H4P2O7
H4P2O7
Then, we have
4(+1) + 2(x) + 7(-2) = 0
⇒ 4 + 2x - 14 = 0
⇒ 2x = +10
⇒ x = +5
Hence, the oxidation number of P is +5.
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$\Delta_\text{f}\text{H}^\circ$ of KF = -560.8kJ mol-1, Sublimation energy of K = 87.8kJ mol-1, Dissociation energy of F, is 158.9kJ mol-1, Lattice energy of KF is -807.5kJ mol-1 and Ionisation energy of K is 414.2kJ mol-1.
| Elements | $\Delta\text{H}_{1}$ | $\Delta{\text{H}}_{2}$ | $\Delta_{\text{eg}}\text{H}$ |
| I | 520 | 7300 | -60 |
| II | 419 | 3051 | -48 |
| III | 1681 | 3374 | -328 |
| IV | 1008 | 1846 | -295 |
| V | 2372 | 5251 | +48 |
| VI | 738 | 1451 | -40 |

$\text{Li(s)}+\frac{1}{2}\text{F}_2(\text{g})\overrightarrow{\ \ \ \ \ \ \ }\ \text{LiF(s)}$
$\text{Li(s)}\overrightarrow{\ \ \ \ \ \ \ \ }\ \text{Li(g)};$ $\Delta_\text{s}\text{H}^\circ=155\text{kJ mol}^{-1}$
$\frac{1}{2}\text{F}_2(\text{g})\overrightarrow{\ \ \ \ \ \ \ }\ \text{F(g)};$ $\Delta\text{H}^\circ=75\text{kJ}$
$\text{Li(g)}\overrightarrow{\ \ \ \ \ } \ \text{Li}^{+}(\text{g})+\text{e}^-;$ $\Delta\text{H}^\circ=520\text{kJ mol}^{-1}$
$\text{F(g)}+\text{e}^-\overrightarrow{\ \ \ \ \ \ } \ \text{F}^-(\text{g});$ $\Delta\text{H}^\circ=-333\text{kJ mol}^{-1}$
$\text{Li}^+\text{(g)}+\text{F}^-(\text{g})\overrightarrow{\ \ \ \ \ \ \ \ }\ \text{LiF(s)};$ $\Delta\text{H}^\circ=-1012\text{kJ mol}^{-1}$