Question
A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of the container is suddenly increased.
How do rates of evaporation and condensation change initially?

Answer

On increasing the volume of the container, the rate of evaporation will increase initially because now more space is available. Since the amount of the vapours per unit volume decrease on increasing the volume, therefore, the rate of condensation will decrease initially.

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