i. e. carbanion formed.
$2,4,6$ -trinitrophenol after the loss of a proton gives $2,4,6$ -trinitrophenoxide ion which is stabilised by resonance, $-l-$effect and $- M-$effect, thus is most acidic among the given compounds.
Phenol after losing a proton form phenoxide ion which is also stabilised by resonance, $- M$ and $-I$ effects but is less stabilised as compared to
$2,4,6$ -trinitrophenoxide ions. Thus, it is less acidic as compared to $2,4,6$ -trinitrophenol. $\left(C H_{3} C O O H\right)$ after losing a proton gives acetate
ion which is stabilised by only resonance. However, it is more resonance stabilised as compared to a phenoxide ion, thus more acidic as compared to phenol. $2,4,6$ -trinitrophenol, however, is more acidic than acetic acid due to the presence of three
electron withdrawing $-N O_{2}$ groups. Cyclohexanol gives an anion that is least stable among the given, thus, it is least acidic.
Hence, the correct order of acidic strength is
$2,4,6$ -trinitrophenol > acetic acid > phenol > cyclohexanol
$I I I>I I>I V>I$
સૂચિ$-I$ (પ્ર્કિયકો) |
સૂચિ$-II$ (નિપજો) |
($A$) ફિનોલ, $\mathrm{Zn} / \Delta$ |
$(I)$ સેલિસાલ્ડીહાઈડ |
($B$)ફિનોલ $\mathrm{CHCl}_3, \mathrm{NaOH}, \mathrm{HCl}$ |
$(II)$ સેલિસિલિક એસિડ |
($C$)ફિનોલ, $\mathrm{CO}_2, \mathrm{NaOH}, \mathrm{HCl}$ |
$(III)$ બેન્ઝિન |
($D$)ફિનોલ, સાંદ્ર . $\mathrm{HNO}_3$ |
$(IV)$ પિક્રિક એસિડ |
નીચે આપેલા વિકલ્પોમાંથી સાચો જવાબ પસંદ કરો.