MCQ
Ethanol on reaction of acidified potassium dichromate form:
- AEthane
- BEthene
- CEthanal
- DEthanoic acid
Explanation:
C2H5OH + K2Cr2O7/H+ → CH3CHO → CH3COOH
Ethanol is first oxidised to ethanal and then to ethanoic acid.
Potassium dichromate is a very strong oxidising agent, ethanol on oxidation, the dichromate ion (IV) solution which is orange in colour is reduced to a green colour Cr(III) ion solution. This reaction is used in detecting the presence of alcohol in breath in suspected drunken drivers.
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$\text{HO}−\text{CH}_2−\text{CH}−\text{CH}_2−\text{OH}\\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ ∣ \\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \text{CH}_3$