MCQ
Auto-oxidation of bleaching powder gives
- Aonly calcium chlorate
- ✓only calcium chloride
- Conly calcium hypochlorite
- Dboth $(A)$ and $(B)$
$Br_2 + Cl_2 \to 2BrCl$
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| Column $-I$ | Column $-II$ | ||
| $(a)$ | $[Pt(NH_3)_3Cl]Br$ | $(P)$ | Coordination isomerism |
| $(b)$ | $[Cr(NH_3)_5(NCS)]^{+2}$ | $(Q)$ | Ionisation isomerism |
| $(c)$ | $[Co(H_2O)_6]Cl_3$ | $(R)$ | Linkase isomerism |
| $(d)$ | $[PtCl_4] [Pt(NH_3)_4]$ | $(S)$ | Hydrated isomerism |
$\begin{array}{*{20}{c}}{CHO}\\|\\{HCOH}\\|\\{HOCH}\\|\\{HCOH}\\|\\{C{H_2}OH}\\I\end{array}$ $\begin{array}{*{20}{c}}{CHO}\\|\\{HCOH}\\|\\{HCOH}\\|\\{HOCH}\\|\\{C{H_2}OH}\\{II}\end{array}$ $\begin{array}{*{20}{c}}{CHO}\\|\\{HCOH}\\|\\{HCOH}\\|\\{HCOH}\\|\\{C{H_2}OH}\\{III}\end{array}$
takes places through the mechanism given below :
$NO + Br _2 \Leftrightarrow NOBr _2 \text { (fast) }$
$NOBr _2+ NO \rightarrow 2 NOBr \text { (slow) }$
The overall order of the reaction is $.....$.
