Question
Describe the physical properties of amines.

Answer

SELF

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Calculate the depression in the freezing point of water when $10\ g$ of $CH_3CH_2CHClCOOH$ is added to $250\ g$ of water. $K_a = 1.4 \times 10^{–3},\ K_f = 1.86\ K\ kg\ mol^{–1}.$
Explain the relationship between $\Delta G$ and $E _{\text {cell }}^{\circ}$ with the help of an example.
How will you distinguish between the following pairs of terms:
  1. Hexagonal close-packing and cubic close-packing?
  2. Crystal lattice and unit cell?
  3. Tetrahedral void and octahedral void?
Using crystal field theory, draw energy level diagram, write electronic configuration of the central metal atom/ion and determine the magnetic moment value in the following:
  1. $[\text{CoF}_6]^{3-}, [\text{Co(H}_2\text{O})_6]^{2+}, [\text{Co(CN)}_6]^{3-}$
  2. $[\text{FeF}_6]^{3-}, [\text{Fe(H}_2\text{O})_6]^{2+}, [\text{Fe(CN})_6]^{4-}$
Answer the following question:
Arrange the following in order of property indicated for each set:
  1. $F_2, Cl_2, Br_2, I_2$-increasing bond dissociation enthalpy.
  2. $HF, HCl, HBr, HI$-incre acid strength.
  3. $NH_3, PH_3, AsH_3, SbH_3, BiH_3​​​​​​​$​​​​​​​-increasing base strength.asing acid strength.
What is crystal field theory? On the basis of this, explain the crystal field splitting in octahedral coordinaton compounds.
The time required for $10 \%$ completion of a first order reaction at $298 K$ is equal to that required for its $25 \%$ completion at $308 K $. If the value of A is $4 \times 10^{10} S^{-1}$. Calculate k at $318 K $ and $E _{ a }$.
  1. Following are the transition metal ions of $3d$ series:
$Ti^{4+}, V^{2+}, Mn^{3+}, Cr^{3+}$

$($Atomic numbers : $Ti = 22, V = 23, Mn = 25, Cr = 24)$

Answer the following:
  1. Which ion is most stable in an aqueous solution and why?
  2. Which ion is a strong oxidising agent and why?
  3. Which ion is colourless and why?
  1. Complete the following equations:
  1. $2\text{ }\text{MnO}_4^-+16\text{ }\text{H}^++5\text{ }\text{S}^{2-}\xrightarrow{\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }\text{ }}$
  1. $\text{KMnO}_4\xrightarrow{\text{ }\text{ }\text{ }\text{ }\text{ }\text{heat}\text{ }\text{ }\text{ }\text{ }\text{ }}$
$(a).$ An experiment was carried out in the laboratory, to study depression in freezing point. $1 \ M$ aqueous solution of $Al(NO_3)_3$ and $1 \ M$ aqueous solution of glucose were taken. From the given figure identify solution $1.$ and solution $2.$ Give a plausible reason for your answer
Image
$(b).$ The osmotic pressure of a solution of cane sugar was found to be $2.46 \ atm$ at $300 \ K.$ If the solution was diluted five times, calculate the osmotic pressure at the same temperature.
How can the osmotic pressure of the given cane sugar solution be decreased without changing its volume? Give a reason for your answer.
What is the role of adsorption in heterogenous catalysis?