- ✓$SO_2$
- B$SO_3$
- C$CO_2$
- D$NH_3$
Anode $\left\{\begin{array}{c}2 \mathrm{H}_{2} \mathrm{SO}_{4} \rightarrow \mathrm{H}_{2} \mathrm{S}_{2} \mathrm{O}_{8}+2 \mathrm{H}^{+}+2 \mathrm{e}^{-} \\ 2 \mathrm{H}_{2} \mathrm{O} \rightarrow \mathrm{O}_{2}+4 \mathrm{H}^{+}+4 \mathrm{e}^{-}\end{array}\right\}$
Cathode $\left\{2 \mathrm{H}_{2} \mathrm{O} \rightarrow \mathrm{H}_{2}+2 \mathrm{OH}^{-}-2 \mathrm{e}^{-}\right\} \times 3$
Net: $2 \mathrm{H}_{2} \mathrm{SO}_{4}+8 \mathrm{H}_{2} \mathrm{O} \rightarrow \mathrm{H}_{2} \mathrm{S}_{2} \mathrm{O}_{8}+\mathrm{O}_{2}+3 \mathrm{H}_{2}+6 \mathrm{H}^{+}+6 \mathrm{OH}^{-}$
Hence ratio of $\mathrm{n}_{\mathrm{O}_{2}}$ and $\mathrm{n}_{\mathrm{H}_{2}}$ is $1: 3 .$
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Statement $I :$ The $E ^{\circ}$ value of $Ce ^{4+} / Ce ^{3+}$ is $+1.74 \,V$
Statement $II :$ $Ce$ is more stable in $Ce ^{4+}$ state than $Ce ^{3+}$ state.
In the light of the above statements, choose the most appropriate answer from the options given below