MCQ
$\begin{matrix}
   O\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,  \\
   ||\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,  \\
   P{{h}_{2}}CH-C-H\xrightarrow{aqueous\,acid}\underset{81\%}{\mathop{(A)}}\,+\underset{2\%}{\mathop{enol}}\,+\underset{17\%}{\mathop{aldehyde}}\,  \\
\end{matrix}$

Product $(A)$ of above reaction will be

  • A
    $\begin{matrix}
       Ph-C=CH-O  \\
       |\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,  \\
       Ph\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,  \\
    \end{matrix}$
  • B
    $\begin{matrix}
       \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,OH  \\
       \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|  \\
       P{{h}_{2}}CH-C{{H}_{2}}  \\
    \end{matrix}$
  • $\begin{matrix}
       \,\,\,\,\,\,\,\,\,\,\,OH  \\
       \,\,\,\,\,\,\,|  \\
       P{{h}_{2}}CH-CH-OH  \\
    \end{matrix}$
  • D
    $\begin{matrix}
       \,\,\,\,\,\,\,\,\,\,O  \\
       \,\,\,\,\,\,\,\,\,\,||  \\
       P{{h}_{2}}CH-C-C{{H}_{3}}  \\
    \end{matrix}$

Answer

Correct option: C.
$\begin{matrix}
   \,\,\,\,\,\,\,\,\,\,\,OH  \\
   \,\,\,\,\,\,\,|  \\
   P{{h}_{2}}CH-CH-OH  \\
\end{matrix}$
c
$(c)$ Geminal diol will be formed.

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