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Question 31 Mark
If two different reactions are carried out at the same temperature and the activation energy for both is also same, then will the rates of these reactions also be the same?
Answer
The rate of these reactions cannot be same because the rate constant also depends on pre-exponential factor (A), which is different for different reactions.
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Question 41 Mark
Give the formula for rate constant for the gaseous reaction $A \rightarrow B + C$.
Answer
$k=\frac{2.303}{t} \log \frac{P_i}{\left(2 P_i-P_t\right)}$
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Question 51 Mark
Why does the sugar powder dissolves faster than sugar crystals in a jar?
Answer
In the powder state, the surface area of sugar is more than that of crystals, hence it dissolves quickly in water.
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Question 61 Mark
For a reaction, if $t_{1 / 2} \propto[ R ]_0$ is 0 , then what will be the order of reaction?
Answer
Zero.
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Question 71 Mark
What is effective collision?
Answer
Those collisions which results in formation of product are called effective collisions.
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Question 81 Mark
In a reaction the energy of a sufficient number of molecules colliding is more than the threshold energy, yet the rate of the reaction is low, why?
Answer
The rate of the reaction is low because the orientation of the molecules is not correct.
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Question 91 Mark
What is threshold energy?
Answer
The minimum energy required for a reactant to be converted in to a product is called threshold energy.
Threshold energy = Energy of normal molecule + Activation energy
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Question 101 Mark
What will happen if there is an effective collision between all the molecules of the reactant in a reaction?
Answer
The reaction will occur at high rate and will be almost complete.
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Question 111 Mark
Give the formula to find half life of zero order reaction.
Answer
$t _{\frac{1}{2}}=\frac{[ R ]_0}{2 k }$
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Question 121 Mark
Give the formula for the rate constant of a zero order reaction.
Answer
Rate constant for zero order reaction :
$
k=\frac{[R]_0-[R]}{t}
$
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Question 131 Mark
What is the unit of rate constant of a first order reaction?
Answer
Time ${ }^{-1}\left(s^{-1}\right.$ or $\left.min ^{-1}\right)$.
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Question 141 Mark
What will be the order of radioactive disintegration reaction?
Answer
Radioactive disintegration reaction is always of first order.
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Question 151 Mark
Which term determines the rate of any reaction?
Answer
The slowest term in complex reactions is rate determining term because the rate of reaction is determined through the slow term.
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Question 161 Mark
What is differential rate equation?
Answer
The equation based on concentration of a reaction is called differential rate equation.
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Question 171 Mark
In which situation will any biomolecular reaction be of first order?
Answer
In a binary reaction, if any one reactant is taken in excess, the reaction will be of first order because the rate of the reaction will not depend on the concentration of this reactant.
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Question 181 Mark
Write one difference between molecularity and order of a reaction.
Answer
Molecularity of a reaction is always an integer whereas order is not necessarily to be an integer.
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Question 191 Mark
What is molecularity and order of the reaction is $2 NO + O _2$ ?
Answer
Both the order and molecularity of the reaction is 3.
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Question 201 Mark
What will be the effect on the rate of a zero order reaction if the concentration of reactant is tripled?
Answer
The rate of the reaction will remain unchanged because the rate of a zero order reaction does not depend on concentration.
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Question 211 Mark
What are the factors affecting the rate constant of a reaction?
Answer
The rate constant of reaction depends on the nature and temperature of the reactants.
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Question 221 Mark
The unit of rate constant of which type of reaction does not depend on concentration?
Answer
For first order reaction, the unit of rate constant $( k )$ is $s ^{-1}$, hence it does not depend on concentration.
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Question 231 Mark
If the rate constant and unit of reaction rate are same for a reaction, then what will be the order of the reaction?
Answer
This will be a zero order reaction, because for this reaction rate $=k$.
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Question 241 Mark
When is the average rate and instantaneous rate of a reaction is same?
Answer
When the time interval $\Delta t$ is very small (very close to zero), then the average and instantaneous rate of a reaction is same.
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Question 251 Mark
What is the order of decomposition of $N _2 O _5$ ?
Answer
Decomposition of $N _2 O _5$ is a first order reaction.
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Question 261 Mark
In a pseudo first order reaction in water, the following results were obtained :
t/s0306090
[A] mol L-10.550.310.170.085
Calculate the average rate of reaction between the time interval 30 to 60 seconds.
Answer
Average rate $=\left(r_{a v}\right)=-\frac{\Delta[R]}{\Delta t}=\frac{c_2-c_1}{\Delta t}$
$=-\frac{(0.17-0.31)}{60-30}=-\frac{(-0.14)}{30}$
$\begin{array}{l}=4.666 \times 10^{-3} \\ =4.67 \times 10^{-3} mol L ^{-1} s^{-1}\end{array}$
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