Consider the following reaction sequence,
IIT 2022, Advanced
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- 1The increasing basicity order of the following compounds isView Solution
$(1)$ $C{H_3}C{H_2}N{H_2}$ $(2)$ $\begin{array}{*{20}{c}}
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{H_2}C{H_3}}\\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,}\\
{\,C{H_3}C{H_2}NH\,\,\,\,\,\,\,}
\end{array}$$(3)$ $\begin{array}{*{20}{c}}
{\,\,\,\,\,\,\,C{H_3}}\\
{\,|}\\
{{H_3}C - N - C{H_3}}
\end{array}$ $(4)$ $\begin{array}{*{20}{c}}
{\,\,\,\,\,\,\,C{H_3}}\\
{\,|}\\
{Ph - N - H}
\end{array}$ - 2View SolutionThe amine formed from an amide by means of bromine and alkali has
- 3Which one doesn't liberate $N{H_3}$ when undergoes hydrolysisView Solution
- 4Given below are two statements:View Solution
Statement $I$ : Aniline does not undergo Friedel-Crafts alkylation reaction.
Statement $II$ : Aniline cannot be prepared through Gabriel synthesis.
In the light of the above statements, choose the correct answer from the options given below:
- 5View SolutionWhich of the following compound do not gives isocyanide test
- 6View SolutionThe order of basicity of amines in gaseous state is
- 7$(i)$ chlorobenzene is mono-nitrated to $M$View Solution
$(ii)$ nitrobenezene is mono-chlorinated to $N$
$(iii)$ anisole is mono-nitrated to $P$
$(iv)\, 2-$ nitrochlorobenzene is mono-nitrated to $Q.$
Out of $M, N, P$ and $Q$ the compound that undergoes reaction with $aq. NaOH$ fastest is - 8Number of compounds from the following which cannot undergo Friedel-Crafts reactions is ............ toluene, nitrobenzene, xylene, cumene, anline, chlorobenzene, $m$-nitroaniline, $m$-dinitrobenzeneView Solution
- 9$(A)\xrightarrow[{\begin{array}{*{20}{c}}View Solution
{(2){\kern 1pt} A{g_2}O/{H_2}O} \\
{(3){\kern 1pt} \Delta }
\end{array}}]{{(1){\kern 1pt} \,excess\,{\kern 1pt} C{H_3}I/{K_2}C{O_3}}}(B)$ $\xrightarrow[{(iii){\kern 1pt} \Delta }]{{\begin{array}{*{20}{c}}
{(i){\kern 1pt} excess{\kern 1pt} C{H_3}I/{K_2}C{O_3}} \\
{(ii){\kern 1pt} A{g_2}O}
\end{array}}}$ $\begin{array}{*{20}{c}}
{{H_2}C = CH - CH - CH = C{H_2}} \\
{|{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} } \,\,\,\,\\
{{\mkern 1mu} {\mkern 1mu} C{H_3}}
\end{array}$Identify $A$
- 10View SolutionWhich of the following give hofmann's degradation reaction