Question
Assign oxidation number to the underlined elements in the following species:

NaH2PO4

Answer

Let the oxidation number of P be x.

We know that,

Oxidation number of Na = +1

Oxidation number of H = +1

Oxidation number of O = -2

$\begin{matrix}\ \ +1&+1&\text{x}&-2\\\Rightarrow\ \text{Na}& \ \ \text{ H}_2 &\text{P}&\ \text{ O}_4\end{matrix}$

Then, we have

1(+1) + 2(+1) + 1(x) + 4(-2) = 0

⇒ 1 + 2 + x - 8 = 0

⇒ x = +5

Hence, the oxidation number of P is +5.

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