Question
Discuss aldol condensation in detail.
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| | Column I (Compound/element) | | Column II (Use) |
| (i) | Lanthanoid oxide | (a) | Production of iron alloy |
| (ii) | Lanthanoid | (b) | Television screen |
| (iii) | Misch metal | (c) | Petroleum cracking |
| (iv) | Magnesium based alloy is constituent of | (d) | Lanthanoid metal + iron |
| (v) | Mixed oxides of lanthanoids are employed | (e) | Bullets |
| | | (f) | In X-ray screen |
(Kf for water = 1.86 K kg mol–1).
| t/s | 0 | 400 | 800 | 1200 | 1600 | 2000 | 2400 | 2800 | 3200 |
| 102 × [N2O5]/mol L-1 | 1.63 | 1.36 | 1.14 | 0.93 | 0.78 | 0.64 | 0.53 | 0.43 | 0.35 |
| | Column I (Catalyst) | | Column II (Process) |
| (i) | Ni in the presence of hydrogen | (a) | Zieglar Natta catalyst |
| (ii) | Cu2Cl2 | (b) | Contact process |
| (iii) | V2O5 | (c) | Vegetable oil to ghee |
| (iv) | Finely divided iron | (d) | Sandmeyer reaction |
| (v) | TiCl4 + Al (CH3)3 | (e) | Haber’s Process |
| | | (f) | Decomposition of KClO3 |