Question
At room temperature hydrogen fluoride is a liquid while all other hydrogen halides are gases.

Answer

  • Fluorine has the highest electronegativity compared to remaining halogens.
  • H-F bond has the highest bond polarity compared to other halides.
  • The presence of strong intermolecular hydrogen bonding leads to the association of HF molecules as follows :
    Image
  • Other hydrogen halides do not show hydrogen bonding due to their larger atomic size and less electronegativity.
Hence HF is a liquid while other hydrogen halides (HCl to HI) are gases.

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