Question
Answer the following questions.
A non-reducing disaccharide ‘A’ on hydrolysis with dilute acid gives an equimolar mixture of D-(+)-glucose and D-(-)-fructose.
$\text{A}+\text{H}_2\text{O}\xrightarrow{\text{HCl}\ \ \ \ }\ \ \ \ \ \ \text{C}_6\text{H}_{12}\text{O}_6+\ \ \ \ \ \ \text{C}_6\text{H}_{12}\text{O}_6\\ [\alpha]_{\text{D}}=+66.5\hat{\text{O}}\phi\Omega\ \ \ \ \ +52.5\hat{\text{O}}\phi\Omega\ \ \ \ \ -92.4\hat{\text{O}}\phi\Omega$
Identify A. What is the mixture of D-(+)-glucose and D-(-)-fructose known as? Name the linkage that holds the two units in the disaccharide.

Answer

  1. $A = C_{12}H_{22}O_{11}$ (sucrose).
  2. Invert sugar.
  3. Glycosidic linkage.

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