- ✓$C{H_3}COCl$
- B$CHC{l_2}COOH$
- C$C{H_2}ClCOOH$
- D$C{H_3}COOCl$
$\mathop {C{H_3}COOH}\limits_{Aceticacid} + \mathop {PC{l_5}}\limits_{\begin{subarray}{l}
Phosphorus \\
pentachloride
\end{subarray}} \to \mathop {C{H_3}COCl}\limits_{\begin{subarray}{l}
Acetyl \\
Chtoride
\end{subarray} } + \mathop {HCl}\limits_{\begin{subarray}{l}
Hydro - Chtortic \\
acid
\end{subarray}} +\mathop {POC{l_3}}\limits_{\begin{subarray}{l}
Phosphoryl \\
chtoride
\end{subarray} }$
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Statement $I :$ The nucleophilic addition of sodium hydrogen sulphite to an aldehyde or a ketone involves proton transfer to form a stable ion.
Statement $II :$ The nucleophilic addition of hydrogen cyanide to an aldehyde or a ketone yields amine as final product.
In the light of the above statements, choose the most appropriate answer from the options given below :
Assertion $(A)$ : Experimental reaction of $CH _{3} Cl$ with aniline and anhydrous $AlCl _{3}$ does not give $o$ and $p-methylaniline$.
Reason $(R)$ : The - $NH _{2}$ group of aniline becomes deactivating because of salt formation with anhydrous $AlCl _{3}$ and hence yields $m$-methyl aniline as the product.
In the light of the above statements, choose the most appropriate answer from the options given below.