cause the reaction to go into forward or backward direction.
$\text{4NH}_3\text{ (g) + 5O}_2\text{ (g)}\rightleftharpoons\text{4NO}\text{ (g) + 6H}_2\text{O (g)}$
Answer
Only those reactions will be affected by increasing the pressure in which the number of moles of the gaseous reactants and products are different (np ≠ nr) (gaseous). With the exception of the reaction (1); all the reamaining five reactions will get affected by increasing the pressure. In general,
  • The reaction will go to the left if n> nr.
  • The reaction will go to the right if nr > np.
    Keeping this in mind,
Increase in pressure will favour backward reaction because np (1) > nr (0).
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Question 161 Mark
Calculate the hydrogen ion concentration in the following biological fluids whose pH are given below:
Human muscle-fluid, 6.83
Answer
Human muscle fluid 6.83:
$\text{pH}=6.83$
$\text{pH}=-\log\text{[H}^+]$
$\therefore\ 6.83=-\log[\text{H}^+]$
$[\text{H}^+]=1.48\times10^{-7}\text{M}$
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Question 171 Mark
Predict which of the following reaction will have appreciable concentration of reactants and products:
$\text{Cl}_2\text{ (g)}+\text{2NO}_2\text{ (g)}\rightleftharpoons2\text{NO}_2\text{Cl (g) K}_\text{c}=1.8$
Answer
Following conclusions can be drawn from the values of Kc.
Since the value of Kc is 1.8, this means that both the products and reactants have appreciable concentration.
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Question 181 Mark
Write the expression for the equilibrium constant, Kc for each of the following reactions:
$\text{I}_2\text{(S)}+5\text{F}_2\rightleftharpoons2\text{IF}_5$
Answer
$\text{K}_{\text{c}}=\frac{[\text{IF}_5\text{(l)}]^2}{[\text{l}_2\text{(S)}][\text{F}_2\text{(g)}]^5}$
$=\frac{[\text{IF}_5\text{(l)}]^2}{[\text{F}_2\text{(g})']^5}$
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Question 191 Mark
Which of the following reactions will get affected by increasing the pressure? Also, mention whether change will cause the reaction to go into forward or backward direction.
$\text{COCl}_2\text{ (g)}\rightleftharpoons\text{CO (g) + Cl}_2\text{ (g)}$
Answer
Only those reactions will be affected by increasing the pressure in which the number of moles of the gaseous reactants and products are different (np ≠ nr) (gaseous). With the exception of the reaction (1); all the reamaining five reactions will get affected by increasing the pressure. In general,
  • The reaction will go to the left if n> nr.
  • The reaction will go to the right if nr > np.
    Keeping this in mind,
Increase in pressure will not affect equilibrium because np = nr = 3.
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Question 201 Mark
Ethyl acetate is formed by the reaction between ethanol and acetic acid and the equilibrium is represented as:
$\text{CH}_3\text{COOH (1) + C}_2\text{H}_5\text{OH (1)}\rightleftharpoons\text{CH}_3\text{COOC}_2\text{H}_5 \text{ (1) + H}_2\text{O (1)}$
Write the concentration ratio (reaction quotient), Qc, for this reaction (note: water is not in excess and is not a solvent in this reaction)
Answer
Reaction quotient,$\text{Q}_{\text{c}}=\frac{[\text{CH}_3\text{COOC}_2\text{H}_5][\text{H}_2\text{O]}}{[\text{CH}_3\text{COOH][}\text{C}_2\text{H}_5\text{OH}] }$
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Question 211 Mark
Predict which of the following reaction will have appreciable concentration of reactants and products:
$\text{Cl}_2\text{ (g)}\rightleftharpoons2\text{Cl (g) K}_\text{c}=5\times10^{-39}$
Answer
Following conclusions can be drawn from the values of Kc.
Since the value of Kc is very small, this means that the molar concentration of the products is very small as compared to that of the reactants.
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Question 221 Mark
Which of the following reactions will get affected by increasing the pressure? Also, mention whether change will cause the reaction to go into forward or backward direction.
$\text{CaCO}_3\text{ (S)}\rightleftharpoons\text{CaO}\text{ (S) + CO}_2\text{ (g)}$
Answer
Only those reactions will be affected by increasing the pressure in which the number of moles of the gaseous reactants and products are different (np ≠ nr) (gaseous). With the exception of the reaction (1); all the reamaining five reactions will get affected by increasing the pressure. In general,
  • The reaction will go to the left if n> nr.
  • The reaction will go to the right if nr > np.
    Keeping this in mind,
Increase in pressure will favour backward reaction because np (2) > nr(1)
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Question 231 Mark
Which of the following reactions will get affected by increasing the pressure? Also, mention whether change will cause the reaction to go into forward or backward direction.
$\text{CO}_2\text{ (g) + C}\text{ (S)}\rightleftharpoons\text{2CO}\text{ (g)}$
Answer
Only those reactions will be affected by increasing the pressure in which the number of moles of the gaseous reactants and products are different (np ≠ nr) (gaseous). With the exception of the reaction (1); all the reamaining five reactions will get affected by increasing the pressure. In general,
  • The reaction will go to the left if n> nr.
  • The reaction will go to the right if nr > np.
    Keeping this in mind,
Increase in pressure will favour backward reaction because np (10) > nr (9)
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Question 241 Mark
Describe the effect of:
addition of H2
on the equilibrium of the reaction:
$2\text{H}_2\text{ (g) + CO (g)}\rightleftharpoons\text{CH}_3\text{OH (g)}$
Answer
According to Le Chatelier’s principle, on addition of H2, the equilibrium of the given reaction will shift in the forward direction.
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Question 251 Mark
At 473K, equilibrium constant Kc for decomposition of phosphorus pentachloride, PCl5 is 8.3 ×10-3. If decomposition is depicted as,
$\text{PCl}_5\text{ (g)}\rightleftharpoons\text{PCl}_3\text{ (g) + Cl}_2\text{ (g)}\ \Delta_\text{r}\text{H}^\ominus=124.0\text{ kJ mol}^{-1}$
what would be the effect on Kc if
  1. more PCl5 is added
  2. pressure is increased
  3. the temperature is increased?
Answer
$\text{PCl}_{5\text{(g)}}\rightleftharpoons\text{PCl}_{3\text{(g)}}+\text{Cl}_{2\text{(g)}}$
  1. If more $\text{PCl}_5$ is added, then $\text{Q}_\text{c}$ becomes less than $\text{K}_{\text{c}'}$ the reaction will shift in the forward direction.
  2. If the pressure is increased, the reaction will shift towards backward direction as it contains less number of gaseous species. $\text{K}_\text{c}$ remains constant.
  3. As the reaction is endothermic, the increase in temperature will favour the forward reaction. More $\text{PCl}_5$ will dissociate to form $\text{PCl}_3$ and $\text{Cl}_2.$ $\text{K}_\text{c}$ increases.
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Question 261 Mark
Predict which of the following reaction will have appreciable concentration of reactants and products:
$\text{Cl}_2\text{ (g)}+\text{2NO (g)}\rightleftharpoons2\text{NOCl (g) K}_\text{c}=3.7\times10^8$
Answer
Following conclusions can be drawn from the values of Kc.
Since the value of Kc is quite large, this means that the molar concentration of the products is very large as compared to that of the reactants.
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Question 271 Mark
At 473K, equilibrium constant Kc for decomposition of phosphorus pentachloride, PCl5 is 8.3 ×10-3. If decomposition is depicted as,
$\text{PCl}_5\text{ (g)}\rightleftharpoons\text{PCl}_3\text{ (g) + Cl}_2\text{ (g)}\ \Delta_\text{r}\text{H}^\ominus=124.0\text{ kJ mol}^{-1}$
write an expression for Kc for the reaction.
Answer
$\text{K}_\text{c}=\frac{[\text{PCl}_{3\text{(g)}}][\text{Cl}_{2\text{(g)}}]}{[\text{PCl}_{5\text{(g)}}]}$
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Question 281 Mark
At 473K, equilibrium constant Kc for decomposition of phosphorus pentachloride, PCl5 is 8.3 ×10-3. If decomposition is depicted as,
$\text{PCl}_5\text{ (g)}\rightleftharpoons\text{PCl}_3\text{ (g) + Cl}_2\text{ (g)}\ \Delta_\text{r}\text{H}^\ominus=124.0\text{ kJ mol}^{-1}$
what is the value of Kc for the reverse reaction at the same temperature?
Answer
$\text{PCl}_{3\text{(g)}}+\text{Cl}_{2\text{(g)}}\rightleftharpoons\text{PCl}_{5\text{(g)}}$
$\therefore\ \text{K}'_\text{c}=\frac{[\text{PCl}_{5\text{(g)}}]}{[\text{PCl}_{3\text{(g)}}][\text{Cl}_{2\text{(g)}}]}=\frac{1}{8.3\times10^{-3}}=120.48$
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Question 291 Mark
Which of the following reactions will get affected by increasing the pressure? Also, mention whether change will cause the reaction to go into forward or backward direction.
$\text{CH}_4\text{ (g) + 2S}_2\text{ (g)}\rightleftharpoons\text{CS}_2\text{ (g) + 2H}_2\text{S}\text{ (g)}$
Answer
Only those reactions will be affected by increasing the pressure in which the number of moles of the gaseous reactants and products are different (np ≠ nr) (gaseous). With the exception of the reaction (1); all the reamaining five reactions will get affected by increasing the pressure. In general,
  • The reaction will go to the left if n> nr.
  • The reaction will go to the right if nr > np.
    Keeping this in mind,
Increase in pressure will favour backward reaction because np (2) > nr (1)
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Question 301 Mark
Write the conjugate acids for the following Brönsted bases: $\text{NH}_2^-$, NH3 and HCOO.
Answer
The table below lists the conjugate acids for the given Bronsted bases.
$\text{Bronsted base Conjugate acid}$
$\text{NH}_2^-$ $\text{NH}_3$
$\text{NH}_3$ $\text{NH}_4^+$
$\text{HCOO}^-$ $\text{HCOOH}$
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Question 311 Mark
Calculate the hydrogen ion concentration in the following biological fluids whose pH are given below:
Human stomach fluid, 1.2
Answer
Human stomach fluid, 1.2:
$\text{pH}=1.2$
$1.2=-\log[\text{H}^+]$
$\therefore\ [\text{H}^+]=0.063$
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Question 321 Mark
Describe the effect of:
removal of CH3OH
on the equilibrium of the reaction:
$2\text{H}_2\text{ (g) + CO (g)}\rightleftharpoons\text{CH}_3\text{OH (g)}$
Answer
On removing CH3OH, the equilibrium will shift in the forward direction.
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Question 331 Mark
Calculate the hydrogen ion concentration in the following biological fluids whose pH are given below:
Human saliva, 6.4.
Answer
Human saliva, 6.4:
$\text{pH}=6.4$
$6.4=-\log[\text{H}^+]$
$[\text{H}^+]=3.98\times10^{-7}$
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Question 341 Mark
Write the expression for the equilibrium constant, Kc for each of the following reactions:
$\text{CH}_3\text{COOC}_2\text{H}_5\text{(aq)}+\text{H}_2\text{O(l)}\rightleftharpoons\text{CH}_3\text{COOH(aq)+}\text{C}_2\text{H}_5\text{OH(aq)}$
Answer
$\text{K}_{\text{c}}=\frac{[\text{CH}_3\text{COOH(aq)]}[\text{C}_2\text{H}_5\text{OH(aq)}]}{[\text{CH}_3\text{COOC}_2\text{H}_5\text{(aq)}][\text{H}_2\text{O(l)}]}$
$=\frac{[\text{CH}_3\text{COOH(aq)]}[\text{C}_2\text{H}_5\text{OH(aq)}]}{[\text{CH}_3\text{COOC}_2\text{H}_5\text{(aq)}]}$
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Question 351 Mark
Which of the followings are Lewis acids? H2O, BF3, H+, and $\text{NH}_4^+$
Answer
BF3, H+ and $\text{NH}_4^+$ are Lewis acids because they can accept a lone pair of electrons.
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Question 361 Mark
Write the expression for the equilibrium constant, Kc for each of the following reactions:
$\text{2Cu(NO}_3)_2\rightleftharpoons\text{2CuO (s) + 4NO}_2\text{ (g) + O}_2\text{ (g)}$
Answer
$\text{K}_{\text{c}}=\frac{[\text{CuO(g)]}^2[\text{NO}_2\text{(g)}]^4[\text{O}_2\text{(g)]}}{[\text{Cu(NO}_3)_2\text{}\text{(s)}]^2}=[\text{NO}_2\text{(g)}]^4[\text{O}_2\text{(g)}]$
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Question 371 Mark
Describe the effect of:
addition of CH3OH
on the equilibrium of the reaction:
$2\text{H}_2\text{ (g) + CO (g)}\rightleftharpoons\text{CH}_3\text{OH (g)}$
Answer
On addition of CH3OH, the equilibrium will shift in the backward direction.
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Question 381 Mark
Describe the effect of:
removal of CO
on the equilibrium of the reaction:
$2\text{H}_2\text{ (g) + CO (g)}\rightleftharpoons\text{CH}_3\text{OH (g)}$
Answer
On removing CO, the equilibrium will shift in the backward direction.
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Question 391 Mark
The equilibrium constant expression for a gas reaction is,
$\text{K}_{\text{c}}=\frac{[\text{NH}_3]^4[\text{O}_2]^5}{[\text{NO}]^4[\text{H}_2\text{O}]^6}$
Write the balanced chemical equation corresponding to this expression.
Answer
Balanced chemical equation for the reaction is 4
$4\text{NO (g) + 6H}_2\text{O (g)}\rightleftharpoons4\text{NH}_3\text{ (g) + 5O}_2\text{ (g)}$
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Question 401 Mark
Write the expression for the equilibrium constant, Kc for each of the following reactions:
$\text{2NOCl(g)}\rightleftharpoons\text{2NO (g) + Cl}_2\text{ (g)}$
Answer
$\text{K}_{\text{c}}=\frac{[\text{NO(g)]}^2[\text{Cl}_2\text{(g)}]}{[\text{NOCl(g)}]^2}$
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Question 411 Mark
Write the expression for the equilibrium constant, Kc for each of the following reactions:

$\text{Fe}^{3+}\text{(aq)}+3\text{OH}^-\text{(aq)}\rightleftharpoons\text{Fe(OH})_3\text{(S)}$

Answer
$\text{K}_{\text{c}}=\frac{[\text{Fe(OH})_3\text{(S)]}}{[\text{Fe}^{3+}\text{(aq)}][\text{OH}^-\text{(aq)}]^3}$
$=\frac{1}{[\text{Fe}^{3+}\text{(aq)}][\text{OH}^-\text{(aq)}]^3}$
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Question 421 Mark
What is the effect of temperature on solubility product (Ksp)?
Answer
Ksp increases with increase in temperature because solubility increases.
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Question 431 Mark
Classify the following as Lewis acid or Lewis base:
$\text{NH}_4^+\text{ and }\text{NH}_3$
Answer
$\text{NH}^+_4$ Lewis acid, whereas NH3 is Lewis base.
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Question 441 Mark
What happens to ionic product of water if some acid is added to it?
Answer
Ionic product will remain unchanged.
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Question 451 Mark
Under what conditions is a substance precipitated from its solution?
Answer
Precipitation takes place, when ionic product exceeds the solubility product.
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Question 461 Mark
Write expression of Kp for the reaction:
$\text{N}_2\text{O(g)}\rightleftharpoons2\text{NO}_2(\text{g})$
Answer
$\text{K}_{\text{p}}=\frac{(\text{P}_{\text{NO}_2})^2}{(\text{P}_{\text{N}_2\text{O}_4})}$
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Question 471 Mark
Why is solubility of AgI in NaI in less than that of pure water?
Answer
It is due to common ion effect. I- will combine with Ag+ to from AgI, therefore solubility of AgI will decrease.
$\text{A}_2\text{B}\rightleftharpoons2\text{A}^++\text{B}^{2-}\\'\text{s}'\ \ \ \ \ \ \ \ \ \ \ \text{2s}\ \ \ \ \ \ \ \ '\text{s}'$
$\text{K}_{\text{sp}}=[\text{A}^+]^2[\text{B}^{2-}]$
$32\times10^{-9}=4\text{s}^3$
$32\times10^{-9}=4\text{s}^{3}$
$\text{s}^3=8\times10^{-9}$
$\text{s}=2\times10^{-3}\text{mol L}^{-1}$
$[\because3\sqrt{8}=2]\text{ and }(10^{-9})\frac{1}{3}=10^{-3}$
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Question 481 Mark
For Tribasic acid Ka1 > Ka2 > Ka3 what will happen to the acid strength of polyprotic acids if protons are lost?
Answer
Acid strength will decrease because Ka2, is less than Ka1 and K a3 is less than Ka2
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Question 491 Mark
Which of the following is weakest acid?

$\text{HClO}_4,\text{HClO}_3,\text{HCl}_2,\text{HClO}$

Answer
HCl4O is weakest acid because Cl is in +1 oxidation state, i.e., lowest oxidation state.
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Question 501 Mark
Write the expression for the equilibrium constant (Kc) for the reaction:
$\text{CH}_3\text{COOC}_2\text{H}_5(\text{aq})+\text{H}_2\text{O(l)}\\\rightleftharpoons\text{CH}_3\text{COOH}(\text{aq})+\text{C}_2\text{H}_5\text{OH}(\text{aq})$
Answer
$\text{K}_{\text{c}}=\frac{[\text{CH}_3\text{COOH}][\text{C}_2\text{H}_5\text{OH}]}{[\text{CH}_3\text{COOC}_2\text{H}_2\text{H}_5][\text{H}_2\text{O}]}$
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Question 511 Mark
Write the equilibrium constant expression for following reaction:
$2\text{NOCl}(\text{g})\rightleftharpoons2\text{NO(g)}+\text{Cl}_2(\text{g})$
Answer
$\text{K}=\frac{[\text{NO}^2][\text{Cl}_2]}{[\text{NOCl}^2]}$
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Question 521 Mark
Why pH of our blood remains constant at 7.4 through we quite often eat spicy food?
Answer
Blood contains basic buffer which keep its pH constant.
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Question 531 Mark
Write Kp in terms of Kc for the following chemical reaction:
$2\text{SO}_2(\text{g})+\text{O}_2(\text{g})\rightleftharpoons2\text{SO}_3\text{(g)}$
Answer
$\text{K}_{\text{p}}=\text{K}_{\text{c}}(\text{RT}^{\Delta\text{n}})$
$\Delta\text{n}=2-3=-1$
$\text{K}_{\text{c}}(\text{RT})^{-1}$
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Question 541 Mark
$\text{SO}_3^{2-}$ is Bronsted base or acid and why?
Answer
$\text{SO}_3^{2-}$ is Bronsted base because it can accept H+.
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Question 561 Mark
Which of the following is strongest Lewis acid?
$\text{CCl}_4,\text{AlCl}_3,\text{NCl}_3,\text{OCl}_2$
Answer
AlCl3 is strongest Lewis acid because its octet is not complete.
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Question 571 Mark
Fizz is observed when soda water bottle is opened. Why?
Answer
Pressure is decreased, solubility of CO2 in water decreases, CO2 escapes from cold drink bottle.
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Question 581 Mark
Which of the following is strongest conjugate base?
$\text{CH}_3^-,\text{NH}^-_2,\text{OH}^-,\text{F}^-$
Answer
$\text{CH}_4^-$ is strongest conjugate base because CH4 is weakest acid, i.e., cannot donate H+ easily.
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Question 591 Mark
Write expression of Kc for reaction:
$\text{N}_2(\text{g})+3\text{H}_2(\text{g})\rightleftharpoons2\text{NH}_3(\text{g})$
Give units of K.
Answer
$\text{K}=\frac{[\text{NH}_3]^2}{[\text{N}_2][\text{H}_2]^3}$
$=\frac{(\text{mol L}^{-1})^2}{(\text{mol}^{-1})(\text{mol L}^{-1})^3}=\text{L}^2\text{mol}^{-2}$
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Question 601 Mark
How does common ion affect the solubility of electrolyte?
Answer
Solubility of electroyte decreases due to common ion effect.
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Question 611 Mark
Write the conjugate acid for the Bronsted base $\text{C}_6\text{H}_5\text{OH},\text{H}_2\text{O}$
Answer
$\ \ \ \ \ \ \ \ \oplus{}\ \ \ \ \ \ \ \ \ \ \oplus{}\\\text{C}_6\text{H}_5\text{OH}_2,\text{H}_3\text{O}$
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Question 621 Mark
If Qc < Kc, in which direction reaction will proceed?
Answer
If Qc < Kc, the reaction will proceed in the direction of products.
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Question 631 Mark
Which of the following is not Lewis base Ag+, H2O, CN-, NH3.
Answer
Ag+, It is Lewis acid because it is positively charged and can accept electrons.
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Question 641 Mark
Why is Lewis concept more useful than Bronsted Lowry concept?
Answer
Lewis concept includes some of compounds like BF3, BCl3, AlCl3 as acids which Bronsted Lowry concept does not.
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Question 651 Mark
Is it possible to get precipitate of Fe(OH)2 at pH = 2? Give reason.
Answer
No, Because Fe(OH)3 will dissolve in strongly acidic medium.
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Question 661 Mark
Is it possible to get precipitate of Fe(OH)3 at pH = 2? Give reason.
Answer
No, because Fe(OH)3 will dissolve in strongly acidic medium.
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