b
${\text{CaC}}{{\text{O}}_3}({\text{s}})\overset \Delta \longleftrightarrow {\text{CaO}}({\text{s}}) + {\text{C}}{{\text{o}}_2}({\text{g}}) \uparrow ,{{\text{K}}_{\text{p}}} = 8 \times {10^{ - 2}}$
$\mathrm{K}_{\mathrm{p}}$ will be due to $\mathrm{CO}_{2}(\mathrm{g})$
So, $\left[\mathrm{P}_{\mathrm{CO}_{2}}\right]=8 \times 10^{-2}$
$\mathrm{CO}_{2}(\mathrm{g})+\mathrm{C}(\mathrm{s}) \rightleftharpoons 2 \mathrm{CO}(\mathrm{g}), \mathrm{K}_{\mathrm{p}}=2$
$\mathrm{K}_{\mathrm{p}}=\frac{\left[\mathrm{P}_{\mathrm{CO}}\right]^{2}}{\left[\mathrm{P}_{\mathrm{CO}_{2}}\right]} \quad \mathrm{K}_{\mathrm{P}}=\frac{\left[\mathrm{P}_{\mathrm{CO}}\right]^{2}}{0.08}=2$
$\left[\mathrm{P}_{\mathrm{CO}}\right]^{2}=2 \times 0.08 \quad[\mathrm{PCO}]=\sqrt{0.16}=0.4$
Partial press. of $\mathrm{CO}=0.4$