Given, Temperature of A = 12°C Temperature of B = 19°C Temperature of C = 28°C Temperature of mixture of A and B = 16°C Temperature of mixture of B and C = 23°C Let the mass of the mixtures be M and the specific heat capacities of the liquids A, B and C be CA, CB, and CC, respectively. According to the principle of calorimetry, when A and B are mixed, we get Heat gained by Liquid A = Heat lost by liquid B ⇒ MCA(16 - 12) = MCB(19 - 16) ⇒ 4MCA = 3MCB $\Rightarrow\text{MC}_\text{A}=\Big(\frac{3}{4}\Big)\text{MC}_\text{B}\ \dots(1)$
When B and C are mixed, Heat gained by liquid B = Heat lost by liquid C ⇒ MCB(23 - 19) = MCC(28 - 23) ⇒ 4MCB = 5MCC $\Rightarrow\text{MC}_\text{C}=\Big(\frac{4}{5}\Big)\text{MC}_\text{B}\ \dots(2)$
When A and C are mixed, Let the temperature of the mixture be T. Then, Heat gained by liquid A = Heat lost by liquid C ⇒ MCA (T - 12) = MCC (28 - T) Using the values of MCA and MCC, we get From eqs. (1) and (2), $\Rightarrow\Big(\frac{3}{4}\Big)\text{MC}_\text{B}(\text{T}-12)=\Big(\frac{4}{5}\Big)\text{MC}_\text{B}(28-\text{T})$
$\Rightarrow\Big(\frac{3}{4}\Big)(\text{T}-12)=\Big(\frac{4}{5}\Big)(28-\text{T})$
$\Rightarrow(3\times5)(\text{T}-12)=(4\times4)(28-\text{T})$
$\Rightarrow15\text{T}-180=448-16\text{T}$
$\Rightarrow31\text{T}=628$
$\Rightarrow\text{T}=\frac{628}{31}=20.253^\circ\text{C}$
$\Rightarrow\text{T}=20.3^\circ\text{C}$