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Explain solubility of haloalkane.
Out of $C _6 H _5 CH _2 Cl$ and $C _6 H _5 CHClC _6 H _5$, which is more easily hydrolysed by aqueous KOH ?
Nitrogen pentoxide decomposes according to equation: $\text{2N}_{2}\text{O}_{5}\text{(g)}\rightarrow\text{4NO}_{2}\text{(g)}+\text{O}_{2}\text{(g)}.$
This first order reactionwas allowed to proceed at $40^\circ C$ and the data below were collected:
$[N_2O_5](M)$ Time $(min)$
$0.400$ $0.00$
$0.289$ $20.0$
$0.209$ $40.0$
$0.151$ $60.0$
$0.109$ $80.0$
  1. Calculate the rate constant. Include units with your answer.
  2. What will be the concentration of $N_2O_5 $ after $100$ minutes?
  3. Calculate the initial rate of reaction.
Accomplish the following conversion:
Benzene to m-bromophenol.
How are interhalogen compounds formed? What general compositions can be assigned to them?
Give the general formula of diazonium salt. State the possible negative ions present in this salt and explain with an example how diazonium salts are named.
Give the structures of A, B and C in the following reaction:
$\text{CH}_3\text{COOH}\xrightarrow[\Delta]{\text{NH}_3}\text{A}\xrightarrow[]{\text{NaOBr}}\text{B}\xrightarrow[]{\text{NaNO}_2/\text{HCl}}\text{C}$
Match the reactions given in Column $I$ with the suitable reagents given in Column $II.$ 
 
Column $I ($Reactions$)$
 
Column $II ($Reagents$)$
$(i)$
Benzophenone $\rightarrow$ Diphenylmethane
$(a)$
$\ce{LiAlH_4}$
$(ii)$
enzaldehyde $\rightarrow 1-$Phenylethanol
$(b)$
$\ce{DIBAL-H}$
$(iii)$
Cyclohexanone $\rightarrow$ Cyclohexanol
$(c)$
$\ce{Zn(Hg)/Conc. HCl}$
$(iv)$
Phenyl benzoate $\rightarrow$ Benzaldehyde
$(d)$
$\ce{CH_3MgBr}$
Explain Pseudo first order reaction with example.
Derive nernst equation for general reaction $a A+b B \rightarrow c C+d D$