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Question 12 Marks
What is Schottky defect? Explain with example.
Answer
This defect is created in the crystal when the same number of cations and anions are missing from their positions and thus holes (called cation vacancy or anion vacancy) are produced. Since the number of cations and anions that are left in the crystal even after the missing of cations and anions is the same, the crystal remains electrically neutral. The production of two holes, one due to the missing of a cation and the other due to the missing of an anion. Examples of ionic crystals having Schottky defect are NaCl, KCI, KBr, CsCl etc.
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Question 22 Marks
What are network solids? Give an example.
Answer
Covalent or Network Solids: In this type of solids the constituent particles are atoms of same or different elements connected to each other by covalent bond network. The atoms interlocked by a network of covalent bonds produce a crystal which is considered to be a single giant molecule. Example of covalent solid is Diamond.
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Question 32 Marks
What do you mean by point defect in a crystal?
Answer
Point defects are imperfections in the structure of a material at specific points within its lattice. These defects can arise due to missing atoms (vacancies), extra atoms (interstitials), or atoms occupying irregular positions (substitutional defects). They influence material's properties such as electrical conductivity and mechanical strength.
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Question 42 Marks
Lithium forms bcc crystals. Calculate the atomic radius of lithium if the length of the side of a unit cell of lithium is 351 pm.
Answer
$a=351 pm$
$r=\frac{a \sqrt{3}}{4}$
$=\frac{351 \times \sqrt{3}}{4}$
$=\frac{351 \times 1.732}{4}$
$=151.98 pm$
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Question 52 Marks
Differentiate between tetrahedral voids and octahedral voids.
Answer
Differentiate between tetrahedral voids and octahedral voids
Tetrahedral VoidsOctahedral Voids
These voids are surrounded by four spheres which lie at the vertices of a regular tetra-hedron. There are two tetra-hedral voids per atom in a crystal and the radius ratio is 0.225.These voids are surrounded by six spheres and formed by a combination of two triangular voids of the first and second layer. There is one octahedral void per atom in a crystal. The radius ratio $\left(\frac{r_{\text {void }}}{r_{\text {sphere }}}\right)$ is 0.414.
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2 Marks Questions - Chemistry STD 12 Science Questions - Vidyadip