MCQ
Ammonium carbamate $(NH_4COONH_2)$ when heated to $200\,^oC$ gives a mixture of $NH_3$ and $CO_2$ with a vapour density of $26$ at equilibrium. What is the degree of dissociation of ammonium carbamate ?
  • A
    $2/3$
  • $0.25$
  • C
    $0.5$
  • D
    $1$

Answer

Correct option: B.
$0.25$
b
$\mathrm{D}_{t}=\frac{\mathrm{M.} \mathrm{W.}}{2}=\frac{78}{2}=39, \mathrm{D}_{0}=26$

$\alpha=\frac{D_{t}-D_{0}}{D_{0}(n-1)}$

$\alpha=\frac{39-26}{26(3-1)}=\frac{13}{52}=\frac{1}{4}$

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