d
At constant pressure
$W=n R \Delta T=66$
$\Delta U=n\left(C_V\right)_{\text {mix }} \Delta T$
$\left(C_v\right)_{\text {mii }}=\frac{n_1 C_{v_1}+n_2 C_{v_2}}{n_1+n_2}$
$\left(C_v\right)_{\text {mii }}=\frac{2 \times \frac{3}{2} R+1 \times \frac{5}{2} R}{3}$
$\left(C_v\right)_{\text {min }}=\frac{11}{6} R$
$\Delta U=\frac{11}{6}(n R \Delta T)$
$\Delta U=\frac{11}{6} \times 66=121 J$