Question
A violet colour compound is formed in detection of $S$ in a compound:
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Answer
$\ce{Na2S + Na2[Fe(CN)5NO] \rightarrow Na4[Fe(CN)5NOS}]\ ($Violet Color Compond$)$.
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$\text{E}^\ominus_{\text{cr}_2\text{O}^{2-}_7/\text{cr}^{3+}}=1.33\text{V}\ \ \ \text{E}^\ominus_{\text{Cl}_2/\text{Cl}^-}=1.36\text{V}$
$\text{E}^\ominus_{\text{MnO}^-_4/\text{Mn}^{2+}}=1.51\text{V}\ \ \ \ \text{E}^\ominus_{\text{Cr}^{3+}/\text{Cr}}=-0.74\text{V}$
→$\text{E}^\ominus_{\text{cr}_2\text{O}^{2-}_7/\text{cr}^{3+}}=1.33\text{V}\ \ \ \text{E}^\ominus_{\text{Cl}_2/\text{Cl}^-}=1.36\text{V}$
$\text{E}^\ominus_{\text{MnO}^-_4/\text{Mn}^{2+}}=1.51\text{V}\ \ \ \ \text{E}^\ominus_{\text{Cr}^{3+}/\text{Cr}}=-0.74\text{V}$
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