- AAt a slower rate
- BAt a faster rate
- CWith equal rate
- DWith equal rate (or) different rate depending upon the temperature.
Explanation:
Bromination of an alkane occurs at a slower rate than chlorination of an alkane.
As we know that halogenation involves the formation of a carbon-halogen bond. Now, the ease of halogenation will certainly depend on the carbon-halogen bond strength.
Bond formation energy of C−Cl is higher than that of C−Br bond.
So, the ease of bromination is lower than the ease of chlorination.
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Then, which of the following is correct?
$\begin{array}{*{20}{c}}
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{H_3}} \\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|} \\
{C{H_3} - CH - C{H_2} - C - C{H_3}} \\
{\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|} \\
{\,\,\,\,\,\,\,OH\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,OH\,}
\end{array}$ and $\begin{array}{*{20}{c}}
{C{H_2} - CH - C{H_2}} \\
{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,} \\
{CN\,\,\,\,\,\,\,\,CN\,\,\,\,\,\,\,\,CN\,\,}
\end{array}$
