$\therefore$ Number of ways in which three letters can be inserted randomly into three envelopes = 3! = 6
Out of three letters insertion of one letter into proper envelope can be done in $\style{font-size:28px}{{}^3C_1=3}$ ways, and insertion of other two letters into wrong envelope can be done in one way.
$\therefore$ Number of ways in which one letter can be inserted into proper envelope and other two in wrong envelopes =$\style{font-size:28px}{{}^3C_1\times1=3}$
Also, number of ways in which two letters can be inserted into proper envelopes = 1
Number of ways in which atleast one letter is in proper envelope = 3 + 1 = 4
Thus the required probability that atleast one letter is in its proper envelope = $\style{font-size:24px}{\frac46=\frac23}$