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7 questions · self-marked practice — reveal the answer and mark yourself.

Question 14 Marks
Column AColumn B
(1) Isochoric process(a) zero
(2) First law of thermodynamics(b) $d V=0$
(3) Density(c) $\Delta U = q + w$
(4) Enthalpy of formation of any element in transition state(d) intensive property
Answer
(1) (b), (2) (c), (3) (d), (4) (a).
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Question 24 Marks
Column AColumn B
(1) $\Delta H _s$(a) R
(2) $C _{ p }- C _{ V }$(b) System + surroundings
(3) Law of conservation of energy(c) $\Delta H _{ f }+\Delta H _V$
(4) Universe(d) First law of thermodynamics
Answer
(1) (c), (2) (a), (3) (d), (4) (b).
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Question 34 Marks
Column AColumn B
(1) Neutralization energy of HCl + NaOH(a) Heat exchange due to difference in temperature
(2) Formation of mixture of gases(b) 57.32 kJ
(3)$\Delta G$  > 0(c) increase in entropy
(4) Heat(d) non-spontaneous process
Answer
(1) (b), (2) (c), (3) (d), (4) (a).
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Question 44 Marks
Column AColumn B
(1) Enthalpy of solution(a) irreversible process
(2) Volume(b) decrease in entropy
(3) Spontaneous process(c) hydration enthalpy/ salvation enthalpy
(4) Crystallisation of sugar from solution(d) Extensive property
Answer
(1) (c), (2) (d), (3) (a), (4) (b),
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Question 54 Marks
Column AColumn B
(1) For isothermal reversible process(a) calculation of combustion energy
(2) Entropy change at equilibrium(b) $\begin{array}{l} W _{ rev }=-2303 nRT \\ \log \frac{ V _{ f }}{ V _{ i }}\end{array}$
(3) Ideal process(c) $\Delta S =0$
(4) Bomb calorimeter(d) reversible process
Answer
(1) (b), (2) (c), (3) (d), (4) (a).
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Question 64 Marks
Column AColumn B
(1) Spontaneous process(a) conversion of ice to water
(2) Entropy(b) $\Delta G$ negative
(3) Mechanical energy(c) Measure of disorder of system
(4) Isothermal process(d) conversion of mechanical energy to kinetic energy
Answer
(1) (b), (2) (c), (3) (d), (4) (a).
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Question 74 Marks
Column AColumn B
(1) Standard state of substance(a) $\Delta G =\Delta H - T \Delta S$
(2) Entropy of sublimation(b) 1 atm pressure and 298 K temperature
(3) Gibbs equation(c) non-crystalline
(4) Glass(d) $\Delta S _{\text {sub }}=\frac{\Delta H _{\text {(sub) }}}{ T }$
Answer
(1) (b), (2) (d), (3) (a), (4) (c).
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