MCQ
Benzene can react with
  • A
    $B{r_2}$ water
  • $HN{O_3}$
  • C
    ${H_2}O$
  • D
    $C{H_3}OH$

Answer

Correct option: B.
$HN{O_3}$
b
$A.$ If double bonds were present then benzene would react in a similar way to alkenes, decolourising bromine water. However this does not happen as benzene doesn't react with bromine. Benzene cannot react in any other electrophilic addition reaction.

$B.$ Benzene reacts with concentrated nitric acid at $323-333\, k$ in the presence of concentrated sulphuric acid to form nitrobenzene. This reaction is known as nitration of benzene

$C.$ Benzene is nonpolar and water is highly polar. If we add benzene to water, benzene will float on the top of the water with no apparent mixing.

$D.$ The alkylation reaction of benzene with methanol to produce toluene: $Y - C$ and $Y - C _{ cs }$ catalyst. The secondary reaction of toluene is difficult to be suppressed in benzene alkylation with methanol over conventional acidic zeolite catalysts. Moreover, the formation of coke yet remains a challenging problem.

Therefore on seen the all above option, we find $NO _3$ is best Suitable option.

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