Question 14 Marks
A sample contains a mixture of $^{108}Ag$ and $^{110}Ag$ isotopes each having an activity of $8.0 \times 10^8$ disintegration per second. $^{110}Ag$ is known to have larger half$-$life than $^{108}Ag$. The activity A is measured as a function of time and the following data are obtained.
| Time $(s)$ | $Activity (A) (10^8 disinte- grations s^{-1})$ | Time $(s)$ | $Activity (A) (10^8 disinte-grations s^{-1})$ |
| $20$ | $11.799$ | $200$ | $3.0828$ |
| $40$ | $9.1680$ | $300$ | $1.8899$ |
| $60$ | $7.4492$ | $400$ | $1.1671$ |
| $80$ | $6.2684$ | $500$ | $0.7212$ |
| $100$ | $5.4115$ |
- Plot ln $\Big(\frac{\text{A}}{\text{A}_0}\Big)$ versus time.
- See that for large values of time, the plot is nearly linear. Deduce the half-life of $^{110}Ag$ from this portion of the plot.
- Use the half-life of $^{110}Ag$ to calculate the activity corresponding to $^{108}Ag$ in the first $50s.$
- Plot In $\Big(\frac{\text{A}}{\text{A}_0}\Big)$ versus time for $^{108}Ag$ for the first 50s.
- Find the half-life of $^{108}Ag.$
Answer
View full question & answer→Activities of sample containing $^{108}Ag and ^{110}Ag$ isotopes $= 8.0 \times 10^8$ disintegration/sec.
The activity $\text{A = A}_{0}\text{e}^{-\lambda\text{t}}=8\times10^8\times\text{e}^{-0.0284\times50}=1.93\times10^8$
- Here we take $A = 8 \times 108 dis./sec$
- $\text{ln}\Big(\frac{\text{A}_1}{\text{A}_{0_{1}}}\Big)=\text{ln}\Big(\frac{11.79}{8}\Big)=0.389$
- $\text{ln}\Big(\frac{\text{A}_2}{\text{A}_{0_{2}}}\Big)=\text{ln}\Big(\frac{9.1680}{8}\Big)=0.1362$
- $\text{ln}\Big(\frac{\text{A}_3}{\text{A}_{0_{3}}}\Big)=\text{ln}\Big(\frac{7.4492}{8}\Big)=-0.072$
- $\text{ln}\Big(\frac{\text{A}_4}{\text{A}_{0_{4}}}\Big)=\text{ln}\Big(\frac{6.2684}{8}\Big)=-0.244$
- $\text{ln}\Big(\frac{5.4115}{8}\Big)=-0.391$
- $\text{ln}\Big(\frac{3.0828}{8}\Big)=-0.954$
- $\text{ln}\Big(\frac{1.8899}{8}\Big)=-1.443$
- $\text{ln}\Big(\frac{1.167}{8}\Big)=-1.93$
- $\text{ln}\Big(\frac{0.7212}{8}\Big)=-2.406$
- The half life of $^{110}Ag$ from this part of the plot is $24.4s.$
- Half life of $^{110}Ag = 24.4s.$
The activity $\text{A = A}_{0}\text{e}^{-\lambda\text{t}}=8\times10^8\times\text{e}^{-0.0284\times50}=1.93\times10^8$
- The half life period of $^{108}Ag$ from the graph is $144s.$