MCQ
At $90\,^oC$ pure water has $H_3O^+ = 10^{-6}\, mol\, litre^{-1}$. The value of $K_w$ at $90\,^oC$ is
- A$10^{-6}$
- ✓$10^{-12}$
- C$10^{-14}$
- D$10^{-8}$
and for pure $\mathrm{H}_{2} \mathrm{O},\left[\mathrm{H}^{+}\right]=\left[\mathrm{OH}^{-}\right]$
$\therefore \mathrm{K}_{\mathrm{w}}=\left[\mathrm{H}^{+}\right]^{2}=\left(10^{-6}\right)^{2}$
$=10^{-12}$
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$PCl_5 \longrightarrow PCl_4^+ + Cl^-$