Question
Describe laboratory method for preparation of ammonia.

Answer

Ammonia is prepared on laboratory scale by decomposition of the ammonium salts with calcium hydroxide or caustic soda.
i. $\underset{\substack{\text { Ammonium } \\ \text { chloride }}}{2 NH _4 Cl }+\underset{\text { hydroxide }}{ Ca ( OH )_2} \longrightarrow \underset{\text { Ammonia }}{2 NH _3}+\underset{\substack{\text { Calcium } \\ \text { chloride }}}{ CaCl _2}+2 H _2 O$
ii. $\underset{\substack{\text { Ammonium } \\ \text { sulphate }}}{\left( NH _4\right)_2 SO _4}+\underset{\begin{array}{c}\text { Sodium } \\ \text { Hydroxide } \\ \text { (caustic soda) }\end{array}}{2 NaOH } \longrightarrow \underset{\text { Ammonia }}{2 NH _3}+\underset{\begin{array}{c}\text { Sodium } \\ \text { sulphate }\end{array}}{ Na _2 SO _4}+2 H _2 O$

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