MCQ
Although benzene is highly unsaturated it does not undergo addition reactions. The explanation of this can be suggested as:
  • A
    $\pi$-electrons of benzene ring are delocalised.
  • B
    Since $\pi$-electrons are present inside the ring, addition cannot take place.
  • C
    Cyclic structures do not show addition reactions
  • D
    Benzene is not a reactive compound.

Answer

  1. $\pi$-electrons of benzene ring are delocalised.

​​​​​​Explanation:

$\pi$-electrons of the benzene ring are delocalised.

There are delocalised π-electrons above and below the plane of the ring. The presence of the delocalised $\pi$-electrons makes benzene particularly stable.

Benzene resists addition reactions because that would involve breaking the delocalisation and losing that stability.

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