એક કાર્બનિક સંયોજન $A$, $C_5H_8O$; નીચે વર્ણવ્યા મુજબ $H_2O$, $NH_3$ અને $CH_3COOH$ સાથે પ્રક્રિયા આપે છે તો $A$ હશે ?
JEE MAIN 2014, Diffcult
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c
Given compound \(A\) is
Given compound \(A\) is
\(\begin{matrix}
C{{H}_{3}}-C{{H}_{2}}-C=C=O \\
\,\,\,\,\,\,\,\,\,\,\,\,| \\
\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{{H}_{3}} \\
\end{matrix}\)
Reactions given are as following:
\(\begin{array}{*{20}{c}}
{C{H_3} - C{H_2} - C = C = O\xrightarrow{{N{H_3}}}} \\
{{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} |{\mkern 1mu} \,\,{\mkern 1mu} \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,{\mkern 1mu} } \\
{{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{H_{3\,}}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}
\end{array}\) \(\left[ \begin{matrix}
C{{H}_{3}}-C{{H}_{2}}-C=\overset{+}{\mathop{C}}\,-{{O}^{-}} \\
\,\,\,\,\,\,\,\,\,\,\,\,| \\
\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{{H}_{3}} \\
\end{matrix} \right]\)
\(\updownarrow \)
\(\left[ \begin{matrix}
C{{H}_{3}}-C{{H}_{2}}-C=C-OH \\
\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,| \\
\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{{H}_{3}}\,\,N{{H}_{2}}\,\, \\
\end{matrix} \right]\)
\(\downarrow \)
\(\begin{matrix}
\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\begin{matrix}
\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,O\,\, \\
\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|| \\
\end{matrix}\,\,\,\,\,\,\,\,\, \\
C{{H}_{3}}-C{{H}_{2}}-CH-C-N{{H}_{2}} \\
| \\
\,\,\,\,\,\,\,\,C{{H}_{3}} \\
\end{matrix}\)
\(\begin{matrix}
C{{H}_{3}}-C{{H}_{2}}-C=C=O\xrightarrow{{{H}_{2}}O} \\
\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\, \,\,\,\, \\
\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{{H}_{3}}\,\,\,\,\,\,\,\,\, \\
\end{matrix}\) \(\begin{matrix}
C{{H}_{3}}-C{{H}_{2}}-CH-COOH \\
\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\
\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{{H}_{3}}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\
\end{matrix}\)
\(\begin{matrix}
C{{H}_{3}}-C{{H}_{2}}-C=C=O\xrightarrow{C{{H}_{3}}COOH} \\
\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\
\,\,\,\,\,\,\,\,\,\,C{{H}_{3}}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\
\end{matrix}\) \(\begin{matrix}
\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\begin{matrix}
O\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,O \\
||\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|| \\
\end{matrix} \\
C{{H}_{3}}-C{{H}_{2}}-CH-C-O-C-C{{H}_{3}} \\
|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\
C{{H}_{3}}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\
\end{matrix}\,\)
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